Nitrogen and phosphorus spatio-temporal distribution and fluxes intensifying eutrophication in three tropical rivers of Côte d'Ivoire (West Africa).

Nutrient contamination assessments in the three West African tropical Comoé, Bandama, and Bia Rivers (Côte d'Ivoire) were performed from March 2016 to March 2018. Five stations per river were sampled. Nutrients spatio-temporal distributions were mapped and showed nitrogen concentrations (nitrite 0.001 to 0.025 mg/L NO2--N, and nitrate 0.26 to 3.60 mg/L NO3--N) increased significantly with rainfall contrary to phosphorus (0.01 to 0.12 mg/L P). The Chl-a and TSItsr data revealed the hypereutrophic status of rivers. Moreover, N:P mass ratio suggests nitrogen as the main limiting factor of primary production during the low (March) and high flow periods (October-November), while phosphorus is the limiting factor in June, at the high flow beginning. The land uses around watersheds were the main sources of phosphorus and nitrogen enhancing the rivers' eutrophication. Phosphorus and nitrogen fluxes were related to leaching river catchments and were significant sources of nutrients to the Atlantic Ocean.

Impact of municipal solid waste dumpsites on trace metal contamination levels in the surrounding area: a case study in West Africa, Abidjan, Cote d'Ivoire.

The impact of uncontrolled municipal dumping sites on metal contamination in the surrounding waters, sediments, and soils are of great concern in many developing countries. Total concentrations of trace metals Cd, Zn, Cu, Pb, Ni, and Co were measured in 33 sediments collected in the vicinity of the Akouedo dumpsite (Abidjan, Cote d'Ivoire) and in a baseline station. The Cu, Zn, Cd, and Pb concentrations in surface sediments around the dumpsite were at least three times higher than those at the reference station, suggesting that the Akouedo dumping site is a significant contamination source of these metals to the surrounding sediments. The extent of contamination affects sediment as deep as 100 cm. Sediment pH and total organic carbon content control the distribution of Cu, Zn, and Cd in subsurface sediments. Significant Cd, Zn, and Cu enrichments were measured at the dumpsite and its surrounding environment. Zn concentrations in the sediments might cause high ecological risks at 46% of the samples based on the sediment quality guidelines (SQGs). Single and sequential extraction results showed a low mobility rate of Cd, Cu, Pb, and Ni from sediments around the dumpsite. However, the results suggest that the high total metal concentrations in the dumpsite sediments have resulted in a significant metal load in the surrounding environment.

Trace metal(loid)s contamination in paddy rice (Oryza sativa L.) from wetlands near two gold mines in Côte d'Ivoire and health risk assessment.

This study examined the concentrations of arsenic (As), cadmium (Cd), and mercury (Hg) in rice grains grown in wetlands associated with gold mining in central-southern of Côte d'Ivoire to evaluate potential health risks exposure via rice consumption. In total, 30 rice grains were sampled around Agbaou and Bonikro gold mines. Arsenic and cadmium concentrations were determined using an inductively coupled plasma-optical emission spectrometer (ICP-OES), while atomic absorption spectrometry (AAS) was used for mercury. Results showed that As and Hg average concentrations in rice were above the permissible limits, while Cd average concentrations were below the permissible limit established by FAO/WHO in both sites. Except for Hg at Agbaou, no significant (p < 0.05) difference was found between trace metal concentrations in the two sites. The average daily intake (ADI) of As via rice consumption exceeded the USEPA reference dose (RfD) of 0.0003 µg g-1 day-1, indicating that rice ingestion is a pathway of As exposure for adults and children in the area. The average values of non-carcinogen (HQ) for As and carcinogen (CR) for As and Cd risks index suggest that potential health risks exist for both adults and children due to rice consumption at Agbaou and Bonikro. The maximum safe weekly consumption (MSWC) of rice relative to As, Cd, and Hg was estimated for the study area. Overall, this study provides strong evidence that As could threaten local population health in Côte d'Ivoire regions where gold mine extraction is occurring through rice ingestion.

Preliminary data on arsenic and trace metals concentrations in wetlands around artisanal and industrial mining areas (Cote d'Ivoire, West Africa).

This data article is issued from the research article ''Distribution trends and ecological risks of arsenic and trace metals in wetland sediments around gold mining activities in central-southern and southeastern Côte d'Ivoire'' [1]. It presents arsenic and trace metal Cd, Pb, Cu, Zn, Cr, Co, Fe, Al, Mn, and Ni loadings in surface sediments collected from industrial mining, artisanal and small scale mining, and non-mining areas (West Africa). Are also provided, hierarchical dendrograms and factor loadings derived from the Hierarchical Clustering Analysis (HCA) and the principal component analysis (PCA), respectively. Data ranged from