Electrocatalytic oxidation of aromatic amine (4-aminobiphenyl): Kinetics and transformation products with mechanistic approach.

Electrocatalytic oxidation (EO) of carcinogenic 4-aminobiphenyl (4-ABP) aromatic amine was performed using Ti-RuO2 anodes. Current (I), pH, electrolysis time (t), and 4-ABP initial concentration (Co ) were selected as EO parameters, and their effects on %4-ABP removal (R1 ) and energy consumed (R2 ) were studied. Experimental design, parameters optimization, and their interaction with responses R1 and R2 were performed using response surface methodology. At optimized parameters, %TOC removal and 4-BP mineralization current efficiency (%MCE) were assessed to evaluate the potential of Ti/RuO2 anodes towards 4-ABP mineralization. Simultaneous TOC and 4-ABP degradation kinetics were also studied to evaluate the competition in 4-ABP mineralization and degradation. Further, UPLC-Q-TOF-MS analysis was performed to identify the 4-ABP transformation products during the EO, and a mechanism describing the EO transformation was proposed. At optimum parameters (I = 1.2 A; pH = 4.0; t = 30 min; Co = 30 ppm), responses were found to be R1 = 60.25%; R2 = 2.49 kWh/g of 4-ABP removed. %TOC removal and %MCE were 52.4% and 34.2%, respectively. PRACTITIONER POINTS: 4-Aminobiphenyl electro-oxidation (EO) was explored using Ti/RuO2 anode. Achieved 34.2% mineralization current efficiency, 52.4% TOC and 61.3% TKN removal. Three electro-oxidation transformation products of 4-ABP were detected. 4-Aminobiphenyl was found degrading at ≈1.6 times higher rate than TOC A plausible EO transformation pathway and mechanism was proposed.

Deep eutectic solvent functionalized rice husk ash for effective adsorption of ofloxacin from aqueous environment.

Deep eutectic solvents (DESs) have achieved the rising attention of the scientific community because of their distinctive physicochemical properties and variety of applications. Herein, DES composed of choline chloride as hydrogen bond acceptor (HBA) and glycolic acid as hydrogen bond donor (HBD) was synthesized. Next, the prepared DES was examined as a functionalization agent for rice husk ash (RHA) to form a novel adsorbent (DES-RHA). To ensure the formation of DES and to recognize the modifications occurred due to the functionalization process, a comprehensive characterization study was performed using 1HNMR, FTIR spectroscopy, TGA, XRD, FESEM, HR-TEM and BET surface area. Potential of the prepared DES-RHA was investigated for the uptake of ofloxacin (OFL) from an aqueous environment. The impact of relevant process parameters was evaluated under optimum conditions, and the data were examined applying various kinetic and isotherm models. As per the regression findings, adsorption kinetics data were well described by pseudo-second-order model, and the isotherm data were in good agreement with Langmuir, Temkin, RP and Freundlich isotherm models. Further, the adsorption procedure was endothermic and spontaneous. The high regeneration and adsorption capacity of DES-RHA than untreated RHA adds a promising approach to eliminate emerging pollutants present in effluent sites.

Electro-oxidation of amoxicillin trihydrate in continuous reactor by Ti/RuO2 anode.

Electro-oxidation (EO) of synthetic wastewater containing amoxicillin (AMT) antibiotic as a model pollutant was performed using dimensionally stable Ti/RuO2 electrodes in a continuous reactor set-up. Response surface methodology (RSM) was used for optimization of continuous EO process. Individual and interactive effects of initial pH of synthetic wastewater (2-10), applied current, I (0.25-1.25 A), elapsed time, t (20-180 min) and retention time, RT (15-195 min) on AMT removal, total organic carbon (TOC) removal and specific energy consumption (SEC, kWh (g TOC removed)-1) were investigated. At optimum conditions (pH = 7.53, I = 0.7 A, RT = 175.6 min, t = 128.89 min), 51.64% and 37.82% AMT and TOC removal was achieved, with SEC value of 0.408 kWh (g TOC removed)-1. AMT and TOC removal at optimum conditions was found to follow pseudo-first order kinetics. Mineralization current efficiency for optimum run of continuous EO came out to be 9.81%. Furthermore, 8 transformation products/reaction intermediates of AMT (ARIs) were determined by UPLC-Q-TOF-MS analysis, and subsequently, a plausible degradation scheme of AMT by anodic oxidation and cathodic reduction using Ti/RuO2 electrodes was proposed.

