Efficient preparation of anisotropic cellulose sponge from cotton stalks: An excellent material for separation applications.

Water pollution and solid waste resource reuse demand immediate attention and research. Here, we present a method to create anisotropic cellulose sponges from cotton stalk waste. Using the inherent structure of cotton stalks, we selectively remove lignin and hemicellulose via acid and alkali pretreatment. This process yields cellulose sponges with a natural pore structure. Our findings demonstrate that these sponges retain the original pore configuration of cotton stalks, providing excellent connectivity and compressibility due to their unique anisotropic three-dimensional structure. Moreover, these sponges exhibit exceptional super-hydrophilic and underwater super-oleophobic properties, with underwater oil contact angles exceeding 150° for all tested oils. External pressure can reduce the pore size of the cellulose sponge, facilitating the gravity-driven separation and removal of dyes and emulsions. Remarkably, removal efficiencies for Methylene Blue (MB), Congo Red (CR), water-in-oil (w/o) emulsions, and oil-in-water (o/w) emulsions exceed 99 %, 97 %, 99 %, and 99 %, respectively, highlighting superior removal and recyclability. Further investigation into the mechanisms of dye and emulsion removal employs X-ray photoelectron spectroscopy (XPS) characterization and molecular dynamics (MD) simulation. These insights lay the groundwork for the efficient recycling and resource utilization of waste cotton stalks, offering promising applications in water purification.

Adsorption behavior of UV aged microplastics on the heavy metals Pb(II) and Cu(II) in aqueous solutions.

As the "vector" of heavy metals in the aquatic environment, microplastics (MPs) have a great influence on the migration and transformation of heavy metals. In this study, the adsorption of polypropylene (PP), polyethylene (PE) and polystyrene (PS) on two models of heavy metals after UV aging and environmental variables (ionic coexistence, pH, salinity, and fulvic acid) were comprehensively explored on adsorption. The results show that new oxidation functional groups are formed and their hydrophilicity is enhanced after MPs aging. As a result, the adsorption experiments showed that the adsorption of contaminants by UV aged MPs exceeds that of pristine MPs. The adsorption amounts of Pb(II) and Cu(II) by PP, PE and PS increased by 1.45, 1.46, 1.25 and 1.63, 1.39, 1.22 times, respectively. Adsorption kinetic data were more consistent with the pseudo-second-order kinetic model, proving chemisorption to be the mechanism governing the interaction between metal ions and MPs. The Freundlich model could accurately predict the heavy metal adsorption isotherms on MPs, showing that non-homogeneous multilayer adsorption dominates the process. In Pb(II)-Cu(II) binary composite system, metal ion adsorption capacity on MPs is less than that of the single system adsorption capacity, which proves that there is a specific inhibitory effect between coexisting ions. Additionally, external factors like pH, salinity, and fulvic acid content have a big impact on adsorption behavior. According to mechanism analysis, the adsorption process mainly relies on electrostatic interaction, surface complexation, and van der Waals force.

UV and chemical aging alter the adsorption behavior of microplastics for tetracycline.

This study evaluates the "vector" effects of different microplastics (MPs) on coexisting pollutants. The adsorption of tetracycline was studied on biodegradable plastics poly(butylene adipate-co-terephthalate) (PBAT) and non-biodegradable plastics polystyrene (PS), polypropylene (PP), and polyethylene (PE) after UV aging and chemical aging. The physicochemical properties of PBAT changed more obviously after UV radiation and chemical aging comparing to PS, PP and PE. Pores and cracks appear on the surface of aged PBAT. The crystallinity increased from 29.2% to 52.62%. In adsorption experiments, pristine and aged PBAT had strong vector effects on the adsorption of tetracycline than PS, PP and PE. The adsorption capacity of tetracycline on PBAT was increased from 0.7980 mg g-1 to 1.2669 mg g-1 after chemical aging. The adsorption mechanism indicated that electrostatic interactions and hydrogen bonds contribute to the adsorption process. In addition, for the adsorption of tetracycline on PS, π-π interaction was the main cause, and the adsorption mechanism was not considerably changed by aging. In conclusion, this study demonstrates that biodegradable plastics have substantial vector effect on coexisting pollutants at the end of their life cycle, this contributes to assessment of the risk from microplastic pollution.

Underwater superoleophobic polyurethane-coated mesh with excellent stability for oil/water separation.

Oil/water separation has been a challenge in chemical engineering for various applications. There are numbers of studies on using coated metal meshes as a filter for oil/water separation. However, water resistance, chemical (such as: acid, base, and fouling) resistance and heat resistance for coating materials need further exploration, especially in terms of the durability of the coating materials. In this study, we synthesized a new coating material, hydrophilic polycarbonate polyurethane (HPCPU). We used HPCPU to chemically modify a steel mesh, and the mesh exhibits superhydrophilic and underwater superoleophobic properties. The HPCPU coated mesh shows excellent capacity for oil/water separation with a separation efficiency higher than 99.99% even after 40 cycles of separation. The coating material also exhibits excellent properties of water resistance, heat resistance, and chemical resistance. Moreover, the HPCPU-coated mesh exhibits a strong durability. For example, the separation efficiency for various oil/water mixtures remains higher than 99.7% after the HPCPU-coated mesh has been soaked in water for 30 days, hot water for 5 days, oils for 5 days, 0.5 M HCl solution, 0.5 M NaOH solution and 0.5 M NaCl solution for 24 hours.