RESUMO
A proper understanding on the charge mobility in organic materials is one of the key factors to realize highly functionalized organic semiconductor devices. So far, however, although a number of studies have proposed the carrier transport mechanism of rubrene single crystal to be band-like, there are disagreements between the results reported in these papers. Here, we show that the actual dispersion widths of the electronic bands formed by the highest occupied molecular orbital are much smaller than those reported in the literature, and that the disagreements originate from the diffraction effect of photoelectron and the vibrations of molecules. The present result indicates that the electronic bands would not be the main channel for hole mobility in case of rubrene single crystal and the necessity to consider a more complex picture like molecular vibrations mediated carrier transport. These findings open an avenue for a thorough insight on how to realize organic semiconductor devices with high carrier mobility.
RESUMO
A museum is an important place for science education for children. The learning method in the museum is reading exhibits and explanations. Museums are investing efforts to quantify interests using questionnaires and sensors to improve their exhibitions and explanations. Therefore, even in places where many people gather, such as in museums, it is necessary to quantify people's interest by sensing behavior of multiple people. However, this has not yet been realized. We aim to quantify the interest by sensing a wide range of human behavior for multiple people by coordinating multiple noncontact sensors. When coordinating multiple sensors, the coordinates and the time of each sensor differ. To solve these problems, coordinates were transformed using a simultaneous transformation matrix and time synchronization was performed using unified time. The effectiveness of this proposal was verified through experimental evaluation. Furthermore, we evaluated the actual museum content. In this paper, we describe the proposed method and the results of the evaluation experiment.