RESUMO
CeO2, an n-type semiconductor material, has been widely used in microwave absorption (MA) due to its unique structural features such as oxygen vacancies and interstitial atoms. In this paper, Co/CeO2/C composites were prepared by a hydrothermal method followed by a pyrolysis process. The effect of different pyrolysis temperatures (650-950 °C) on the MA property of the composites was investigated. When the pyrolysis temperature was 850 °C, the Co/CeO2/C-850 composite exhibited outstanding MA behavior in the frequency range of 2-18 GHz, displaying a minimum reflection loss (RLmin) of -45.22 dB and an effective absorption bandwidth (EAB) of 4.61 GHz at a thin thickness of 1.75 mm. The MA performance of the Co/CeO2/C composites is mainly attributed to the dielectric loss due to interfacial polarization originating from different interfaces and dipole polarization caused by the oxygen vacancies in CeO2. In addition, the introduction of Co nanoparticles not only provides the magnetic loss but also modulates impendence matching for the current magnetoelectric coupling system.
RESUMO
FeNiMo/SiO2 powder cores were prepared using the sol-gel method. Tetraethyl orthosilicate (TEOS) was added to produce an amorphous SiO2 coating outside the FeNiMo particles to form a core-shell structure. The thickness of the SiO2 layer was designed by varying the concentration of TEOS, and the optimized permeability and magnetic loss of the powder core could achieve 78.15 and 633.44 kW m-3 at 100 kHz and 100 mT, respectively. Compared with other soft magnetic composites, these FeNiMo/SiO2 powder cores have a significantly higher effective permeability and a lower core loss. Surprisingly, the high-frequency stability of permeability could be substantially enhanced through the insulation coating process in which µf/µ100 kHz could reach 98.7% at 1 MHz. In comparison with 60µ commercial products, the comprehensive soft magnetic properties of the FeNiMo/SiO2 cores were superior to most manufacturers, which would be potentially applied to high-performance inductance devices in high-frequency ranges.
RESUMO
The controllable preparation of ligand-protected clusters is still an unresolved problem, which may be due to that their formation mechanism is unclear. We propose that the ligand is the key to solve the above problems. Here, by using p-, m-, and o-methylbenzenethiol ligand protected gold clusters as examples, we try to explore the effect of ligand structures on ligand-protected gold clusters. The geometrical structures, relative stabilities and surface properties of small-sized ligand-protected gold clusters [Au-SR]1-8 (SR = p-/m-/o-MBT) have been systematically studied based on the density functional theory. The results show that the ground state structures of [Au-SR]1-8 clusters tend to form closed rings except for [Au-SR]1,2. The different structures of ligand have significant effect on the structures and stabilities of ligand-protected clusters. By analyzing their surface properties and possible growth patterns, it is found that [Au-SR]1,2 clusters serve as the basic building blocks, and the larger clusters can be regarded as the combinations of them. This study provides some insights into the effect of ligands on ligand-protected clusters, which is useful for understanding the formation mechanism of ligand-protected clusters.
RESUMO
We report on all-optical devices prepared from WSe2 combined with drawn tapered fibers as saturable absorbers to achieve ultrashort pulse output. The saturable absorber with a high damage threshold and high saturable absorption characteristics is prepared for application in erbium-doped fiber lasers by the liquid phase exfoliation method for WSe2, and the all-optical device exhibited strong saturable absorption characteristics with a modulation depth of 15% and a saturation intensity of 100.58 W. The net dispersion of the erbium-doped fiber laser cavity is ~-0.1 ps2, and a femtosecond pulse output with a bandwidth of 11.4 nm, a pulse width of 390 fs, and a single-pulse capability of 42 pJ is obtained. Results indicate that the proposed WSe2 saturable absorbers are efficient, photonic devices to realize stable fiber lasers. The results demonstrate that the WSe2 saturable absorber is an effective photonic device for realizing stable fiber lasers, which have a certain significance for the development of potential photonic devices.
RESUMO
Using density functional theory and semiclassical Boltzmann transport equation, the lattice thermal conductivity and electronic transport performance of monolayer SnI2 were systematically investigated. The results show that its room temperature lattice thermal conductivities along the zigzag and armchair directions are as low as 0.33 and 0.19 W/mK, respectively. This is attributed to the strong anharmonicity, softened acoustic modes, and weak bonding interactions. Such values of the lattice thermal conductivity are lower than those of other famous two-dimensional thermoelectric materials such as MoO3, SnSe, and KAgSe. The two quasi-degenerate band valleys for the valence band maximum make it a p-type thermoelectric material. Due to its ultralow lattice thermal conductivities, coupled with an ultrahigh Seebeck coefficient, monolayer SnI2 possesses an ultrahigh figure of merits at 800 K, approaching 4.01 and 3.34 along the armchair and zigzag directions, respectively. The results indicate that monolayer SnI2 is a promising low-dimensional thermoelectric system, and would stimulate further theoretical and experimental investigations of metal halides as thermoelectric materials.
