Shortcuts of Freely Relaxing Systems Using Equilibrium Physical Observables.

Many systems, when initially placed far from equilibrium, exhibit surprising behavior in their attempt to equilibrate. Striking examples are the Mpemba effect and the cooling-heating asymmetry. These anomalous behaviors can be exploited to shorten the time needed to cool down (or heat up) a system. Though, a strategy to design these effects in mesoscopic systems is missing. We bring forward a description that allows us to formulate such strategies, and, along the way, makes natural these paradoxical behaviors. In particular, we study the evolution of macroscopic physical observables of systems freely relaxing under the influence of one or two instantaneous thermal quenches. The two crucial ingredients in our approach are timescale separation and a nonmonotonic temperature evolution of an important state function. We argue that both are generic features near a first-order transition. Our theory is exemplified with the one-dimensional Ising model in a magnetic field using analytic results and numerical experiments.

Slow growth of magnetic domains helps fast evolution routes for out-of-equilibrium dynamics.

Cooling and heating faster a system is a crucial problem in science, technology, and industry. Indeed, choosing the best thermal protocol to reach a desired temperature or energy is not a trivial task. Noticeably, we find that the phase transitions may speed up thermalization in systems where there are no conserved quantities. In particular, we show that the slow growth of magnetic domains shortens the overall time that the system takes to reach a final desired state. To prove that statement, we use intensive numerical simulations of a prototypical many-body system, namely, the two-dimensional Ising model.

Kovacs Memory Effect with an Optically Levitated Nanoparticle.

The understanding of the dynamics of nonequilibrium cooling and heating processes at the nanoscale is still an open problem. These processes can follow surprising relaxation paths due to, e.g., memory effects, which significantly alter the expected equilibration routes. The Kovacs effect can take place when a thermalization process is suddenly interrupted by a change of the bath temperature, leading to a nonmonotonic evolution of the energy of the system. Here, we demonstrate that the Kovacs effect can be observed in the thermalization of the center of mass motion of a levitated nanoparticle. The temperature is controlled during the experiment through an external source of white Gaussian noise that mimics an effective thermal bath at a temperature that can be changed faster than any relaxation time of the system. We describe our experiments in terms of the dynamics of a Brownian particle in a harmonic trap without any fitting parameter, suggesting that the Kovacs effect can appear in a large variety of systems.

Exponentially Accelerated Approach to Stationarity in Markovian Open Quantum Systems through the Mpemba Effect.

Ergodicity breaking and slow relaxation are intriguing aspects of nonequilibrium dynamics both in classical and quantum settings. These phenomena are typically associated with phase transitions, e.g., the emergence of metastable regimes near a first-order transition or scaling dynamics in the vicinity of critical points. Despite being of fundamental interest the associated divergent timescales are a hindrance when trying to explore steady-state properties. Here we show that the relaxation dynamics of Markovian open quantum systems can be accelerated exponentially by devising an optimal unitary transformation that is applied to the quantum system immediately before the actual dynamics. This initial "rotation" is engineered in such a way that the state of the quantum system no longer excites the slowest decaying dynamical mode. We illustrate our idea-which is inspired by the so-called Mpemba effect, i.e., water freezing faster when initially heated up-by showing how to achieve an exponential speeding-up in the convergence to stationarity in Dicke models, and how to avoid metastable regimes in an all-to-all interacting spin system.

Induced correlations and rupture of molecular chaos by anisotropic dissipative Janus hard disks.

A system of smooth "frozen" Janus-type disks is studied. Such disks cannot rotate and are divided by their diameter into two sides of different inelasticities. Taking as a reference a system of colored elastic disks, we find differences in the behavior of the collisions once the anisotropy is included. A homogeneous state, akin to the homogeneous cooling state of granular gases, is seen to arise and the singular behavior of both the collisions and the precollisional correlations are highlighted.

Erratum: Energy nonequipartition in gas mixtures of inelastic rough hard spheres: The tracer limit [Phys. Rev. E 96, 052901 (2017)].

This corrects the article DOI: 10.1103/PhysRevE.96.052901.

Large Mpemba-like effect in a gas of inelastic rough hard spheres.

We report the emergence of a giant Mpemba effect in the uniformly heated gas of inelastic rough hard spheres: The initially hotter sample may cool sooner than the colder one, even when the initial temperatures differ by more than one order of magnitude. In order to understand this behavior, it suffices to consider the simplest Maxwellian approximation for the velocity distribution in a kinetic approach. The largeness of the effect stems from the fact that the rotational and translational temperatures, which obey two coupled evolution equations, are comparable. Our theoretical predictions agree very well with molecular dynamics and direct simulation Monte Carlo data.

