Scott Blair Fractional-Type Viscoelastic Behavior of Thermoplastic Polyurethane.

In this paper, the experimental characterization of the viscoelastic properties of thermoplastic polyurethane (TPU) samples through creep experiments is presented. Experiments were conducted at different constant temperature levels (15, 25, and 35 ∘C), for three different tensile stress levels (0.3, 0.5, and 0.7 MPa), and at different physisorbed water contents, providing access to: (i) the temperature dependency of creep parameters and (ii) the assessment, if behavior is indeed viscoelastic. The physisorbed water content was achieved by exposing virgin samples to environments with relative humidity ranging from 0 to 80 percent until mass stability was reached. Creep tests were conducted immediately afterwards with this particular humidity level. The main results of this study are as follows. The temperature dependency of the obtained creep parameters is well described in Arrhenius plots. With regard to water content, two prototype material responses were observed in the experimental program and accurately modeled using the following fractional-type models: (i) Scott Blair-type (i.e., power-law-type) only behavior, pronounced for the combination of low water content/low temperature; (ii) combined Scott Blair plus Lomnitz (i.e., log-type) behavior for high water content/high temperature. This change in behavior associated with certain thresholds for the specified environmental conditions (temperature and relative humidity) may indicate the initiation of hydrogen bond breakage and rearrangement (carbamate H-bonds and physisorbed water H-bonds). Regarding the short-term or quasi-instantaneous behavior, the Scott Blair element seems highly appropriate and may be better suited than the standard elastic model: the Hookean spring. We associated Scott Blair behavior with the load-induced, quasi-instantaneous re-arrangement of polymer network chains. The secondary viscoelastic mechanism associated with the Lomnitz element, hydrogen bond breakage and rearrangement, comes into play for higher temperatures and/or higher physisorbed water contents. In this case, the contribution of the two constitutive elements is well separated due to the large number of the characteristic time of the Lomnitz element, much larger than the respective value for the Scott Blair element.

Porous Talcum-Based Steatite Ceramics Fabricated by the Admixture of Organic Particles: Experimental Characterization and Effective Medium/Field Modeling of Thermo-Mechanical Properties.

In this paper, an experimental campaign, as regards the thermo-mechanical properties (heat capacity, thermal conductivity, Young's modulus, and tensile (bending) strength) of talcum-based steatite ceramics with artificially introduced porosity, is presented. The latter has been created by adding various amounts of an organic pore-forming agent, almond shell granulate, prior to compaction and sintering of the green bodies. The so-obtained porosity-dependent material parameters have been represented by homogenization schemes from effective medium/effective field theory. As regards the latter, thermal conductivity and elastic properties are well described by the self-consistent estimate, with effective material properties scaling in a linear manner with porosity, with the latter in the range of 1.5 vol-%, representing the intrinsic porosity of the ceramic material, to 30 vol-% in this study. On the other hand, strength properties are, due to the localization of the failure mechanism in the quasi-brittle material, characterized by a higher-order power-law dependency on porosity.

Application of Hyperspectral Imaging for identification of aging state of Styrene-Butadiene-Styrene.

In the context of the circular economy, the sorting process during recycling of polymers is essential as regards the efficiency of the process itself and the quality of the so-obtained recycled materials. In this paper, the application of Hyperspectral Imaging (HSI) is proposed for this purpose, providing additional insight into the state of aging and the polymer quality. The underlying study comprises HSI in the wavelength range of 1115-1678 nm considering artificially aged Styrene-Butadiene-Styrene (SBS), where aging is performed for 2, 5, 10, 15 and 20 days in a forced-draft oven at a temperature of 105 °C. The obtained HSI spectra are normalized using the Standard Normal Variate (SNV) method, with the normalized spectra as well as their first and second derivative entering the modeling attempt for SBS aging. For the latter, different partial least squares regression (PLSR) models are evaluated, where the original spectra achieved a correlation of R2=0.94 and a root mean squared error of prediction (RMSEP) of 1.83 days, showing the suitability of HSI for the proper identification of the state of aging of SBS and its potential use for other polymers.

Effect of Different Bearing Ratios on the Friction between Ultrahigh Molecular Weight Polyethylene Ski Bases and Snow.

The purpose of this study was to analyze the effect of surfaces with different bearing ratios, but similar roughness heights, on the friction between ultrahigh molecular weight polyethylene (UHMWPE) and snow. On a linear tribometer positioned inside a cold chamber, the different samples were tested over a wide range of velocities and snow temperatures. The surface roughness was measured with a focus variation microscope and analyzed using the bearing ratio curve and its parameters. The surface energy was investigated by measuring the contact angles of a polar (water) and nonpolar (diiodmethane) liquid. The friction tests showed that the bearing ratio had a major effect on the friction between UHMWPE and snow. For temperatures close to the melting point a surface with wide grooves and narrow plateaus (nonbearing surface) performed well. For cold conditions, the friction was less for a surface with narrow grooves and wide plateaus (bearing surface). Interpretations of the results are given on the basis of mixed friction, with lubricated friction being dominant at higher snow temperatures and solid-solid interaction at lower ones.