Luminescence characteristics and X-ray-induced defects in BaFBr:Eu2+ storage phosphor.

Three different approaches used to synthesize a sensitive BaFBr:Eu2+ X-ray storage photostimulated luminescence (PSL) phosphor at 850°C for 1 h in a reducing atmosphere are reported. The effects of F/Br and Eu concentration on photoluminescence (PL) and PSL sensitivities synthesized by the three approaches were compared. In the first recipe, BaFBr:Eu2+ prepared using a BaF2 , BaBr2 and EuF3 mixture using solid-state diffusion (Recipe I), even in a reducing atmosphere, yielded a low PL and PSL intensity due to oxygen contamination that acted as competing hole traps. When BaFBr:Eu2+ was prepared using ammonium bromide and ammonium fluoride by two different recipes (Recipes II and III), oxygen contamination was eliminated, resulting in enhanced PSL efficiency. The proposed PSL process in BaFBr:Eu2+ was consistent with the experimental results. Increased F/Br molar ratios would incorporate fluorine ion interstitials that act as hole traps accompanied by bromine ion vacancies that act as electron traps. Although two types of F centres, F(Br- ) and F(F- ) are possible, F(Br- ) centres formed during X-irradiation are only vital for the PSL process. Structural, morphology, and thermoluminescence (TL) properties of the samples were also examined using XRD, field emission scanning electron microscope (FESEM), energy-dispersive X-ray spectroscopy (EDAX), and TL studies.

Cellulose-based hydrogel for adsorptive removal of cationic dyes from aqueous solution: isotherms and kinetics.

The development of economic and recyclable adsorbents for removing pollutants from contaminated water is gaining increasing attention. Agro residue or nature-based material sourced absorbents could revolutionize the future of wastewater treatment. Hence in this study, nanocellulose was synthesized from coconut husk fiber and immobilized onto chitosan to form hydrogel beads. The BET surface area and zeta potential of the adsorbent nanocrystalline cellulose-chitosan hydrogel (NCC-CH) bead was 25.77 m2 g-1 and +50.6 mV, respectively. The functional group analysis also confirmed that the adsorbent had functional groups appropriate for the adsorption of textile dyes. The adsorption performance of NCC-CH and also the influence of initial dye concentration, adsorbent dose, pH, and contact time was evaluated by batch adsorption studies with crystal violet (CV) and methylene blue (MB) dyes. The most favorable operational conditions achieved through I-optimal design in response surface methodology were 0.5 g NCC-CH, 1 h, 9 pH, and 60 mg L-1 for CV removal (94.75%) and 0.13 g NCC-CH, 1 h, 9 pH, and 30 mg L-1 for MB removal (95.88%). The polynomial quadratic model fits the experimental data with an R 2 value of 0.99 and 0.98 for CV and MB removal, respectively. The optimum depiction of the isotherm data was obtained using the Freundlich model for MB adsorption and Freundlich and Langmuir model for CV adsorption. The Dubinin-Radushkevich (D-R) isotherm was also a good fit to the adsorption of CV and MB dye, suggesting the physisorption due to its free energy of adsorption < 8 kJ mol-1. The kinetics were effectively explained by a pseudo-second order model for both the dyes suggesting that chemical mechanisms influenced the adsorption of CV and MB dyes onto NCC-CH. The intraparticle diffusion model best suited the MB adsorption with three stages rather than the CV with a single step process. Also, the removal efficiency of adsorbent was retained at above 60% even after seven adsorption-desorption cycles indicating the effectiveness of the NCC-CH hydrogel beads for the removal of textile dyes.

DEVELOPMENT AND APPLICATION OF SOLID FORMS OF CaSO4:Dy THERMOLUMINESCENT DOSEMETERS IN RADIATION PROTECTION DOSIMETRY-A REVIEW.

CaSO4:Dy is a reliable high-sensitive themoluminescent phosphor useful for low-level and high-level radiation measurements as it exhibits fading free linear dose response with a single glow peak at ~230°C in these dose regions. For large-scale radiation protection dosimetry service, it is embedded in Teflon matrix with varying thicknesses. Extensive studies have been carried out with such CaSO4:Dy Teflon discs in individual and environmental radiation monitoring applications including its capability to measure International Commission on Radiation Units and Measurements operational quantities. The review highlights their development and application in high-energy photon measurements, thin wafers and graphite-loaded Teflon discs for beta-dosimetry, phosphor-filled aluminium discs for high-dose applications, 6LiF-mixed CaSO4:Dy Teflon discs for thermal and albedo or moderated fast neutrons, sulphur-mixed CaSO4:Dy pellets for fast-neutron exposure even in the presence of gamma-rays and polyethylene-mixed CaSO4:Dy discs for fast neutrons.