The Mpemba effect in spin glasses is a persistent memory effect.

The Mpemba effect occurs when a hot system cools faster than an initially colder one, when both are refrigerated in the same thermal reservoir. Using the custom-built supercomputer Janus II, we study the Mpemba effect in spin glasses and show that it is a nonequilibrium process, governed by the coherence length ξ of the system. The effect occurs when the bath temperature lies in the glassy phase, but it is not necessary for the thermal protocol to cross the critical temperature. In fact, the Mpemba effect follows from a strong relationship between the internal energy and ξ that turns out to be a sure-tell sign of being in the glassy phase. Thus, the Mpemba effect presents itself as an intriguing avenue for the experimental study of the coherence length in supercooled liquids and other glass formers.

When the Hotter Cools More Quickly: Mpemba Effect in Granular Fluids.

Under certain conditions, two samples of fluid at different initial temperatures present a counterintuitive behavior known as the Mpemba effect: it is the hotter system that cools sooner. Here, we show that the Mpemba effect is present in granular fluids, both in uniformly heated and in freely cooling systems. In both cases, the system remains homogeneous, and no phase transition is present. Analytical quantitative predictions are given for how differently the system must be initially prepared to observe the Mpemba effect, the theoretical predictions being confirmed by both molecular dynamics and Monte Carlo simulations. Possible implications of our analysis for other systems are also discussed.

Energy nonequipartition in gas mixtures of inelastic rough hard spheres: The tracer limit.

The dynamical properties of a tracer or impurity particle immersed in a host gas of inelastic and rough hard spheres in the homogeneous cooling state is studied. Specifically, the breakdown of energy equipartition as characterized by the tracer/host ratios of translational and rotational temperatures is analyzed by exploring a wide spectrum of values of the control parameters of the system (masses, moments of inertia, sizes, and coefficients of restitution). Three complementary approaches are considered. On the theoretical side, the Boltzmann and Boltzmann-Lorentz equations (both assuming the molecular chaos ansatz) are solved by means of a multitemperature Maxwellian approximation for the velocity distribution functions. This allows us to obtain explicit analytical expressions for the temperature ratios. On the computational side, two different techniques are used. First, the kinetic equations are numerically solved by the direct simulation Monte Carlo (DSMC) method. Second, molecular dynamics simulations for dilute gases are performed. Comparison between theory and simulations shows a general good agreement. This means that (i) the impact of the molecular chaos ansatz on the temperature ratios is not significant (except at high inelasticities and/or big impurities) and (ii) the simple Maxwellian approximation yields quite reliable predictions.

Unified rheology of vibro-fluidized dry granular media: From slow dense flows to fast gas-like regimes.

Granular media take on great importance in industry and geophysics, posing a severe challenge to materials science. Their response properties elude known soft rheological models, even when the yield-stress discontinuity is blurred by vibro-fluidization. Here we propose a broad rheological scenario where average stress sums up a frictional contribution, generalizing conventional µ(I)-rheology, and a kinetic collisional term dominating at fast fluidization. Our conjecture fairly describes a wide series of experiments in a vibrofluidized vane setup, whose phenomenology includes velocity weakening, shear thinning, a discontinuous thinning transition, and gaseous shear thickening. The employed setup gives access to dynamic fluctuations, which exhibit a broad range of timescales. In the slow dense regime the frequency of cage-opening increases with stress and enhances, with respect to µ(I)-rheology, the decrease of viscosity. Diffusivity is exponential in the shear stress in both thinning and thickening regimes, with a huge growth near the transition.

An itinerant oscillator model with cage inertia for mesorheological granular experiments.

Recent experiments with a rotating probe immersed in weakly fluidized granular materials show a complex behavior on a wide range of time scales. Viscous-like relaxation at high frequency is accompanied by an almost harmonic dynamical trapping at intermediate times, with possibly anomalous long time behavior in the form of super-diffusion. Inspired by the itinerant oscillator model for diffusion in molecular liquids, and other models with coupled thermostats acting at different time scales, here we discuss a new model able to account for fast viscous relaxation, dynamical trapping, and super-diffusion at long times. The main difference with respect to liquids is a non-negligible cage inertia for the surrounding (granular) fluid, which allows it to sustain a slow but persistent motion for long times. The computed velocity power density spectra and mean-squared displacement qualitatively reproduce the experimental findings. We also discuss the linear response to external perturbations and the tail of the distribution of persistency time, which is associated with superdiffusion, and whose cut-off time is determined by cage inertia.