1.
Chemistry
; 29(46): e202301063, 2023 Aug 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37252754
RESUMO
Homoallylic amines prepared via addition of allylsilanes often require preformed imine substrates, metal catalysts, fluoride activators, or use of protected amines. In this metal-free, air- and water-tolerant procedure, aromatic aldehyde and aniline substrates undergo direct alkylative amination using easily accessible 1-allylsilatrane.