1.
Molecules
; 17(11): 13330-44, 2012 Nov 08.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23138536
RESUMO
An asymmetric Claisen rearrangement using Oppolzer’s camphorsultam was developed. Under thermal conditions, a geraniol-derived substrate underwent the rearrangement with good stereoselectivity. The absolute configuration of the newly formed all-carbon quaternary stereocenter was confirmed by the total synthesis of (+)-bakuchiol from the rearrangement product.