1.
Org Biomol Chem
; 19(48): 10587-10595, 2021 Dec 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34542128
RESUMO
Long-chain n-alkyl-H-phosphinic acids (Alk = C4-C18) are chemoselectively synthesized in yields up to 90% via the direct one-pot alkylation/oxidation of red phosphorus (Pn) in the multi-phase alkyl bromide/KOH/H2O/toluene system with alkyl-PEG recyclable micellar catalysts, which demonstrate good recyclability.