1.
Chem Commun (Camb)
; 52(19): 3750-3, 2016 Mar 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26800518
RESUMO
The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses.