A fluidized-bed reactor for the photocatalytic mineralization of phenol on TiO2-coated silica gel.

TiO2 photocatalysis represents a promising class of oxidation techniques that are intended to be both supplementary and complementary to the conventional approaches for the removal of refractory and trace organic contaminants in water and air. Powdered TiO2 dispersion systems employed in most studies require an additional separation step to recover the catalyst from the effluent water, which represents a major drawback for large scale applications. The optimization of photocatalytic treatment systems involves merging the benefits of catalyst immobilization on a retainable support, thus eliminating the need for downstream catalyst separation, maximization of photon-exposed catalyst area, and continuous operation. Aiming to integrate such conditions into a single system, a bench-scale annular photo-reactor with concentric UV-C lamp was built to study the photocatalytic mineralization of phenol on fluidized silica gel beads coated with sol-gel-synthetized TiO2. Reactor efficiency was investigated for different silica particle diameters (224, 357 and 461 µm), fluidized-bed concentrations in the bulk liquid (5, 10, 20 and 30 g L-1), initial phenol concentrations in the aqueous solution (0.25 mmol L-1 to 4.0 mmol L-1), and single and multiple sol-gel depositions. Then, the resulting optimum reactor configuration was compared to that of the same process on suspended Degussa P25 TiO2 nanoparticles under similar experimental conditions. The latter is expected to be more efficient, but post-treatment catalyst recovery, being an energy intensive process, represents a major limitation for large scale applications. Process efficiency was measured as a function of the accumulated energy necessary for the mineralization of 50% of the initial dissolved chemical oxygen demand (COD), or, Q0.5. Results showed that for any given mass of fluidized bed material, photo-oxidation efficiency increases with decreasing particle size (even for bed concentrations with similar equivalent surface area), decreasing initial phenol concentrations, and increasing number of sol-gel coatings. It was found that, for any given particle size and contaminant mass, there is an optimum bed concentration of 20 g L-1 for which Q0.5 reaches a minimum. Finally, under the optimum configuration, the fluidized-bed reactor efficiency is only 30% lower than that of photocatalysis on suspended TiO2 nanopowder, thus making the proposed fluidized system a viable alternative to slurry-TiO2 reactors.

Simultaneous removal of oil and grease, and heavy metals from artificial bilge water using electro-coagulation/flotation.

US and international regulations pertaining to the control of bilge water discharges from ships have concentrated their attention to the levels of oil and grease rather than to the heavy metal concentrations. The consensus is that any discharge of bilge water (and oily water emulsion within 12 nautical miles from the nearest land cannot exceed 15 parts per million (ppm). Since there is no specific regulation for metal pollutants under the bilge water section, reference standards regulating heavy metal concentrations are taken from the ambient water quality criteria to protect aquatic life. The research herein presented discusses electro-coagulation (EC) as a method to treat bilge water, with a focus on oily emulsions and heavy metals (copper, nickel and zinc) removal efficiency. Experiments were run using a continuous flow reactor, manufactured by Ecolotron, Inc., and a synthetic emulsion as artificial bilge water. The synthetic emulsion contained 5000 mg/L of oil and grease, 5 mg/L of copper, 1.5 mg/L of nickel, and 2.5 mg/l of zinc. The experimental results demonstrate that EC is very efficient in removing oil and grease. For oil and grease removal, the best treatment and cost efficiency was obtained when using a combination of carbon steel and aluminum electrodes, at a detention time less than one minute, a flow rate of 1 L/min and 0.6 A/cm(2) of current density. The final effluent oil and grease concentration, before filtration, was always less than 10 mg/L. For heavy metal removal, the combination of aluminum and carbon steel electrodes, flow rate of 1 L/min, effluent recycling, and 7.5 amps produced 99% zinc removal efficiency. Copper and nickel are harder to remove, and a removal efficiency of 70% was achieved.

Effect of operational parameters on the removal of particulate chemical oxygen demand in the activated sludge process.

The removal of particulate material in the aeration basin of the activated sludge process is mainly attributed to bioflocculation and hydrolysis of particulate substrate. The bioflocculation process in the aeration tank of the activated sludge process occurs only under favorable conditions in the system, and several common operational parameters affect its performance. The principal objective of this research was to observe the effect of mixed liquor suspended solids, solids retention time (SRT), and extracellular polymer substances on the removal of particulate substrate by bioflocculation. A first-order particulate removal expression, based on flocculation, accurately described the removal rates for supernatant suspended solids and colloidal chemical oxygen demand. Based on the results presented in this investigation, a mixed liquor concentration of approximately 2200 mg/L, an SRT of at least 3 days, and a contact time of 30 minutes are needed for relatively complete removal of the particulate substrate in a plug-flow reactor.

Kinetics of particulate organic matter removal as a response to bioflocculation in aerobic biofilm reactors.

Recent research has identified that the major fraction of chemical oxygen demand in domestic wastewaters is in particulate form. The research presented herein develops the kinetics of particle removal as a response to bioflocculation at the surface of aerobic biofilms. This study focuses on the removal of particles that are maintained in aqueous suspension after 30 minutes of gravity settling. It is helpful to consider the particulate organics removal process in biofilms as the sum of four steps, namely (1) external transport of the particles to the biofilm surface, (2) bioflocculation, (3) organic particulate hydrolysis, and (4) diffusion and reaction of the solubilized organics by the bacterial cells comprising the biofilm. Organic (native corn starch) and inorganic particle (Min-U-Sil 10 [U.S. Silica Company, Berkeley Springs, West Virginia]) suspensions, with micronutrients, were continuously fed to a rotating disc biofilm reactor to verify a first-order kinetic expression that has been used to describe bioflocculation and to demonstrate that bioflocculation is the primary particle removal mechanism. Extracellular polymeric substances were extracted and quantified to describe the role they play in the bioflocculation process.

Kinetics of removal of particulate chemical oxygen demand in the activated-sludge process.

The existing theories incorporated to state-of-the-art, activated-sludge-consensus models indicate that the removal of particulate substrate from the liquid in the activated-sludge process is a two-step process: instantaneous enmeshment of particles and hydrolysis followed by oxidation. However, experimental observations indicate that the removal of particles is not instantaneous and needs a more accurate description. This removal process can actually be described as a three-step process: flocculation, hydrolysis, and oxidation. The principal objective of this research was to observe and model the kinetics of the removal of suspended particles and colloidal particles. A first-order, particulate-removal expression, based on flocculation, accurately described the removal rates for supernatant suspended solids and colloidal chemical oxygen demand (COD). The rate of reaction for removal of colloidal COD was slow and comparable to that for soluble organic matter.

Manejo de la calidad ambiental por medio de instrumentos de mercado

Propone un sistema de control ambiental basado en los instrumentos económicos mas utilizados en política ambiental.Los principios de estos instrumentos son el de "Ordenar y Controlar", basado en leyes y reglamentos ambientales, y el de "Quien contamina paga", y ambos son analizados a lo largo del trabajo.Tambien se describen los principios y objetivos ambientales que debe tener un país, las estrategias para alcanzarlos, y la manera de desarrollar nuevas reglamentaciones ambientales