Graphene-oxide loading on natural zeolite particles for enhancement of adsorption properties.

Multiple methods of grafting graphene oxide (GO) nanosheets to natural clinoptilolite-rich zeolite particles were developed in our laboratory. In this study, we have systematically characterized the GO coated particles prepared by various methods to select the most promising method for further research efforts. This study revealed that the most promising coating method was the clean-acid-treated zeolite particles followed by deposition of GO nanosheets onto the zeolite surface and mild thermal treatment of the particles. GO and its synergistic interaction in zeolite was attributed to electrostatic interactions, hydrophobic interactions and hydrogen bonds. Hydrophobic interactions are enhanced both due to dealumination of zeolite caused by the cleaning method followed by acid treatment and due to partial thermal deoxygenation of GO. This method provided a ten times larger surface area (from 10.55 m2 g-1 to 117.96 m2 g-1) and three times smaller pore diameter (from 81.91 Å to 30.68 Å), providing great particles for a variety of applications as adsorbents or catalysts.

Flooding flows in city crossroads: experiments and 1-D modelling.

This study focuses on the discharge distribution in an intersection of four channels, similar to a city crossroad. The channels and the intersection are all horizontal. Flow enters through two of the channels, and leaves through the other two. The flow is subcritical everywhere, and flow depths are controlled by vertical weirs at the exits of the outlet channels. The main variables that are measured are the flow rates in the four channels. When the weir heights in the outlet channels are the same, the ratio of flow rates in the outlet channels depends only on the ratio of flow rates in the inlet channels; if the outlet conditions are different, other parameters, such as the total flow rate also become important. The flow has also been simulated numerically using a solution of the 1-D Saint Venant equations, with a simple model to predict flow distribution in the intersection. A comparison with the experimental data shows that this model works well for the limited range of experimental conditions studied here. However, further work is needed on a wider range of conditions, closer to real conditions, before the model can be considered valid for practical applications.