Determination of radon concentrations and physicochemical parameters of non-alcoholic carbonated beverages consumed in Türkiye and assessment of radiological health risk.

The strategy for controlling the existence of radionuclides in drinking water depends upon an individual dose criterion (IDC) of 0.1 mSv/y, which represents a very low level of risk that is not expected to cause any identified adverse health effects. Radon gas, considered a carcinogenic radionuclide, can dissolve and accumulate in drinking water. Non-alcoholic carbonated beverages (NACBs), which mainly contain drinking water, phosphoric acid, citric acid, caffeine, and sugar, represent one of the most consumed groups worldwide and in Türkiye. In this study, the radon activity concentration and some physicochemical characteristics of 45 NACB samples from 24 most preferred commercial brands in Türkiye were determined to assess the radiological health risk associated with the ingestion of these samples. Radon activity concentrations measured in NACB samples using the AlphaGUARD radon analyzer ranged from 22.8 ± 0.7 to 54.9 ± 1.7 mBq/L. The pH, conductivity, total dissolved solids, and brix values in NACB samples ranged from 2.31 to 7.29, 401 to 3281 µSv/cm, 355 to 2453 mg/L, and 0.10 to 12.95%, respectively. Total (ingestion and inhalation) annual effective doses and the corresponding excess lifetime cancer risks estimated for adults to assess the radiological health risk are significantly below the IDC and advised safety limit (10-3), respectively.

Assessment of internal radiation exposure caused by radon in commercially bottled spring waters consumed in Turkey.

The variation of dissolved radon levels in water supplies remains of interest since radon ingested through drinking water can give considerable radiation to the lining of the stomach. This study aims to determine the radon concentration levels in bottled spring drinking water (BSW) brands commercially sold in Turkey using a radon gas monitor and to assess the internal radiation exposure caused by the ingestion and inhalation of radon. The activity concentrations of radon analyzed in 77 BSW brands varied from 7.1±0.8 to 28.7±2.7 mBq/L with an average of 15.7±5.1 mBq/L. The total annual effective dose was estimated to assess the radiological risk for three age groups in four different scenarios based on annual drinking water intake. All estimated dose values are well below the recommended reference dose of 100 µSv for drinking water. Therefore, radon gas in the investigated BSW samples poses no significant radiological risk to the public.

Evaluation of radiological health risk due to ingestion and inhalation of radon in commercial packaged fruit juices consumed in Turkey.

Fruit juices (FJs) are among the most popular beverages frequently preferred by consumers, believing FJs contain the nutritional values, minerals, phytochemicals, vitamins, and antioxidants necessary for a healthy life. However, FJs may contain natural radionuclides such as radon (222Rn), which originates from the fruit and water utilized in their production, at levels that may pose a health risk to people. Inhalation and ingestion of 222Rn gas increases the risk of lung and stomach cancer. In this study, commercially packaged FJs from the seventeen most popular brands consumed in Turkey were analyzed for physicochemical properties and 222Rn activity concentrations to evaluate the radiological health risk. The values of pH, brix and 222Rn activity concentrations in FJ samples varied from 2.68 to 4.28, 2.50 to 14.30%, 9.6 ± 1.1 to 25.2 ± 2.5 mBq/L, respectively. The radiological health risk caused by internal exposure was evaluated for children and adults by estimating the ingestion and inhalation annual effective dose. The average values of the total annual effective dose for children and adults were found as 0.039 µSv and 0.056 µSv, respectively, which are much lower than the recommended dose of 100 µSv for drinking water.

Heavy metal contamination and health risk evaluation of chestnut (Castanea sativa Miller) consumed in Turkey.

This study was performed to determine heavy metals and metalloids in twenty-eight chestnut (Castanea sativa Miller) samples consumed in Turkey by inductively coupled plasma optical emission spectrometry and evaluate health risks for humans through the consumption of chestnut samples. The concentrations of Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni and Zn analyzed in chestnut samples varied from 537 to 635, 608 to 5333, 347 to 972, 207 to 8619, 12,739 to 86,310, 278 to 7549, 8676 to 67,622, 1068 to 18,661 and 3625 to 12,876 µg/kg (dry weight), respectively. The concentrations of Cd and Pb were above the maximum limits determined by the Turkish Food Codex. Healthy risks caused by the heavy metals in the consumed chestnut samples were evaluated by estimating the average daily intake of metal, health risk index (HRI), and total HRI. These results revealed that there is no possible health risk to consumers due to the intake of chestnut samples studied under the current consumption rate.

Evaluation of terrestrial radionuclide levels and concomitant radiological risks of bentonites used in many industries.

Bentonite is a soft, porous, easily shaped, and absorbent material rich in aluminum, sodium, and potassium. Bentonite is a mineral widely utilized as drilling mud, ore pelletizing, absorbent/adsorbent, bleaching agent, water impedance, coating, and raw material in various industries. In this study, radiometric measurements of 90 bentonite samples collected from 21 quarries in Turkey were performed using gamma-ray spectrometry. The radiological hazards caused by indoor exposure to adults due to the utilization of bentonites as raw materials in the construction industry and outdoor external exposures to quarry workers were evaluated by estimating the activity concentration index, annual effective doses, and lifetime cancer risk. The average activity concentrations of 226Ra, 232Th and 40K measured in bentonite samples were found as (50 ± 5) Bq/kg, (76 ± 4) Bq/kg and (373 ± 19) Bq/kg, respectively. The evaluation results reveal that the bentonites examined could be safely utilized as raw materials.

