Relationship of properties of polycyclic aromatic hydrocarbons to sequestration in soil.

A study was conducted to determine whether the sequestration of 21 polycyclic aromatic hydrocarbons (PAHs) in soil was correlated with their properties. From 22 to 58% of the PAHs was not extracted with n-butanol after their addition to soil. After 28 days of aging, the percentage of the PAHs remaining in the soil increased to 47-77%; however, nearly all of each compound was recovered by Soxhlet extraction. Correlations were based on the amounts of aged compound extracted with butanol. Properties of compounds used in the correlations included Kow, molecular length and molecular-connectivity indices (MCIs). No one property, including log Kow, resulted in an R2 value greater than 0.26. A chain MCI (2 chi vCH) together with log Kow or a first-order MCI (1 chi) resulted in R2 values of 0.49 and 0.54, respectively. The data suggest that the properties tested are not important to predicting the sequestration of PAHs in soil.

Influence of soil moisture on the sequestration of organic compounds in soil.

A study was conducted as a part of continuing investigation of the effect of soil moisture on the sequestration of organic compounds aged in the soil. Here, experiments focused on the effects of moisture changes within the soil before, during, and after contaminant addition. The extractability of aged (68 d) phenanthrene was greater from soil that had been subjected to wetting and drying cycles prior to solute addition as compared to soil initially maintained at constant moisture. The recovery of phenanthrene added to moist soil was increased relative to extractability from soil that was air-dried at the time of the contaminant addition. Repeated wetting and drying of soil after the addition of atrazine or phenanthrene resulted in decreased extractability of the compounds as compared to samples maintained at constant moisture. A method for rapidly sequestering contaminants is proposed and may be useful in limiting the time required for laboratory studies involving "aged" contaminants. These data build upon the findings of earlier work from our laboratory and indicate that changes in the moisture conditions of soil can affect the availability of sequestered contaminants possibly through alterations in the structure of the natural solid.