Effect of chitosan coating on basil (Ocimum sanctum) leaves dried by microwave-assisted drying method: Analysis of color, effective moisture diffusivity, and drying kinetics.

Basil (Ocimum sanctum) leaves, commonly known as holy basil, have various health benefits due to their rich phytochemical content. However, fresh basil leaves face challenges related to their perishability and short shelf life. This study explores the use of edible coating, specifically chitosan, to extend the shelf life of basil leaves. Then basil leaves with chitosan coating were dried using microwave-assisted drying (MAD) method with variations of microwave power (136, 264, 440, and 616 W), mass of basil leaves (5, 10, and 15 g), and chitosan concentration (0, 2.5, and 5 %). The purpose of this study is to analyze the color, effective moisture diffusivity, and drying kinetics. Five mathematical models and seven error functions were used. The Avhad and Marchetti Model was identified as the most suitable model to describe the drying kinetics of basil leaves with chitosan coating. The Deff value increased with decreasing mass of basil leaves, decreasing chitosan concentration, and increasing microwave power. Deff values ranged from 0.001 to 0.002 m2/s. The thickness of the basil leaves also played a role in the fluctuation of Deff values. The highest ΔE value was obtained by 5 % concentration of chitosan. The chitosan coating, especially at a concentration of 2.5 %, showed discoloration indicating better preservation of the original color of basil leaves. In conclusion, this study shows that chitosan coating and MAD are effective strategies to extend the shelf life of basil leaves and can provide valuable insights for future applications in leaf drying or thin layer drying processes.

A critical review and bibliometric analysis of methylene blue adsorption using leaves.

The rapid development of the industrial world causes wastewater containing dyes to continue to increase. Even in recent years, the food, textile, cosmetic, plastic, and printing industries have developed the use of dyes. Methylene blue (MB) is one of the cationic dyes widely used in dyeing silk, wood, and cotton because of its absorbency and good fastness to materials. The adsorption process is the best technique and preferred in removing dyes from wastewater due to excellent selectivity, high efficiency from high-quality treated effluent, flexibility in design, and simplicity. Therefore, there is a growing interest to identify low-cost alternative adsorbents that have reasonable adsorption efficiency, especially natural materials such as leaves. In this study, research on MB adsorption using leaves was analyzed using bibliometric analysis. Information of bibliometric is extracted from the Scopus database with the keyword "Methylene Blue", "Adsorption or Desorption", and "Leaves or leaf". The results showed that India, Desalination and Water Treatment, and SASTRA Deemed University were the country, journal, and institution that contributed the most publications on this topic. Therefore, it is expected that with the use of bibliometrics, the use of leaf-based MB adsorption processes in their potential for MB dye removal can be investigated especially for large-scale development.

A comprehensive review of recent advances in the applications and biosynthesis of oxalic acid from bio-derived substrates.

Organic acids are important compounds with numerous applications in different industries. This work presents a comprehensive review of the biological synthesis of oxalic acid, an important organic acid with many industrial applications. Due to its important applications in pharmaceuticals, textiles, metal recovery, and chemical and metallurgical industries, the global demand for oxalic acid has increased. As a result, there is an increasing need to develop more environmentally friendly and economically attractive alternatives to chemical synthesis methods, which has led to an increased focus on microbial fermentation processes. This review discusses the specific strategies for microbial production of oxalic acid, focusing on the benefits of using bio-derived substrates to improve the economics of the process and promote a circular economy in comparison with chemical synthesis. This review provides a comprehensive analysis of the various fermentation methods, fermenting microorganisms, and the biochemistry of oxalic acid production. It also highlights key sustainability challenges and considerations related to oxalic acid biosynthesis, providing important direction for further research. By providing and critically analyzing the most recent information in the literature, this review serves as a comprehensive resource for understanding the biosynthesis of oxalic acid, addressing critical research gaps, and future advances in the field.

Trends on adsorption of lead (Pb) using water hyacinth: Bibliometric evaluation of Scopus database.

