1.
Beilstein J Org Chem
; 5: 1, 2009.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19259337
RESUMO
Tetrakis(dimethylamino)ethylene (TDAE 1), has been exploited for the first time as a mild reagent for the reduction of arenediazonium salts to aryl radical intermediates through a single electron transfer (SET) pathway. Cyclization of the aryl radicals produced in this way led, in appropriate substrates, to syntheses of indolines and indoles. Cascade radical cyclizations of aryl radicals derived from arenediazonium salts are also reported. The relative ease of removal of the oxidized by-products of TDAE from the reaction mixture makes the methodology synthetically attractive.
2.
Org Lett
; 4(16): 2735-8, 2002 Aug 08.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12153222
RESUMO
[reaction: see text] Indolines and indoles are prepared for the first time by direct electrochemical reduction of arenediazonium salts.