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1.
BMC Med Inform Decis Mak ; 23(1): 221, 2023 10 16.
Artigo em Inglês | MEDLINE | ID: mdl-37845677

RESUMO

This article focuses on the development of algorithms for a smart neurorehabilitation system, whose core is made up of artificial neural networks. The authors of the article have proposed a completely unique transfer of ACE-R results to the CHC model. This unique approach allows for the saturation of the CHC model domains according to modified ACE-R factor analysis. The outputs of the proposed algorithm thus enable the automatic creation of a personalized and optimized neurorehabilitation plan for individual patients to train their cognitive functions. A set of tasks in 6 levels of difficulty (level 1 to level 6) was designed for each of the nine CHC model domains. For each patient, the results of the ACE-R screening helped deter-mine the specific CHC domains to be rehabilitated, as well as the initial gaming level for rehabilitation in each domain. The proposed artificial neural network algorithm was adapted to real data from 703 patients. Experimental outputs were compared to the outputs of the initially designed fuzzy expert system, which was trained on the same real data, and all outputs from both systems were statistically evaluated against expert conclusions that were available. It is evident from the conducted experimental study that the smart neurorehabilitation system using artificial neural networks achieved significantly better results than the neurorehabilitation system whose core is a fuzzy expert system. Both algorithms are implemented into a comprehensive neurorehabilitation portal (Eddie), which was supported by a research project from the Technology Agency of the Czech Republic.


Assuntos
Sistemas Inteligentes , Reabilitação Neurológica , Humanos , Lógica Fuzzy , Redes Neurais de Computação , Algoritmos
2.
IEEE Trans Neural Netw Learn Syst ; 34(4): 2016-2027, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-34449399

RESUMO

The study deals with the issue of using spiking neural networks (SNNs) in multiagent systems. The research objective is a proposal of a control algorithm for the cooperation of a group of agents using SNNs, application of the Izhikevich model, and plasticity depending on the timing of action potentials. The proposed method has been verified and experimentally tested, proving numerous advantages over second-generation networks. The advantages and the application in real systems are described in the research conclusions.

3.
ACS Energy Lett ; 7(10): 3401-3414, 2022 Oct 14.
Artigo em Inglês | MEDLINE | ID: mdl-36277137

RESUMO

Since the inception of the unprecedented rise of halide perovskites for photovoltaic research, ion migration has shadowed this material class with undesirable hysteresis and degradation effects, limiting its practical implementations. Unfortunately, the localized doping and electrochemical reactions triggered by ion migration cause many more undesirable effects that are often unreported or misinterpreted because they deviate from classical semiconductor behavior. In this Perspective, we provide a concise overview of such effects in halide perovskites, such as operational instability in photovoltaics, polarization-induced abnormal external quantum efficiency in light-emitting diodes, and energy channel shift and anomalous sensitivities in hard radiation detection. Finally, we highlight a unique use case of exploiting ion migration as a boon to design emerging memory technologies such as memristors for information storage and computing.

4.
Neural Netw ; 145: 342-355, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34801943

RESUMO

Financial market predictions represent a complex problem. Most prediction systems work with the term time window, which is represented by exchange rate values of a real financial commodity. Such values (time window) provide the base for prediction of future values. Real situations, however, prove that prediction of only a single time-series trend is insufficient. This article aims at suggesting a novelty and unconventional approach based on the use of several neural networks predicting probable courses of a future trend defined in a prediction time window. The basis of the proposed approach is a suitable representation of the training-set input data into the neural networks. It uses selected FFT coefficients as well as robust output indicators based on a histogram of the predicted course of the selected currency pair. At the same time, the given currency pair enters the prediction in a combination with another three mutually interconnected currency pairs. A significant output of the articles is, apart from the proposed methodology, confirmation that the Elliott wave theory is beneficial in the trading environment and provides a substantial profit compared with conventional prediction techniques. That was proved in the performed experimental study.


Assuntos
Redes Neurais de Computação , Previsões , Probabilidade
5.
Neural Netw ; 116: 150-165, 2019 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-31063925

RESUMO

This article presents a steganographic method StegoNN based on neural networks. The method is able to identify a photomontage from presented signed images. Unlike other academic approaches using neural networks primarily as classifiers, the StegoNN method uses the characteristics of neural networks to create suitable attributes which are then necessary for subsequent detection of modified photographs. This also results in a fact that if an image is signed by this technique, the detection of modifications does not need any external data (database of non-modified originals) and the quality of the signature in various parts of the image also serves to identify modified (corrupted) parts of the image. The experimental study was performed on photographs from CoMoFoD Database and its results were compared with other approaches using this database based on standard metrics. The performed study showed the ability of the StegoNN method to detect corrupted parts of an image and to mark places which have been most probably image-manipulated. The usage of this method is suitable for reportage photography, but in general, for all cases where verification (provability) of authenticity and veracity of the presented image are required.


