Plasma-immersion ion implantation surface oxidation on a cobalt-chromium alloy for biomedical applications.

Co-Cr alloys such as L605 are widely applied for the manufacture of medical devices, including tiny cardiovascular stents. The presence of potentially toxic and allergenic release of Ni, Co, and Cr ions from these devices remains an unsolved concern. Surface modification by oxygen plasma immersion implantation (PIII) could be an excellent technique to create a dense and thin passive oxide layer on a relatively complex shape of a tiny device, such as a stent, thus reducing the potential release of metallic ions. The effect of oxygen PIII was investigated on L605 alloy specimens, from 5 to 50 mTorr gas pressures, and under pulsed bias voltages from -0.1 to -10 kV. The surface chemistry was investigated by x-ray photoelectron spectroscopy, while its morphology and surface energy were evaluated, respectively, by atomic force microscopy and scanning electron microscopy and by a sessile drop static contact angle. Electrochemical characterization was performed by potentiodynamic tests in the saline solution. Mechanical properties of the modified surface layer, specifically film adhesion and hardness (H), were assessed by scratch and nanoindentation tests. Results shown that the oxidized layers were composed of a mixture of Co and Cr oxides and hydroxides and were rich in Co. The corrosion rate was considerably reduced after O PIII, even for treatments using low bias voltage (-0.1 kV) and with consequent low oxygen implantation depth. Moreover, O PIII also improved surface hardness. The oxidized layers were found to have good adhesion and to be scratch resistant.

Experimental and Numerical Characterization of High Damping Martensitic CuAlMn Sheets.

This paper deals with the experimental and numerical characterization of a high damping CuAlMn sheet with a martensitic micro-structure at ambient temperature. A Cu-Al-Mn shape memory alloy containing 11.65 wt.% of Al and 3 wt.% of Mn, was cast and hot rolled to the thickness of 0.4-0.3 mm. Transformation temperatures, micro-structure and mechanical properties were studied. Effects of the heat treatment on damping were investigated, identifying the proper heat treatment to obtain a higher damping. Having to model the amplitude dependent damping of the material investigated, a material model was developed based of cyclic behavior under traction-compression load. The model was validated with experiments on the non-linear damping of the material.

A Numerical Method to Model Non-linear Damping Behaviour of Martensitic Shape Memory Alloys.

This article investigates the efficiency of hybridizing composites with thin layers of martensitic shape memory alloys for improvement of damping. The non-linear damping behaviour of martensitic shape memory alloys is simulated using a modified version of Masing's rules. The model was implemented in a user subroutine of a finite element code, and validated by a numerical simulation of experimental hysteresis loops at different maximum strain amplitudes. The experimental free decay of hybridized glass fiber reinforced polymer beams was simulated using the finite element model, including the validated model of the investigated materials. The amplitude-dependent damping of the hybrid beams in free decay was reproduced successfully in the numerical analysis and it was proven that the hybridization technique is efficient for improvement of damping.

Laser surface structuring of AZ31 Mg alloy for controlled wettability.

Structured surfaces exhibit functional properties that can enhance the performance of a bioimplant in terms of biocompatibility, adhesion, or corrosion behavior. In order to tailor the surface property, chemical and physical methods can be used in a sequence of many steps. On the other hand, laser surface processing can provide a single step solution to achieve the designated surface function with the use of simpler equipment and high repeatability. This work provides the details on the surface structuring of AZ31, a biocompatible and biodegradable Mg alloy, by a single-step laser surface structuring based on remelting. The surfaces are characterized in terms of topography, chemistry, and physical integrity, as well as the effective change in the surface wetting behavior is demonstrated. The results imply a great potential in local or complete surface structuring of medical implants for functionalization by the flexible positioning of the laser beam.