Dataset on onshore groundwaters and offshore submarine spring of a Mediterranean karst aquifer during flow reversal and saltwater intrusion.

Groundwater from various shallow and deep reservoirs converges in interaction with marine waters into the limestone aquifer of the Balaruc peninsula (Thau lagoon, southern France). This aquifer faces temporary phenomena of marine water intrusion through the Vise submarine spring located at -29.5 m below the lagoon level. Since the 1960s, seven flow reversal phenomena have occurred, the last one occurring between 11/28/2020 and 03/14/2022. During these phenomena, which can last from a few weeks to several months, the salty water is absorbed from the lagoon to the conduit of the submarine spring, which leads to the salinization of the underlying karst aquifer. The monitoring of flow, water specific conductivity and water temperature data from the karst submarine spring is a key element of the research project to understand the hydrogeological functioning of the karst aquifer under normal conditions or during flow reversal periods. This monitoring allows the characterization of the (in- or out-) flows at the submarine spring, the evaluation of the volume or mass balances, the identification of the hydrogeological and physico-chemical responses (water temperature, specific conductivity) observed within the karstic aquifer. Here, we present the means implemented offshore to acquire data at the submarine spring over the 06/25/2019 - 12/31/2022 time period together with lagoon water's physico-chemical parameters and levels and onshore groundwater's physico-chemical parameters and levels acquired at springs and boreholes from the karst aquifer.

Salinity spatial patterns in Mediterranean coastal areas: The legacy of historical water infrastructures.

Mediterranean coastal areas have been occupied and developed intensively for a long time facing issues related to agricultural production, urbanization, tourism, preservation of natural resources often linked to salinity. This article explores the relationship between historical land planning and water management, and current soil and water salinity to gain insights into future projections. Soil samples (1185) were collected in a coastal plain of 114 km2 in the south of France and saturated paste extract Electrical Conductivity (ECsp) was deduced from 1:5 dilution. Soil salinity exhibits a wide range of variation (from 0.54 to 113.1 mS cm-1) and spatial patterns. ECsp is significantly different among soil types, higher at depth than at the surface and influenced by the distance to ancient water infrastructures (Pettitt test). Surface water and shallow groundwater samples were collected for trace element concentrations and Oxygen (18O/16O) isotope ratio measurements. The geochemical signatures indicate a mixture between surface freshwater and seawater, reveal the presence of over-salted seawater and a stratification of salinity from the surface to the depth. Results suggest that groundwater is the source of soil salinity, and illustrate the long-term impact of old water infrastructures. Less saline soils are found near the freshwater supply channel (constructed from 15th to 18th), while more saline soils are located near drainage channels. The presence of over-salted water reflects temporal evolution of the plain over the last few centuries (initially under seawater, gradually filled in, presence of ponds and salt works that have now disappeared). The current soil salinity patches continue to be a visible reminder of this evolution. The trend towards desalinization of the plain over the last few centuries has been made possible by massive freshwater inflows, which are now under threat due to the general decrease of water resources availability.

Inverse modeling approach to allogenic karst system characterization.

Allogenic karst systems function in a particular way that is influenced by the type of water infiltrating through river water losses, by karstification processes, and by water quality. Management of this system requires a good knowledge of its structure and functioning, for which a new methodology based on an inverse modeling approach appears to be well suited. This approach requires both spring and river inflow discharge measurements and a continuous record of chemical parameters in the river and at the spring. The inverse model calculates unit hydrographs and the impulse responses of fluxes from rainfall hydraulic head at the spring or rainfall flux data, the purpose of which is hydrograph separation. Hydrograph reconstruction is done using rainfall and river inflow data as model input and enables definition at each time step of the ratio of each component. Using chemical data, representing event and pre-event water, as input, it is possible to determine the origin of spring water (either fast flow through the epikarstic zone or slow flow through the saturated zone). This study made it possible to improve a conceptual model of allogenic karst system functioning. The methodology is used to study the Bas-Agly and the Cent Font karst systems, two allogenic karst systems in Southern France.

Deep water circulation, residence time, and chemistry in a karst complex.

We investigated the hydrochemistry of a complex karst hydrosystem made of two carbonate units along a coastal lagoon. Ground water emerges on the lagoon floor from a submarine spring. In addition, thermal waters circulate through the limestone and mix with karst water near the lagoon shore. A distinction between the water from the two carbonate units is related to marine influences and human activities. In one of the massifs, the data show an incongruent dissolution of dolomite with time. In the other system, a slight contamination by saline fluids from the thermal reservoir has led to high calcium and magnesium concentrations. 36Cl, 14C, and 3H data constrain the residence time of the water, and allow for the distinguishing of four circulation types: (1) shallow surface circulation (primarily above sea level) in the karstic units with short residence times (<20 years); (2) shallow subsurface circulation (approximately 0 to -50 m) below the karstic units with residence time in the order of 50 years; (3) deep circulation at depth of 700 to 1500 m in the Jurassic limestones below thick sedimentary cover, with residence time of several thousand years for a part of the water; and (4) deep circulation at a depth of approximately 2500 m, which represents the thermal reservoir in the Jurassic units with residence time of approximately 100,000 years. An interpretative hydrogeological framework is based on the constraints of the geochemical analyses of the deep thermal system, and by water flow from the surface to the deep parts of the carbonate formations.