Assuntos
Redes Neurais de Computação , Reconhecimento Automatizado de Padrão/métodos , Fotografação/métodos , Bases de Dados Factuais/normas , Humanos , Reconhecimento Automatizado de Padrão/normas , Fotografação/normas , Reprodutibilidade dos Testes
6.
Chem Mater ; 31(6): 2121-2129, 2019 Mar 26.
Artigo em Inglês | MEDLINE | ID: mdl-30930536

RESUMO

Hybrid organic-inorganic main-group metal halide compounds are the subject of intense research owing to their unique optoelectronic characteristics. In this work, we report the synthesis, structure, and electronic and optical properties of a family of hybrid tin (II) bromide compounds comprising guanidinium [G, C(NH2)3 +] and mixed cesium-guanidinium cations: G2SnBr4, CsGSnBr4, and Cs2GSn2Br7. G2SnBr4 has a one-dimensional structure that consists of chains of corner-sharing [SnBr5]2- square pyramids and G cations situated in between the chains. Cs+ exhibits a pronounced structure-directing effect where a mixture of Cs+ and G cations forms mono- and bilayered two-dimensional perovskites: CsGSnBr4 and Cs2GSn2Br7. Furthermore, the flat shapes of the guanidinium cations induce anisotropic out-of-plane tilts of the [SnBr6]4- octahedra in the CsGSnBr4 and Cs2GSn2Br7 compounds. In G2SnBr4, the Sn lone pair is highly stereoactive and favors non-octahedral, that is, square pyramidal coordination of Sn(II). G2SnBr4 exhibits bright broad-band emission from self-trapped excitonic states, owing to its soft lattice and electronic localization. This emission in G2SnBr4 is characterized by a photoluminescence (PL) quantum yield of 2% at room temperature (RT; 75 ± 5% at 77 K) and a fast PL lifetime of 18 ns at room temperature.

7.
J Am Chem Soc ; 140(11): 3850-3853, 2018 03 21.
Artigo em Inglês | MEDLINE | ID: mdl-29502407

RESUMO

Two-dimensional hybrid organic-inorganic lead halides perovskite-type compounds have attracted immense scientific interest due to their remarkable optoelectronic properties and tailorable crystal structures. In this work, we present a new layered hybrid lead halide, namely [CH(NH2)2][C(NH2)3]PbI4, wherein puckered lead-iodide layers are separated by two small and stable organic cations: formamidinium, CH(NH2)2+, and guanidinium, C(NH2)3+. This perovskite is thermally stable up to 255 °C, exhibits room-temperature photoluminescence in the red region with a quantum yield of 3.5%, and is photoconductive. This study highlights a vast structural diversity that exists in the compositional space typically used in perovskite photovoltaics.

8.
Inorg Chem ; 56(19): 11552-11564, 2017 Oct 02.
Artigo em Inglês | MEDLINE | ID: mdl-28895725

RESUMO

Interest in hybrid organic-inorganic lead halide compounds with perovskite-like two-dimensional crystal structures is growing due to the unique electronic and optoelectronic properties of these compounds. Herein, we demonstrate the synthesis, thermal and optical properties, and calculations of the electronic band structures for one- and two-layer compounds comprising both cesium and guanidinium cations: Cs[C(NH2)3]PbI4 (I), Cs[C(NH2)3]PbBr4 (II), and Cs2[C(NH2)3]Pb2Br7 (III). Compounds I and II exhibit intense photoluminescence at low temperatures, whereas compound III is emissive at room temperature. All of the obtained substances are stable in air and do not thermally decompose until 300 °C. Since Cs+ and C(NH2)3+ are increasingly utilized in precursor solutions for depositing polycrystalline lead halide perovskite thin films for photovoltaics, exploring possible compounds within this compositional space is of high practical relevance to understanding the photophysics and atomistic chemical nature of such films.

9.
ScientificWorldJournal ; 2015: 205749, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-26221620

RESUMO

The paper deals with ECG prediction based on neural networks classification of different types of time courses of ECG signals. The main objective is to recognise normal cycles and arrhythmias and perform further diagnosis. We proposed two detection systems that have been created with usage of neural networks. The experimental part makes it possible to load ECG signals, preprocess them, and classify them into given classes. Outputs from the classifiers carry a predictive character. All experimental results from both of the proposed classifiers are mutually compared in the conclusion. We also experimented with the new method of time series transparent prediction based on fuzzy transform with linguistic IF-THEN rules. Preliminary results show interesting results based on the unique capability of this approach bringing natural language interpretation of particular prediction, that is, the properties of time series.


Assuntos
Eletrocardiografia/métodos , Lógica Fuzzy , Linguística , Redes Neurais de Computação , Potenciais de Ação , Algoritmos , Humanos , Processamento de Sinais Assistido por Computador , Fatores de Tempo , Análise de Ondaletas
10.
Angew Chem Int Ed Engl ; 54(33): 9606-9, 2015 Aug 10.
Artigo em Inglês | MEDLINE | ID: mdl-26110509

RESUMO

YAlC was prepared by a flux method. It crystallizes as a partially filled-up TlI structure, showing remarkable structural aspects at the border between Zintl phases and intermetallics. This novel ternary aluminide-carbide exhibits a unique one-dimensional multi-center bond and a polyacetylene-related aluminum carbide substructure. The different functionalities of aluminum and of yttrium are quite remarkable. While the latter behaves more like a trivalent ion, aluminum contributes considerably to covalent bonding with carbon. Still yttrium d states contribute, but hardly in a directed manner.

11.
Inorg Chem ; 54(3): 710-2, 2015 Feb 02.
Artigo em Inglês | MEDLINE | ID: mdl-25423353

RESUMO

A novel ternary aluminum carbide, Y(3)AlC(3), has been synthesized under application of a lithium metal flux at high temperature (1523 K). Single-crystal structure determination of this compound revealed a new structure type with the Wyckoff sequence 2j3e and remarkable structural features at the border between Zintl and intermetallic phases. The puzzling bonding structure of Y(3)AlC(3) is analyzed with the aid of electronic structure calculations (energy bands and the electron localization function).

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