Sustainable Soil Additives for Water and Micronutrient Supply: Swelling and Chelating Properties of Polyaspartic Acid Hydrogels Utilizing Newly Developed Crosslinkers.

Drought and water shortage are serious problems in many arid and semi-arid regions. This problem is getting worse and even continues in temperate climatic regions due to climate change. To address this problem, the use of biodegradable hydrogels is increasingly important for the application as water-retaining additives in soil. Furthermore, efficient (micro-)nutrient supply can be provided by the use of tailored hydrogels. Biodegradable polyaspartic acid (PASP) hydrogels with different available (1,6-hexamethylene diamine (HMD) and L-lysine (LYS)) and newly developed crosslinkers based on diesters of glycine (GLY) and (di-)ethylene glycol (DEG and EG, respectively) were synthesized and characterized using Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) and regarding their swelling properties (kinetic, absorbency under load (AUL)) as well as biodegradability of PASP hydrogel. Copper (II) and zinc (II), respectively, were loaded as micronutrients in two different approaches: in situ with crosslinking and subsequent loading of prepared hydrogels. The results showed successful syntheses of di-glycine-ester-based crosslinkers. Hydrogels with good water-absorbing properties were formed. Moreover, the developed crosslinking agents in combination with the specific reaction conditions resulted in higher water absorbency with increased crosslinker content used in synthesis (10% vs. 20%). The prepared hydrogels are candidates for water-storing soil additives due to the biodegradability of PASP, which is shown in an exemple. The incorporation of Cu(II) and Zn(II) ions can provide these micronutrients for plant growth.

The ultraviolet landscape of two-Higgs doublet models.

We study the predictions of generic ultraviolet completions of two-Higgs doublet models. We assume that at the matching scale between the two-Higgs doublet model and an ultraviolet complete theory - which can be anywhere between the TeV and the Planck scale - arbitrary but perturbative values for the quartic couplings are present. We evaluate the couplings down from the matching scale to the weak scale and study the predictions for the scalar mass spectrum. In particular, we show the importance of radiative corrections which are essential for both an accurate Higgs mass calculation as well as determining the stability of the electroweak vacuum. We study the relation between the mass splitting of the heavy Higgs states and the size of the quartic couplings at the matching scale, finding that only a small class of models exhibit sizeable mass splittings between the heavy scalars at the weak scale. Moreover, we find a clear correlation between the maximal size of the couplings and the considered matching scale.