Heavy metals (Cd, Ni, Zn, Cu, Cr, and Pb) are widely recognized as being hazardous to human health and environmentally deleterious. Therefore water hyacinth is used as a greener adsorption material. This study is a bibliometric analysis of research developments on the adsorption of lead (Pb) using water hyacinth (1995-2023). The data was retrieved from the Scopus database and analyzed using VOSviewer software to determine the relationship between keywords from each published document. The results of this research was divided into three parts: 1) publication output, 2) global research, and 3) keyword research. From the data obtained, it was found that there has been an increasing research trend of adsorption of lead using water hyacinth, although it is not significant and fluctuating. Overall, this study can be used by researchers to quantitatively assess trends and future directions of this research topic.

Reflections on food security and smart packaging.

Estimating the number of COVID-19 cases in 2020 exacerbated the food contamination and food supply issues. These problems make consumers more concerned about food and the need to access accurate information on food quality. One of the main methods for preserving the quality of food commodities for export, storage, and finished products is food packaging itself. In the food industry, food packaging has a significant role in the food supply which acts as a barrier against unwanted substances and preserves the quality of the food. Meanwhile, packaging waste can also harm the environment; namely, it can become waste in waterways or become garbage that accumulates because it is nonrenewable and nonbiodegradable. The problem of contaminated food caused by product packaging is also severe. Therefore, to overcome these challenges of safety, environmental impact, and sustainability, the role of food packaging becomes very important and urgent. In this review, the authors will discuss in more detail about new technologies applied in the food industry related to packaging issues to advance the utilization of Smart Packaging and Active Packaging.

Bioenergy revamping and complimenting the global environmental legal framework on the reduction of waste materials: A facile review.

The challenges posed by climate change/global warming are very alarming, and they have become the focal point of attention for researchers within the global environmental domains. The development of bioenergy can help salvage this situation as a renewable energy source that makes use of recycled waste materials to create useful energy products. This review study found that the development of sustainable bioenergy is environmentally friendly, and it has been proven to be a better means of recycling waste materials into final energy products for sustainable development. The study hereby concluded and recommended that environmental policies concerning the sustainable development of bioenergy should be adopted within the various nations' local laws and the global environment at large, as this will result in adhering strictly to international environmental legal frameworks regulating the prevention and reduction of waste materials. The possible correlation of bioenergy with the Sustainable Development Goals is also highlighted.

Greenhouse Gas Emission: Perception during the COVID-19 Pandemic.

The period 2020/2021 was an unprecedented and historic time for industrial, economic, and societal activities all over the world with great challenges to human health, the ecosystems, and other aspects of human endeavors owing to the COVID-19 or SARS-CoV-2 (CV-19) pandemic which is now a topical aspect of research interest. Despite the negative impacts of the CV-19 pandemic, there are also positive reports during the CV-19 pandemic such as the reduction of gas flare, reduction in the burning of fossil fuels from automobile exhaust and a reduction in the other ensuing factors of greenhouse gases emissions (which is one of the major drives for global warming and climate change as well as other environmental effluences). Hence, this brief perspective review study is centered on greenhouse gas (GHG) emission. The study employs a methodical approach to analyze some already available research studies from existing publications and databases on GHG emission using the perception during the CV-19 pandemic. The specific findings from this review show that, from the meteorological perspective, the global response to the catastrophe ensuing from the CV-19 pandemic has a great influence on the reduction of GHGs, the reduction in the burning of fossil fuels from automobiles and industrial devices, and the reduction in the other ensuing factors of GHG emission. Hence, it will not be far from the truth to conclude that there is a possible positive connection between the CV-19 pandemic and GHG emissions. The study has a direct impact on the environment owing to the negative and positive environmental consequences of the CV-19 pandemic. Suggestions and recommendations in the form of future prospects of GHG emission vis-à-vis global warming and climate change are also discussed. Furthermore, suggestions on how to improve food security and agriculture during a pandemic such as the CV-19 outbreak period are highlighted.

Techno-economics of coconut coir bioadsorbent utilization on free fatty acid level reduction in crude palm oil.