Potentially toxic element contamination and health risk assessment in bottled mineral waters consumed in Turkey.

This study aimed to evaluate the human health risk posed by potentially toxic elements (PTEs) in 59 bottled mineral water (BMW) samples of 25 different brands marketed in Turkey. The concentrations of Ag, Al, As, Cd, Cr, Co, Cu, Fe, Mn, Ni, and Pb in the BMW samples were analyzed using an ICP-OES and compared with maximum allowable concentrations (MACs). A higher concentration of As than MAC was detected in five BMW samples. The concentrations of Cd, Pb, Cr, Ni, and Al in the majority of BMW samples are higher than the MACs. The human health risk was evaluated for adults estimating non-carcinogenic risk index (HI), incremental lifetime cancer risk (ILCR) and total cancer risk (TCR). All HI values estimated for PTEs in BMW samples are less than one, except for one sample. ILCR values for Cd in approximately half of the BMW samples are above the upper limit.

Natural Radionuclides in Bottled Mineral Waters Consumed in Turkey and Their Contribution to Radiation Dose.

Bottled natural mineral water (BMW) consumption in Turkey is increasing every year. Depending on the local geology from which the water is extracted, BMW could be enhanced with natural radionuclides. In this study, the activity concentrations of natural radionuclides in 58 BMW samples of 25 different brands marketed in Turkey were measured using a γ-ray spectrometer with high-purity germanium (HPGe) detector. The average activity concentrations of 226Ra, 228Ra, and 40K in BMW samples were found as 0.4, 0.5, and 4.3 Bq/L, respectively. The activity concentrations of 228Ra exceeded the WHO-recommended maximum permissible limit of 0.1 Bq/L for drinking water. The annual effective dose (AED) and excess lifetime cancer risk (LCR) caused by the ingestion of each BMW sample were estimated for adults to assess radiological risks using two different scenarios based on BMW consumption rates (150 and 13 L/y). All estimated total AEDs, except for two samples, were below the guidance dose level of 100 µSv/y recommended by the World Health Organization (WHO) and Turkish regulations for drinking water. For all BMW brands, 228Ra was found as the main contributor to the AEDs. The LCR values were lower than the acceptable value of 10-3 for radiological risks.

Assessment of the Enrichment of Heavy Metals in Coal and Its Combustion Residues.

Coal-fired thermal power plants remain one of the main sources of electricity generation in Turkey. Combustion of coal creates coal ash and slag, which are often stored in landfills located near residential and agricultural fields, increasing the potential for high environmental contamination and health risks. This study investigates the content and enrichment factor (EF) of heavy metals in pulverized lignite coal and its combustion residues from the Kangal lignite coal-fired thermal power plant situated in the Central Anatolian Region of Turkey. The concentration of heavy metals (Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Sr, Zr, Cd, Hg, and Pb) in lignite coal, slag, and fly ash samples were analyzed using an energy dispersive X-ray fluorescence technique. The concentration of Fe is highest while Hg concentration is lowest in the samples. The concentrations of heavy metals are higher in slag and fly ash samples than in lignite coal. Average values of EF (related to Earth's crust average) revealed that extreme enrichment has been shown by arsenic and mercury in lignite coal and fly ash samples while very high enrichment has been shown in slag samples.

Evaluation of natural radioactivity levels and potential radiological hazards of common building materials utilized in Mediterranean region, Turkey.

Radiometric measurement of building materials is very important to assess the internal and external exposure caused by the ionizing radiation emitted from terrestrial radionuclides in building materials. The activity concentrations of 226Ra, 232Th, and 40K in fifty-eight samples of fifteen different structural and covering building materials commonly used in Osmaniye province located in the Mediterranean region of Turkey were measured by using gamma-ray spectroscopy. The activity concentrations of 226Ra, 232Th, and 40K varied from 2.5 ± 0.1 (marble) to 145.7 ± 4.4 (clay brick), 1.3 ± 0.1 (marble) to 154.3 ± 4.1 (marble), and 8.6 ± 0.2 (sand) to 1044.1 ± 70.3 (granite), respectively. Radiological parameters (activity concentration index, alpha index, indoor absorbed gamma dose rate and the corresponding annual effective dose rate, and excess lifetime cancer risk) were estimated to evaluate the health hazards associated with these building materials. Since the estimated values of these parameters are within the recommended safety limits or criteria values, the use of the studied building materials in the construction of dwellings can be considered to be safe for the residents of the region.

BACKGROUND RADIATION MEASUREMENTS AND CANCER RISK ESTIMATES FOR SEBINKARAHISAR, TURKEY.

This paper presents the measurement results of environmental radioactivity levels for Sebinkarahisar district (uranium-thorium area), Giresun, Turkey. The radioactivity concentrations of 238U, 232Th, 40K and the fission product 137Cs in soil samples collected from 73 regions from the surroundings of the study area were determined. In situ measurements of the gamma dose rate in air were performed in the same 73 locations where the soil samples were collected using a portable NaI detector. Also the mean radioactivity concentrations of 238U, 232Th and 40K in rock samples collected from 50 regions were determined. The mean estimated cancer risk value was found. The seasonal variations of the indoor radon activity concentrations were determined in the 30 dwellings in the study area. In addition, the mean gross alpha, gross beta and radon activities in tap water samples were determined in the same 30 dwellings. The excess lifetime cancer risk was calculated using the risk factors of International Commission on Radiological Protection and Biological Effects of Ionizing Radiation. Radiological maps of the Sebinkarahisar region were composed using the results obtained from this study.