Beyond Energy Balance: Environmental Trade-Offs of Organics Capture and Low Carbon-to-Nitrogen Ratio Sewage Treatment Systems.

Several life-cycle assessments (LCAs) have evaluated the environmental impacts (EIs) of different wastewater treatment (WWT) configurations, attempting resource recovery and energy efficiency. However, a plant-wide LCA considering up-concentration primary treatment and low carbon-to-nitrogen (C/N) ratio sewage at the secondary biological treatment (SBT) has not yet been conducted. This study identifies the environmental trade-offs and hotspots for the chemically enhanced primary treatment (CEPT) and low C/N ratio SBT emerging processes compared to conventional WWT. The life-cycle inventories were calculated using a stoichiometric life-cycle inventory framework that couples stoichiometry and kinetics to obtain site-specific water, air, and soil emissions. The midpoint results of LCA show that CEPT with anaerobic digestion (AD) for sludge treatment achieves energy self-sufficiency, but increases marine eutrophication (MEu) by 1 order of magnitude compared to conventional WWT. A mainstream anaerobic fluidized-bed bioreactor and a partial nitritation-anammox fluidized-bed membrane bioreactor which can reduce all environmental impacts by 17-47%, including MEu, are proposed as the SBT of the low-carbon CEPT settled sewage. Integrating the standardized S-LCI framework resulted in a site-specific LCA that aids decision-makers on choosing between higher reductions in most EIs at the expense of high MEu or less but consistent reductions in all EI categories.

A Standardized Stoichiometric Life-Cycle Inventory for Enhanced Specificity in Environmental Assessment of Sewage Treatment.

In recent years, many life-cycle assessments (LCAs) have been applied to the field of sewage treatment (ST). However, most LCAs lack systematic data collection (DC) and processing methods for inventories of conventional ST (CST), much less for recently developed technologies. In addition, the use of site-generic databases results in LCAs that lack the representativeness and understanding of the regional environmental impacts and trade-offs between different impact categories, especially nutrient enrichment and toxicity-related categories. These shortcomings make comparative evaluation and implementation more challenging. In order to assist in the decision-making process, a novel stoichiometric life-cycle inventory (S-LCI) for ST was developed. In the S-LCI, biochemical pathways derived from elemental analyses combined with process-engineering calculations enable steady-state comparison of the water, air, and soil emissions of any sewage and sludge sample treated through the ST configurations analyzed herein. The DC required for the estimation of the foreground data for a CST is summarized in a 41-item checklist. Moreover, the S-LCI was validated for CST by comparing the S-LCI with actual ST plant operations performed in Hong Kong. A novel energy-derived ST inventory is developed and compared here with the CST. The resulting inventories are ready to be integrated into the SimaPro software for life cycle impact assessment as illustrated by the case study. Using the S-LCI not only helps to standardize the DC and processing, but it also enhances the level of specificity by using sample characterization and site-specific data. The EcoInvent database, which contains a single sample characterization per Swiss and global average ST plant class could be expanded by using the S-LCI.