Probing the Effect of Linear and Crosslinked POE-g-GMA on the Properties of Asphalt.

The copolymer ethylene-octene (POE) has good aging resistance and is an inexpensive asphalt additive compared to the styrene-butadiene-styrene copolymer (SBS). However, POE is easy to segregate in asphalt during storage at high temperatures. Grafting glycidyl methacrylate (GMA) onto the molecular backbone of POE (i.e., POE-g-GMA) may solve this problem, for the epoxy groups in GMA can react with the active groups in asphalt. Asphalt modified with linear and crosslinked POE-g-GMA were prepared, and the hot storage stability, physical properties and thermal oxidation aging properties were discussed in detail. The results show that linear and low-degree crosslinked POE-g-GMA-modified asphalts are storage-stable at high temperatures via measurements of the difference in softening points and small-angle X-ray scattering (SAXS) characterizations from macro and micro perspectives. The difference in softening points (ΔSP) between the upper and lower ends is no more than 3.5 °C for modified asphalts after 48 h of being in an oven at 163 °C. More importantly, the crosslinking modification of POE-g-GMA can further increase the softening point and reduce the penetration as well as rheological properties via conventional physical property, dynamic shear rheometer (DSR) and multiple-stress creep recovery (MSCR) tests. Furthermore, asphalt modified with crosslinked POE-g-GMA reveals better aging resistance via measurements of the performance retention rate and electron paramagnetic resonance (EPR) characterizations after a rolling thin film oven test (RTFOT). This work may provide further guidelines for the application of polymers in asphalt.

Influences of Efficient Spraying of Cement-Based Slurries on Recycled Coarse Aggregate.

The inferior property is usually one of the major problems of recycled coarse aggregate (RCA), and the utilization of the RCA is limited. Strengthening the RCA is being widely explored. Immersing the RCA in the cement-based slurry is an effective approach. However, lots of slurry and time are required, and it is difficult to integrate the immersing method into the production line of the RCA. In this paper, a circular spraying method was proposed to treat the RCA using cement-based slurry. The immersing method was also conducted to verify the feasibility of the spraying method. The crushing value (CV), 24 h water absorption (WA), apparent density (AD) and dynamic water absorption (DWA) were tested, and the micro-morphology was also observed to explore the strengthening mechanism. Results showed that the CV and the WA decreased by up to 30.0% and 14.3% when the spraying method was used. The AD was slightly influenced by the cement-based slurry regardless of the treatment method. Considering the CV, WA and AD, the comprehensive grade of the RCA could be enhanced from III to II by using the spraying method. It was worth noting that the effects of the spraying method and the immersing method were basically equivalent. When the spraying method was adopted, only about 1 min and a small amount of slurry (about 5% of the RCA mass) were required to treat the RCA.

Shear Deformation Behavior of a Double-Layer Asphalt Mixture Based on the Virtual Simulation of a Uniaxial Penetration Test.

This paper aims to clarify the shear deformation behavior of double-layer asphalt mixtures using the virtual uniaxial penetration test (UPT) with a discrete element method. For this purpose, asphalt mixtures with two different nominal maximum aggregate sizes were designed for the preparation of double-layer wheel tracking test specimens. Then, the cylindrical cores were prepared from the specimens and were cut for capturing the longitudinal profile images. These images were used to reconstruct a two-dimensional discrete element model (DEM) of the uniaxial penetration test specimen. The results indicate that the shear deformation behavior of the asphalt mixtures showed corresponding changes under the virtual loading. The tensile and compressive stress were distributed unevenly within the upper layer after the test, and both coarse aggregates and asphalt mortars bore a greater shear stress. Therefore, cracks were more likely to occur in the upper layer, leading to the failure of the specimens. This process enhanced the bonding between the asphalt mortars and the mineral aggregates. The aggregate particles in the upper layer moved more vertically, while those in the lower layer generally moved more laterally under the virtual loading. This behavior reveals the rutting mechanism of asphalt pavement.

Physical, Rheological, and Morphological Properties of Asphalt Reinforced by Basalt Fiber and Lignin Fiber.

Studies show that each kind of fiber has its own advantages in improving the properties of asphalt binders. However, there are very limited research studies about mixed fiber-reinforced asphalt (MFRA). In this study, two kinds of fibers, basalt fiber (BF) and lignin fiber (LF), were selected to reinforce SBS (styrene-butadiene-styrene triblock copolymer)-modified asphalt, which is now widely used in pavement engineering. MFRA samples with different fiber mix ratios (FMRs) were prepared for the tests of softening point, ductility, and rheological properties, the micromorphology of which was studied by using scanning electron microscope (SEM). The oil (asphalt) absorption rates of mixed fibers with different FMRs were also tested. The results show that the properties of MFRA were affected by the physical and chemical properties of fibers. Basalt fiber can better strengthen the physical properties of MFRA, while lignin fiber is good for improving the rheological properties, and the oil absorption rate of lignin fiber is higher than that of basalt fiber. Furthermore, the best FMR calculated by the efficacy coefficient method (ECM) was recommended as 1:2 (BF:LF). An interface layer between the fiber and asphalt was observed from the micro images, proving that the fibers bond well with the asphalt. Generally, mixing BF and LF together into SBS-modified asphalt could make full use of the advantages of different fibers and reinforce the comprehensive performance of MFRA better.