1.
J Org Chem
; 83(22): 13854-13860, 2018 11 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30299099
RESUMO
A highly efficient method of visible light mediated Ni(II)-catalyzed photoredox N-arylation of Cbz-amines/Boc-amines with aryl electrophiles at room temperature is reported. The methodology provides a common access to a wide variety of N-aromatic and N-heteroaromatic carbamate products that find use in the synthesis of several biologically active molecules and provides a distinct advantage over traditional palladium-catalyzed Buchwald reaction.