Aromatic amines equilibrium sorptive interaction with synthesized silica based mesoporous MCM-41: Physicochemical evaluation and isotherm modeling.

Present study reports the adsorption of aromatic amine, 4-chloro-o-toluidine (4-COT), onto synthesized mesoporous Mobil Composition of Matter No. 41 (MCM-41) silica nanoparticles, in batch mode. Synthesized MCM-41 was characterized by XRD, BET, FTIR, SEM and TEM analysis. The effects of pH, MCM-41 dose, 4-COT concentration, contact time and temperature were studied, and interaction of 4-COT with the surface of MCM-41 and adsorption process controlling mechanism were investigated. BET analysis of MCM-41 showed 502.77 m2 g-1 of surface area. Kinetic experimental data were well represented by the pseudo-second order kinetic model. Freundlich and Temkin isotherm models well represented the adsorption equilibrium isotherm data.

Transformation products and degradation pathway of textile industry wastewater pollutants in Electro-Fenton process.

In this study, pollutants from textile industry wastewater were transformed/oxidized using Ti/RuO2 electrode by Electro-Fenton (EF) method in a continuous reactor. The performance was evaluated in terms of % COD removal, % color removal and energy consumed. Electrolysis time, retention time, current, and ferrous sulphate concentration as Fenton catalyst were selected as EF process parameters. To determine the optimum operating conditions multiple response optimization with desirability approach based on central composite design under response surface methodology was used. Spectrophotometric and GC-MS analysis were performed to identify the degraded/transformation compounds, and on this basis degradation mechanism during EF process as well as disposability of treated wastewater was analyzed. Further, bioassay test of treated textile wastewater was conducted for toxicity analysis in view of its disposal quality. Results showed that all the components of textile wastewater were totally eliminated/transformed in lower molecular weight compounds after EF treatment of textile effluent. Further, bioassay test analysis confirmed the nontoxic nature of treated wastewater.

Electrocatalytic oxidative treatment of real textile wastewater in continuous reactor: Degradation pathway and disposability study.

Electrocatalytic treatment of real textile wastewater was investigated in continuous electrochemical reactor using dimensionally stable Ti/RuO2 anode. Effects of various parameters such as: elapsed time, current, pH, retention time on the COD removal, color removal and specific energy consumed were evaluated. Central Composite Design under RSM was used for experimental design, data analysis, optimization, interaction analysis between the various electrochemical parameters and steady state time analysis. GC-MS and UV spectrophotometric analysis of the untreated and treated wastewater were conducted to identify the oxidized and transformed/degraded compounds during the oxidation process, and a suitable degradation mechanism was proposed. Treated wastewater may contain toxic chlorinated compounds due to mediated oxidation by various hydrolyzed chlorine species. Therefore, disposability of treated wastewater was assessed by conducting toxicity bioassay test. The optimal set of operating parameters were found to be elapsed time = 124 min, current = 1.37 A, pH = 5.54 and retention time = 157.6 min to simultaneously achieve COD removal, color removal and specific energy consumed as 86.22%, 94.74% and 0.012 kW h, respectively. GC-MS analysis showed presence of chlorinated compounds in the treated wastewater. The toxicity bioassay test resulted acute toxicity with 100% mortality rate within one minute and one hour exposure with untreated and treated textile wastewater, respectively.

Electro-oxidation of Ofloxacin antibiotic by dimensionally stable Ti/RuO2 anode: Evaluation and mechanistic approach.