The quality of crude palm oil (CPO) is generally determined by the levels of free fatty acids (FFA). This helps in balancing the level of acidity during transportation and storage processes. However, high FFA in CPO is not good for consumer health. One of the methods for adsorbing FFA is adsorption, which is the adhesion of atoms, ions, or molecules from a gas, liquid, or dissolved solid to a surface. Therefore, this study aims to analyze the effect of contact time (40, 80 and 120 min) and Coconut Coir (CC) bioadsorbent concentrations of 1, 2 and 3 (%, w/v) on the reduction of CPO FFA levels. This began with the activation of CC biochar synthesis by using NaOH and HCl, which produced CC-NaOH and CC-HCl bioadsorbents based on the product of NaOH. Furthermore, the adsorption process was carried out by mixing CPO with CC-NaOH and CC-HCl bioadsorbents in a three-necked flask. After this, the filtrate product was obtained and analyzed for its FFA levels. The results showed that the largest percentage reduction for the effect of bioadsorbent concentration was 3% (w/v) at a contact time of 120 min. It also indicated that this study enabled lower levels of FFA in CPO. Based on the detailed cost estimate, the production cost of the CC-NaOH bioadsorbent was USD 481,874, sold at USD 95/ton with annual sales and net profit (after tax) at USD 684,000 and USD 141,188, respectively. This profit after tax and rate of return on investment was found to be 20.68 and 39.49% of the entire estimation, respectively. It also had a payback period of 2.95 years and a break-even point at a capacity of 43.16%. In addition, the prepared adsorbent showed significant ability as an inexpensive, reproducible and environmentally friendly compound used in reducing the FFA levels of CPO.

A Methodical Review on the Applications and Potentialities of Using Nanobiosensors for Disease Diagnosis.

Presently, with the introduction of nanotechnology, the evolutions and applications of biosensors and/or nanobiosensors are becoming prevalent in various scientific domains such as environmental and agricultural sciences as well as biomedical, clinical, and healthcare sciences. Trends in these aspects have led to the discovery of various biosensors/nanobiosensors with their tremendous benefits to mankind. The characteristics of the various biosensors/nanobiosensors are primarily based on the nature of nanomaterials/nanoparticles employed in the sensing mechanisms. In the last few years, the identification, as well as the detection of biological markers linked with any form of diseases (communicable or noncommunicable), has been accomplished by several sensing procedures using nanotechnology vis-à-vis biosensors/nanobiosensors. Hence, this study employs a systematic approach in reviewing some contemporary developed exceedingly sensitive nanobiosensors alongside their biomedical, clinical, or/and healthcare applications as well as their potentialities, specifically for the detection of some deadly diseases drawn from some of the recent publications. Ways forward in the form of future trends that will advance creative innovations of the potentialities of nanobiosensors for biomedical, clinical, or/and healthcare applications particularly for disease diagnosis are also highlighted.

Hydroxyapatite-based adsorbents: Applications in sequestering heavy metals and dyes.

Hydroxyapatite (HAp) is a calcium phosphate material that was used primarily in bone regeneration and repair as a result of its chemical similarity with bone. However, HAp has emerged as a very promising adsorbent for sequestering contaminants like heavy metals, dyes, hydrocarbons as well as other emerging pollutants from wastewater as a result of its versatility and encouraging adsorptive properties. Contaminants like heavy metals and dyes have been a major source of environmental concern. Research studies involving the use of HAp as adsorbents for the adsorptive treatment of heavy metal- and dye-contaminated wastewater have become increasingly popular due to its eco-friendliness, easy synthesis, unique adsorption properties etc. Various methods are available for the synthesis of HAp and its composites with some of these methods used in combination with other methods to obtain more efficient HAp-based adsorbents. In this work, the adsorptive removal of heavy metals and dyes by HAp and its composites was extensively reviewed as well as the parametric effects of process factors like contact time, solution pH, temperature, solute concentration etc on the adsorption process. Kinetic, thermodynamic, and isotherm models for elucidating the adsorption process were also considered. Generally, from the works reviewed, HAp-based adsorbents were found to be very effective for sequestering heavy metals and dyes from solution and thus presents a low-cost option for adsorptive wastewater treatment.

Analysis of bentonite performance on the quality of refined crude palm oil's color, free fatty acid and carotene: the effect of bentonite concentration and contact time.

