Perovskite Lanthanum-Doped Barium Stannate: A Refractory Near-Zero-Index Material for High-Temperature Energy Harvesting Systems.

The recent interests in bridging intriguing optical phenomena and thermal energy management has led to the demonstration of controlling thermal radiation with epsilon-near-zero (ENZ) and the related near-zero-index (NZI) optical media. In particular, the manipulation of thermal emission using phononic ENZ and NZI materials has shown promise in mid-infrared radiative cooling systems operating under low-temperature environments (below 100 °C). However, the absence of NZI materials capable of withstanding high temperatures has limited the spectral extension of these advanced technologies to the near-infrared (NIR) regime. Herein, a perovskite conducting oxide, lanthanum-doped barium stannate (La:BaSnO3 [LBSO]), as a refractory NZI material well suited for engineering NIR thermal emission is proposed. This work focuses on the experimental demonstration of superior high-temperature stability (of at least 1000 °C) of LBSO films in air and its durability under intense UV-pulsed laser irradiation below peak power of 9 MW cm-2 . Based on the low optical-loss in LBSO, a selective narrow-band thermal emission utilizing a metal-insulator-metal (MIM) Fabry-Pérot nanocavity consisting of LBSO films as metallic component is demonstrated. This study shows that LBSO is an ideal candidate as a refractory NZI component for thermal energy conversion operating at high temperatures in air and under strong light irradiations.

Controlling of lattice strains for crack-free and strong ferroelectric barium titanate films by post-thermal treatment.

In this study, we experimentally demonstrate fabrication of ultra-smooth and crystalline barium titanate (BTO) films on magnesium oxide (MgO) substrates by engineering lattice strain and crystal structure via thermal treatment. We observe that oxygen-depleted deposition allows growth of highly strained BTO films on MgO substrates with crack-free surface. In addition, post-thermal treatment relaxes strain, resulting in an enhancement of ferroelectricity. Surface roughening of the BTO films caused by recrystallization during post-thermal treatment is controlled by chemical-mechanical polishing (CMP) to retain their initial ultra-smooth surfaces. From Raman spectroscopy, reciprocal space map (RSM), and capacitance-voltage (C-V) curve measurements, we confirm that the ferroelectricity of BTO films strongly depend on the relaxation of lattice strain and the phase transition from a-axis to c-axis oriented crystal structure.

Lead-Sealed Stretchable Underwater Perovskite-Based Optoelectronics via Self-Recovering Polymeric Nanomaterials.

To harness the full potential of halide perovskite based optoelectronics, biological safety, compatibility with flexible/stretchable platforms, and operational stability must be guaranteed. Despite substantial efforts, none has come close to providing a solution that encompasses all of these requirements. To address these issues, we devise a multifunctional encapsulation scheme utilizing hydrogen bond-based self-recovering polymeric nanomaterials as an alternative for conventional glass-based encapsulation. We show that Pb in physically damaged halide perovskite solar cells can be completely contained within the self-recovering encapsulation upon submersion in a simulated rain bath, as indicated by in vitro cytotoxicity tests. In addition, self-recovering encapsulation accommodates stable device operation upon casual bending and even stretching, which is in stark contrast to conventional glass-based encapsulation schemes. We also demonstrate the concept of assembling user-defined scalable modular optoelectronics based on halide perovskite solar cells and light emitting diodes through the use of self-recovering conductive nanocomposites. Finally, long-term operational stability of over 1000 h was achieved under harsh accelerated conditions (50 °C/50% RH and 85 °C/0% RH) with the incorporation of an ultrathin atomic layer deposited TiO2 barrier underneath the multifunctional encapsulation. In light of these merits, the encapsulation scheme based on self-recovering polymeric nanomaterials is proposed as a simple, but practical solution to a multifaceted challenge in the field of halide perovskites.

Effects of ion clustering and excited state absorption on the performance of Ho-doped fiber lasers.

The effects of ion clustering and excited state absorption occurring in holmium-doped fiber lasers are investigated experimentally and theoretically. It is found that the slope efficiencies of holmium-doped fiber lasers are reduced by inhomogeneous upconversion associated with the clustering of Ho3+ ions. Via theoretical analysis based upon Judd-Ofelt theory, it is also found that the effect of excited state absorption on the performance of Ho-doped fiber lasers is negligible, a fact indicating that ion clustering is the dominant cause of the lower-than-expected slope efficiencies observed in holmium-doped fiber lasers. We argue that ion clustering is an intrinsic flaw of holmium-doped fibers and is difficult to eliminate, because our research efforts are based on commercially available low-concentration fiber, which is fabricated with state-of-the-art techniques.

Long-distance transmission of broadband near-infrared light guided by a semi-disordered 2D array of metal nanoparticles.

Near-infrared (NIR) waveguides are a key component of planar photonic devices such as optical communication couplers, image sensors, and spectroscopes for chemical or biological molecules. Conventional NIR waveguides used for signal transmission include silicon-on-insulator (SOI) waveguides and channel/ridge-type metal micro-strips. However, these waveguides usually have limitations of either signal delay or signal loss in optically integrated devices. In this study, a novel NIR waveguide composed of a semi-disordered array of metal nanoparticles (sDAMNPs) on Si substrate was proposed, fabricated, and tested. The disordered metallic nanoparticles array is geometrically localized in the form of 1D metal strips, thus replacing sDAMNPs with less lossy micro strip channel waveguides. From the measurements supported by various computational models, the fabricated waveguides operate effectively in the broadband NIR region (1100 to 1700 nm). The waveguide does not support signal transmission in the ultra violet-visible spectrum due to strong signal absorption, scattering, and localization effects inside the metal nanoparticles. Instead, it is capable of transmitting NIR over a distance longer than 100 µm (signal loss ∼3.85 dB per 100 µm for NIR from 1200 to 1600 nm), which is also sufficiently longer than the conventional surface plasmon polariton propagation distance at the metal-Si interface. Compared to a waveguide-free reference, the waveguide exhibited greatly improved signal transmission efficiency up to a factor of 7.42 × 104 at 1367 nm. It also exhibits a high deflection angle sensitivity of 1.89 dB per 0.01 rad, thus efficiently and straightly guiding the broadband NIR signal over a long distance.

