In Situ Wire + Powder Synchronous Arc Additive Manufacturing of Ti-Cu Alloys.

In this study, a new wire + powder synchronous arc additive manufacturing technique was used to manufacture Ti-Cu alloys. The microstructure and properties of the as-fabricated alloys were studied. The results showed that the prepared Ti-Cu alloys have good properties. The Cu with high growth restriction factor can increase the constitutional supercooling zone in the Ti-Cu alloys, which can override the negative effect of a high thermal gradient in the manufacturing process. Through the observation of the microstructure, the as-printed Ti-Cu alloy specimens have equiaxed fine-grained microstructure. Through corrosion performance analysis, the Cu can also make the passivation film of the alloy more compact and make the alloy more corrosion resistant.

Li2100deplMoO4 Scintillating Bolometers for Rare-Event Search Experiments.

We report on the development of scintillating bolometers based on lithium molybdate crystals that contain molybdenum that has depleted into the double-ß active isotope 100Mo (Li2100deplMoO4). We used two Li2100deplMoO4 cubic samples, each of which consisted of 45-millimeter sides and had a mass of 0.28 kg; these samples were produced following the purification and crystallization protocols developed for double-ß search experiments with 100Mo-enriched Li2MoO4 crystals. Bolometric Ge detectors were utilized to register the scintillation photons that were emitted by the Li2100deplMoO4 crystal scintillators. The measurements were performed in the CROSS cryogenic set-up at the Canfranc Underground Laboratory (Spain). We observed that the Li2100deplMoO4 scintillating bolometers were characterized by an excellent spectrometric performance (∼3-6 keV of FWHM at 0.24-2.6 MeV γs), moderate scintillation signal (∼0.3-0.6 keV/MeV scintillation-to-heat energy ratio, depending on the light collection conditions), and high radiopurity (228Th and 226Ra activities are below a few µBq/kg), which is comparable with the best reported results of low-temperature detectors that are based on Li2MoO4 using natural or 100Mo-enriched molybdenum content. The prospects of Li2100deplMoO4 bolometers for use in rare-event search experiments are briefly discussed.

Effects of ultrasonic vibration on microstructure and mechanical properties of 1Cr12Ni3MoVN alloy fabricated by directed energy deposition.

Due to the rapid melting and solidification during directed energy deposition (DED) process, the defects and columnar crystals are likely to generate in the deposition layers, which reduce the quality and performance of the whole parts. Therefore, in order to improve the microstructure and mechanical properties of 1Cr12Ni3MoVN alloy manufactured by DED method, ultrasonic vibration (UV) has been employed to assist directed energy deposition process in this work. The results indicate that the high-intensity ultrasonic vibration can weaken the epitaxy growth tendency of crystal grains, and significantly improve plasticity while keeping an approximate strength. In addition, a two-dimensional numerical model is established to simulate the effect of ultrasonic vibration in the molten pool. The simulation results show that ultrasonic vibration remarkably improves the flow velocity and pressure in the molten pool, inducing the cavitation effect that breaks dendritic crystal and affects crystal characteristics. Meanwhile, the acoustic streaming effect changes the thermodynamic conditions and promotes high-temperature diffusion, which uniforms temperature distribution and reduces the temperature gradient in the molten pool. Thus the reduced temperature gradient G and raised solidification growth rate R promote the formation of fine equiaxed crystal characteristics after UV treatment. The product G × R increases and the ratio G/R decreases after UV treatment, resulting in the formation of fine equiaxed crystals.

Influence of Constant Magnetic Field upon Fatigue Life of Commercially Pure Titanium.