Present study investigates the potential of Ti/RuO2 electrode for degradation and mineralization of Ofloxacin (OFLX) antibiotic from synthetic wastewater by electro-oxidation (EO) method, not reported earlier. Effects of various EO parameters such as applied current (I), initial pH, initial OFLX concentration (C0) and supporting electrolyte concentration on %OFLX removal efficiency and %TOC removal efficiency were systematically studied and reported. Decay kinetics of OFLX by varying C0 and applied I were also studied. Additionally, mineralization current efficiency and specific energy consumption of OFLX mineralization were evaluated. Moreover, mode of oxidation method involved (direct and/or indirect oxidation) was also explored. Major OFLX transformation products during EO were identified using UPLC-Q-TOF-MS, and possible degradation reaction mechanism was proposed. Furthermore, operating cost analysis was performed to check the economic feasibility of the EO process. The optimum pH and current (I) were found to be ≈6.8 (natural pH of OFLX wastewater) and 1 A, respectively. Mineralization current efficiency decreased from 7.8% to 4.9% with increase in I value from 0.25 to 1 A. ≈80% of OFLX removal in 30 min of electrolysis and 46.3% TOC removal in 240 min of electrolysis at I = 1 A were observed. Pseudo-first-order kinetic model best fitted the experimental data showing R2 value ≈ 0.99 for all the Co and applied I studied.

Electrochemical treatment of Reactive Black 5 textile wastewater: optimization, kinetics, and disposal study.

This research reports treatment of textile wastewater containing Reactive Black 5 (RB5) and other industrial constituents which are found in textile industry effluent, by the electrochemical treatment method using aluminum electrodes. Initial pH, current density (J), and electrolysis time (t) were selected as operational variables to observe the effects on chemical oxygen demand (COD) removal efficiency (Y1), dye removal efficiency (Y2), and specific energy consumed (Y3) (kWh/kg of COD removed). A response surface methodology (RSM) with full factorial central composite design (CCD) was used for designing and optimizing responses. To optimize the multiple responses, multi-response optimization with a desirability function were utilized for maximizing Y1 and Y2, and simultaneously minimizing Y3. To address issues of treated wastewater disposal, aluminum mass balance was performed. Electrocoagulation with subsequent adsorption, electro-floatation, and electro-oxidation were found to be the mechanism for removal of the pollutants.

An overview of various technologies for the treatment of dairy wastewaters.

Dairy industries have shown tremendous growth in size and number in most countries of the world. These industries discharge wastewater which is characterized by high chemical oxygen demand, biological oxygen demand, nutrients, and organic and inorganic contents. Such wastewaters, if discharged without proper treatment, severely pollute receiving water bodies. In this article, the various recent advancements in the treatment of dairy wastewater have been discussed and the areas where further research is needed have been identified.

Treatment of dairy wastewater by inorganic coagulants: Parametric and disposal studies.

Present study reports treatment of simulated dairy wastewater (SDW) by inorganic coagulants such as poly aluminum chloride (PAC), ferrous sulphate (FeSO(4)) and potash alum (KAl(SO(4))(2)·12H(2)O). Batch coagulation experiments were conducted to evaluate the influence of initial pH (pH(i): 5-10) and coagulant dosage (m: 100-5000 mg/L) on chemical oxygen demand (COD) removal from SDW. Residual COD and system pH were observed as function of time. Optimum pH(i) (pH(i,op)) was found to be 8.0 for all the three coagulants. Optimum m (m(op)) was found to be 300, 800 and 500 mg/L for PAC, FeSO(4) and KAl(SO(4))(2)·12H(2)O, respectively, giving 69.2, 66.5 and 63.8% COD removal efficiency in 30 min. Heating values of the sludge generated by the coagulants PAC, FeSO(4) and KAl(SO(4))(2)·12H(2)O were found to be 20.7, 29.6 and 17.3 MJ/kg, respectively.

Treatment of dairy wastewater by commercial activated carbon and bagasse fly ash: Parametric, kinetic and equilibrium modelling, disposal studies.

Present study reports treatment of synthetic dairy wastewater (SDW) in terms of chemical oxygen demand (COD) removal by means of adsorption onto activated carbon-commercial grade (ACC) and bagasse fly ash (BFA). Optimum conditions for SDW treatment were found to be: initial pH approximately 4.8, adsorbent dose of 20g/l for ACC and 10g/l for BFA and contact time approximately 8h. Pseudo-second-order kinetic model was found to fit the kinetic data and Redlich-Peterson isotherm model was generally found to best represent the equilibrium data for SDW treatment by ACC and BFA. The change in entropy and enthalpy for SDW adsorption onto ACC and BFA were estimated as 125.85kJ/molK and 91.53kJ/mol; and 25.71kJ/molK and 17.26kJ/mol, respectively. The negative values of change in Gibbs free energy indicate the feasibility and spontaneous nature of the adsorptive treatment.