The quality of crude palm oil (CPO) must be maintained since it plays an important role in fulfilling the domestic and global needs (food and non-food). The quality of CPO is determined by the color, Free Fatty Acid (FFA) and carotene. This study was aimed at examining the effect of bentonite concentration (1.5, 2.0, 2.5 and 3.0%) and contact time (15, 30, 45 and 60 min) on the quality of crude palm oil. The refining processes of CPO through degumming, bleaching and distillation were carried out before the analysis on color, FFA and carotene was done. The results showed that the effect of bentonite concentration (1.5, 2.0, 2.5 and 3.0%) experienced the highest percentage in reduction at 3.0% (color 88.7%, FFA 2.99% and carotene 56.37%). Meanwhile, the effect of contact time (15, 30, 45 and 60 min) experienced the highest percentage in reduction at 60 min (color 89.58%, FFA 2.38%, carotene 61.32%). The reduction in the CPO's color, FFA and carotene found in this study indicates that bentonite concentration and contact time are proven to be effective methods for CPO refinery based on the standard set by Malaysian Palm Oil Refiners Association. This study also showed that the removal efficiency and adsorption capacity of FFA and carotene were also affected by contact time and bentonite concentration.

Techno-economic analysis of bio-briquette from cashew nut shell waste.

The implementation of this research consists of 2 (two) aspects: the making and testing of bio-briquettes called technological aspects and economic analysis called economic aspects. Bio-briquettes is made from cashew nutshell waste obtained from Southeast Sulawesi, Indonesia. It is followed by pyrolysis, which is carried out in a simple batch type reactor by heating using liquefied petroleum gas (LPG). The bio-briquettes product has a calorific value of 29.49 MJ/kg, moisture content of 5.3%, ash content of 4.96%, volatile substances content of 17.16%, and carbon content of 72.62%, which meets the universally accepted bio-briquettes standard (SNI 016235-2000), Japanese, English and ISO 17225. The bio-briquettes product is suitable as an energy source. The economic analysis of the cashew nutshell was analyzed to determine its economic feasibility. For the bio-briquettes production capacity in 2,000 tons/year, cashew nut shell-briquettes products can be sold at 1,052,878 USD/year. The total production cost is USD842,304/year. The net profit is of USD147,402/year. The cost of LPG for 2,000 tons/year production capacity is USD954,358/years. The replacement of LPG with cashew seed bio-briquettes tends to help the average household of Muna Regency community to reduce the annual cost by 37.00%. In conclusion, bio-briquettes production's economic feasibility as analyzed from the investment rate is 23.55%, payout time is 3.42 years, and break-even point is 50.09%.

Characterization, kinetic, and isotherm data for Cr(VI) removal from aqueous solution by Cr(VI)-imprinted poly(4-VP-co-MMA) supported on activated Indonesia (Ende-Flores) natural zeolite structure.

The adsorption performance of Cr(VI) on the Cr(VI)-imprinted poly(4-VP-co-MMA) (IIP) supported on Activated Indonesia (Ende-Flores) natural zeolite (ANZ) structure for Cr(VI) removal from aqueous solution have been studied. Cr(VI)-imprinted-poly(4-VP-co-MMA)-ANZ (IIP-ANZ) was synthesized using Cr(VI) as a template, 4-vinylphiridine (4-VP) as a complex agent, methyl methacrylate (MMA) as a monomer agent, ethylene glycol dimethylacrylate (EGDMA) as cross-linker and benzoyl peroxide (BPO) as an initiator. XRD, FTIR, SEM-EDX and BET was performed to characterize the synthesized materials. The maximum adsorption capacity was 2.431 mg/g adsorbent at pH 2, contact time of 30 min, under 303 K respectively. Five kinetic and four isotherm models were used to find out the reaction rate of Cr(VI) adsorption processes on this adsorbent. Under the competitive condition, the adsorption capacity of this adsorbent for Cr(VI) is greater than Cr(III), Mn(II) or Ni(II) ions but it less selective if present of Pb(II) ion. Moreover, the reusability of the IIP-ANZ was tested for five times and no significant loss in adsorption capacity observed.

Characterization, isotherm, and thermodynamic data for selective adsorption of Cr(VI) from aqueous solution by Indonesia (Ende-Flores) natural zeolite Cr(VI)-imprinted-poly(4-VP-co-EGDMA)-ANZ (IIP-ANZ).