Cyclic tests of the multicycle fatigue of commercially pure titanium were performed under normal conditions (without a magnetic field) and after exposure to a constant magnetic field of varying density (B = 0.3, 0.4, 0.5 T). It was shown that the application of the constant magnetic field of varying density led to a fold increase in the average number of cycles to destruction of the VT1-0 titanium samples by 64, 123, and 163%, respectively. Scanning electron microscopy revealed that the magnetic field led to a 1.45-fold increase in the critical length of the fracture (the width of the fatigue crack growth zone) and a 1.6-fold decrease in the distance between the fatigue striations in the accelerated crack growth zone of the destroyed titanium samples. It was established that a subgrain (fragmented) structure formed in the area of the fatigue growth of the fracture of the titanium samples. The size of the subgrains corresponded to the spaces between the fatigue striations, which had an inhibitory influence on the microcrack propagation. Collectively, the revealed facts are indicative of a higher material resistance to fatigue fracture propagation and increased operation resources under the fatigue tests in the magnetic field, which correlates with the data on the growth of the average number of cycles to fracture of the VT1-0 titanium samples.

Alloying Elements Effect on the Recrystallization Process in Magnesium-Rich Aluminum Alloy.

This paper addresses the study of the complex effect of alloying elements (magnesium, manganese, copper and zirconium) on changes in magnesium-rich aluminum alloy composition, fine and coarse particle size and number, recrystallization characteristics and mechanical properties. The data obtained made it possible to analyze change in the chemical composition, sizes of intermetallic compounds and dispersoids depending on alloying elements content. The effect of the chemical composition on the driving force and the number of recrystallization nuclei was studied. It was established that the addition of alloying elements leads to grain refinement, including through the activation of a particle-stimulated nucleation mechanism. As a result, with Mg increase from 4 to 5%, addition of 0.5% Mn and 0.5% Cu, the grain size decreased from 72 to 15 µm. Grain refinement occurred due to an increase in the number of particle-stimulated nuclei, the number of which at minimal alloying rose from 3.47 × 1011 to 81.2 × 1011 with the maximum concentration of Mg, Mn, Cu additives. The retarding force of recrystallization, which in the original alloy was 1.57 × 10-3 N/m2, increased to 5.49 × 10-3 N/m2 at maximum alloying. The influence of copper was especially noticeable, the introduction of 0.5% increasing the retarding force of recrystallization by 2.39 × 10-3 N/m2. This is due to the fact that copper has the most significant effect on the size and number of intermetallic particles. It was established that strength increase without ductility change occurs when magnesium, manganese and copper content increases.

Strengthening Mechanisms in CoCrFeNiX0.4 (Al, Nb, Ta) High Entropy Alloys Fabricated by Powder Plasma Arc Additive Manufacturing.

In high entropy alloys (HEAs), the addition of large-size atoms results in lattice distortion and further leads to solid solution strengthening or precipitation strengthening. However, the relationship between atomic radius, solid solution strengthening and precipitation strengthening has not been discerned yet. In this work, CoCrFeNiX0.4 (X = Al, Nb, Ta, with an equi-atomic radius) HEAs were prepared by powder plasma arc additive manufacturing (PPA-AM) and evaluated for their mechanical properties. Compression and nano-indentation hardness tests showed that the HEA with Ta showed the best properties. The influence of atomic radius and solid solubility on solid solution strengthening was investigated and the main strengthening mechanism that determines the mechanical properties of the developed HEAs was analyzed. The results showed that (i) the CoCrFeNiAl0.4 alloy did not show any solid solution strengthening effect and that a clear relation between solid solution strengthening and atomic size was not observed; (ii) in both CoCrFeNiTa0.4 and CoCrFeNiNb0.4 HEAs, precipitation strengthening and grain boundary strengthening effects are observed, wherein the difference in mechanical properties between both the alloys can be mainly attributed to the formation of fine eutectic structure in CoCrFeNiTa0.4; and (iii) from the microstructural analyses, it was identified that, in the CoCrFeNiTa0.4 HEA, the location containing a fine eutectic structure is accompanied by the formation of low-angle grain boundaries (LAGBs), which is also the region where deformed grains gather, giving rise to improved mechanical strengthening.

Influence of Silicon and Magnesium on the Mechanical Properties of Additive Manufactured Cu-Al Alloy.

