Improved Hydrophobicity of a Bacterial Cellulose Surface: Click Chemistry in Action.

The vast application potentials of bacterial cellulose (BC)-based materials for developing leather-like materials, wound-healing materials and electronic materials have been realized very recently. Surface functionalization of these materials can help in improvement of certain properties such as water repellency, mechanical strength, and so forth. In this paper, we reported functionalization of BC surfaces using "click" polymerization for the first time. By this methodology, dense aromatic groups have been incorporated for the improvement of hydrophobicity. For comparative studies, various fluorine-based compounds have been introduced using conventional click reactions. The surface-modified BC materials have been confirmed by various spectroscopic methods. Particularly, the chemical structures of the materials were studied by solid-state 13C NMR spectroscopy and attenuated total reflection-infrared spectroscopy. X-ray photoelectron spectroscopy was used to study the elemental composition of the materials. Moreover, the crystallite changes of modified BC surfaces were investigated by X-ray diffraction. Further, the changes in the morphology of the material after functionalization were evaluated by scanning electron microscopy and atomic force microscopy. Finally, water contact angle measurement revealed manyfold increase in hydrophobicity after click polymerization. A video is also provided in the Supporting Information to show the application potential of this material for developing leather-like materials.

Controlled decoration of the surface with macromolecules: polymerization on a self-assembled monolayer (SAM).

Polymer functionalized surfaces are important components of various sensors, solar cells and molecular electronic devices. In this context, the use of self-assembled monolayer (SAM) formation and subsequent reactions on the surface have attracted a lot of interest due to its stability, reliability and excellent control over orientation of functional groups. The chemical reactions to be employed on a SAM must ensure an effective functional group conversion while the reaction conditions must be mild enough to retain the structural integrity. This synthetic constraint has no universal solution; specific strategies such as "graft from", "graft to", "graft through" or "direct" immobilization approaches are employed depending on the nature of the substrate, polymer and its area of applications. We have reviewed current developments in the methodology of immobilization of a polymer in the first part of the article. Special emphasis has been given to the merits and demerits of certain methods. Another issue concerns the utility - demonstrated or perceived - of conjugated or non-conjugated macromolecules anchored on a functionally decorated SAM in the areas of material science and biotechnology. In the last part of the review article, we looked at the collective research efforts towards SAM-based polymer devices and identified major pointers of progress (236 references).