In this paper, we report for the first time modification of Indonesia (Ende-Flores) natural zeolite Cr(VI)-imprinted-poly(4-VP-co-EGDMA)-ANZ (IIP-ANZ) as a selective adsorbent for Cr(VI) from aqueous solution. The IIP-ANZ was synthesized from Cr(VI) as a template, 4-vinylphiridine (4-VP) as complex agent and as functional monomer, ethylene glycol dimethyl acrylate (EGDMA) as a cross-linker agent, benzoyl peroxide (BPO) as initiator and ethanol/acetone as a porogen. The optimization adsorption parameters optimization such as adsorbent amount, initial pH of sample solution, contact time and temperature were studied. The maximum adsorption capacity was 4.210 mg/g adsorbent. The adsorption process follow Freundlich isotherm model. Under the competitive condition, the adsorption capacity of IIP-ANZ for Cr(VI) is higher than Pb(II), Mn(II), NI(II) and Cr(III). Moreover, the reusability of the IIP-ANZ particle was tested for five times and no significant loss in adsorption capacity observed.

Characterization of a mixture of algae waste-bentonite used as adsorbent for the removal of Pb2+ from aqueous solution.

The usage of wastes of algae would be admirable from environmental and solid waste management point of view. Thus, herein, this data set present a facile method for providing an adsorbent from mixture of algae waste-bentonite. The prepared adsorbent was applied to remove Pb2+ from aqueous solution. The characterization data of the adsorbent were analyzed using FTIR and SEM-EDX methods. The FTIR test results showed that there is a shift in the wave numbers on the adsorbent that has been loaded with Pb indicating that there is an interaction between the adsorbent and Pb. The SEM-EDX test results showed that there is Pb on the adsorbent that has been loaded with Pb. It was conducted in laboratory scale and the adsorption technique was batch technique. The acquired data indicated that the adsorption of Pb2+ by the adsorbent prepared from mixture of algae waste-bentonite is a promising technique for treating Pb-bearing wastewaters.

Characterization, kinetic, and isotherm data for adsorption of Pb2+ from aqueous solution by adsorbent from mixture of bagasse-bentonite.

The usage of wastes of bagasse would be admirable from environmental and solid waste management point of view. Thus, herein, this data set present a facile method for providing an adsorbent from mixture of bagasse-bentonite. The prepared adsorbent was applied to remove Pb2+ from aqueous solution. It was conducted in laboratory scale using completely randomized design with variations in mixed mass ratio (1:0, 1:1, 1:2, 1:3, 2:1, 3:1), pH (2, 3, 4, 5, 6, 7) and contact time (5, 10, 30, 45, 90, 120, 180 min) and the adsorption technique was batch technique. The mixed adsorbent with 3:1 of mass ratio provided the highest Pb2+ adsorption efficiency of 97.31%. The optimum pH of Pb2+ adsorption was 5 and contact time was efficient at 45 min giving adsorption efficiency of 94.76% and 93.38%. The characterization data of the adsorbent were analyzed using XRF and FTIR methods. The XRF test results showed the changes of elemental content in adsorbent after the adsorption indicated that adsorbent can absorb Pb2+. The FTIR test results showed that adsorbent has a functional group that is useful in adsorption process. Adsorption of Pb2+ by adsorbent from mixture of bagasse-bentonite follows pseudo second order model with correlation coefficient value of 99.99% (R2 = 0.9999) and Freundlich isotherm model with correlation coefficient value of 90.05% (R2 = 0.9005). The acquired data indicated that the adsorption of Pb2+ by the adsorbent prepared from mixture of bagasse-bentonite is a promising technique for treating Pb-bearing wastewaters.

Characterization and isotherm data for adsorption of Cd2+ from aqueous solution by adsorbent from mixture of bagasse-bentonite.

The usage of wastes of baggase would be admirable from environmental and solid waste management point of view. Thus, herein, this data set present a facile method for providing an adsorbent from mixture of bagasse-bentonite. The prepared adsorbent was applied to remove Cd2+ from aqueous solution. The characterization data of the adsorbent were analyzed using XRF and FTIR methods. The XRF test results showed the changes of elemental content in adsorbent after the adsorption indicated that adsorbent can absorb Cd2+. The FTIR test results showed that adsorbent has a functional group that is useful in adsorption process. It was conducted in laboratory scale and the adsorption technique was batch technique. The information regarding isotherms of cadmium ions adsorption were listed. The Langmuir isotherm was suitable for correlation of equilibrium data. The acquired data indicated that the adsorption of Cd2+ by the adsorbent prepared from mixture of bagasse-bentonite is a promising technique for treating Cd-bearing wastewaters.