By using cold metal transfer technique, Cu-Al alloy with addition of silicon (Si) and magnesium (Mg), viz (1) Cu-6.5% Al and (2) Cu-6.5% Al-1.2% Si-0.5% Mg were manufactured additively. Four samples were deposited: Cu-6.5% Al alloy as samples 1 and 2, and Cu-6.5% Al-1.2% Si-0.5% Mg alloy as samples 3 and 4. The alloys were homogenized by heat treatments: (1) 800°C (2 h) for sample 2 and (2) sample 4, to improve their mechanical properties. Detailed microstructural investigation conducted using scanning and transmission electron microscopies showed formation of various intermetallic phases. Results revealed that (1) the addition of Si and Mg increases the strength properties and ductility and (2) heat treatments improved strength properties but reduce the ductility of the alloys. The article discusses the correlation of the identified microstructure and the evaluated mechanical properties of the additively manufactured alloys.

Fatigue-Induced Evolution of AISI 310S Steel Microstructure after Electron Beam Treatment.

Research was carried out to explore the effect of pulsed electron beam irradiation on the behavior of structure and phase state in AISI 310S steel exposed to high-cycle fatigue. A 2.2 times increase in the fatigue life of samples irradiated by electron beams was revealed. The outcomes of scanning and transmission electron microscopic studies suggest the most probable reason for the fracture of steel samples irradiated by a high-intensity electron beam to be microcraters originating on a treated surface and acting as stress risers initiating the propagation of microcracks. The irradiation with a pulsed electron beam causes extremely fast melting of the surface. As a result of the subsequent rapid crystallization, a polycrystalline structure nearly twice as small as an average grain in the untreated steel is formed. Since a surface layer crystallizes rapidly, crystallization cells ranging from 120 to 170 nm develop in the volume of grains. The fatigue testing is shown to be associated with a martensite transformation γ ⇒ ε in the surface layer. One option to intensify a fatigue life increase of the steel in focus is supposed to be the neutralization of crater-forming on a surface treated by electron beams.

On the Shaping of a Short Signal at the Output of the Receiving Piezoelectric Transducer in the Radiation-Reception System.

This paper theoretically and experimentally considers the pulsed mode of operation of the radiation-receiving system. The system contains two identical piezoceramic plates separated by a layer of immersion liquid (glycerin). The emitter was excited by the complex electrical signal of the special shape, which consisted of two half-cycles of the sine wave (exciting and compensating) on the natural frequency of the piezoplates. The forms of these signals were calculated by the authors and described in their previous papers using the d’Alembert method. The length of the electrical signal was estimated at the output of the piezoelectric receiver. The problem was solved theoretically using the finite element method. The acoustical system was simulated with the help of the COMSOL Multiphysics modeling environment. A comparative study of the theoretical and experimental results is carried out. The form of the signal at the output of the system was calculated by the d’Alembert method, and the simulated form by the finite element method was in good coincidence with the results of experimental and full-scale modeling. It is shown that the usage of complex waveforms allows achieving a significant pulse duration reduction of the electrical voltage at the output of the receiver.

Numerical simulation of the intra-annual evolution of beryllium-7 (7Ве) in the surface layer of the Black Sea.

A numerical model simulating the distribution of 7Ве in the Black Sea was developed and applied to study the spatial and temporal variations in the content of 7Be in the surface waters. Variations in the distribution of 7Ве were analyzed for the period from January to December of 2012. The average seasonal content of 7Ве in the surface layer ranges from 2.2 to 6.2 Bq m-3. The maximum concentration is typical for the eastern part of the sea in winter to spring, and the minimum concentration is typical for the central and western parts of the sea in summer. The seasonally averaged activity of 7Ве on suspended matter ranges from 440 to 1560 Bq kg-1. The highest values are observed in the sea in winter to spring, and the lowest values are typically observed in the central and western parts of the sea in summer. It was revealed that the adsorption of 7Ве on suspended matter is most significant for the evolution of the content of this radionuclide in shelf waters.