All-fiber Tm-doped soliton laser oscillator with 6 nJ pulse energy based on evanescent field interaction with monoloayer graphene saturable absorber.

We demonstrate an all-fiber Tm-doped soliton laser with high power by using a monolayer graphene saturable absorber (SA). Large area, uniform monolayer graphene was transferred to the surface of the side-polished fiber (SPF) to realize an in-line graphene SA that operates around 2 µm wavelength. To increase the nonlinear interaction with graphene, we applied an over-cladding onto the SPF, where enhanced optical absorption at monolayer graphene was observed. All-fiber Tm-doped mode-locked laser was built including our in-line graphene SA, which stably delivered the soliton pulses with 773 fs pulse duration. The measured 3-dB spectral bandwidth was 5.14 nm at the wavelength of 1910 nm. We obtained the maximum average output power of 115 mW at a repetition rate of 19.31 MHz. Corresponding pulse energy was estimated to be 6 nJ, which is the highest value among all-fiber Tm-doped soliton oscillators using carbon-material-based SAs.

Design of broadband multilayer dichroic coating for a high-efficiency solar energy harvesting system.

We report on the design and performance of a broadband dichroic coating for a solar energy conversion system. As a spectral beam splitter, the coating facilitates a hybrid system that combines a photovoltaic cell with a thermal collector. When positioned at a 45° angle with respect to incident light, the coating provides high reflectance in the 40-1100 nm and high transmission in the 1200-2000 nm ranges for a photovoltaic cell and a thermal collector, respectively. Numerical simulations show that our design leads to a sharp transition between the reflection and transmission bands, low ripples in both bands, and slight polarization dependence.

Broadband supercontinuum generation using a hollow optical fiber filled with copper-ion-modified DNA.

We experimentally demonstrated supercontinuum generation through a hollow core photonic bandgap fiber (HC-PBGF) filled with DNA nanocrystals modified by copper ions in a solution. Both double-crossover nano DNA structure and copper-ion-modified structure provided a sufficiently high optical nonlinearity within a short length of hollow optical fiber. Adding a higher concentration of copper ion into the DNA nanocrystals, the bandwidth of supercontinuum output was monotonically increased. Finally, we achieved the bandwidth expansion of about 1000 nm to be sufficient for broadband multi-spectrum applications.

Active control of all-fibre graphene devices with electrical gating.

Active manipulation of light in optical fibres has been extensively studied with great interest because of its compatibility with diverse fibre-optic systems. While graphene exhibits a strong electro-optic effect originating from its gapless Dirac-fermionic band structure, electric control of all-fibre graphene devices remains still highly challenging. Here we report electrically manipulable in-line graphene devices by integrating graphene-based field effect transistors on a side-polished fibre. Ion liquid used in the present work critically acts both as an efficient gating medium with wide electrochemical windows and transparent over-cladding facilitating light-matter interaction. Combined study of unique features in gate-variable electrical transport and optical transition at monolayer and randomly stacked multilayer graphene reveals that the device exhibits significant optical transmission change (>90%) with high efficiency-loss figure of merit. This subsequently modifies nonlinear saturable absorption characteristics of the device, enabling electrically tunable fibre laser at various operational regimes. The proposed device will open promising way for actively controlled optoelectronic and nonlinear photonic devices in all-fibre platform with greatly enhanced graphene-light interaction.

Brillouin optical correlation domain analysis with more than 1 million effective sensing points based on differential measurement.

Large increase of effective sensing points in Brillouin optical correlation domain analysis (BOCDA) is achieved by simultaneously applying double modulation and optical time gate based on differential measurement scheme. The noise substructure of Brillouin gain spectrum induced by the double modulation is effectively suppressed by the differential measurement, leading to 2,000 times enlargement of the measurement range. Distributed strain and temperature sensing along a 10.5 km fiber with spatial resolution of less than 1 cm is experimentally demonstrated which corresponds to over 1 million effective sensing points.

A femtosecond pulse fiber laser at 1935 nm using a bulk-structured Bi2Te3 topological insulator.

We experimentally demonstrate a femtosecond mode-locked, all-fiberized laser that operates in the 2 µm region and that incorporates a saturable absorber based on a bulk-structured bismuth telluride (Bi(2)Te(3)) topological insulator (TI). Our fiberized saturable absorber was prepared by depositing a mechanically exfoliated, ~30 µm-thick Bi(2)Te(3) TI layer on a side-polished optical fiber platform. The bulk crystalline structure of the prepared Bi(2)Te(3) layer was confirmed by Raman and X-ray photoelectron spectroscopy measurements. The modulation depth of the prepared saturable absorber was measured to be ~20.6%. Using the saturable absorber, it is shown that stable, ultrafast pulses with a temporal width of ~795 fs could readily be generated at a wavelength of 1935 nm from a thulium/holmium co-doped fiber ring cavity. This experimental demonstration confirms that bulk structured, TI-based saturable absorbers can readily be used as an ultra-fast mode-locker for 2 µm lasers.

Linearly configured BOCDA system using a differential measurement scheme.

We experimentally demonstrate a linearly configured Brillouin optical correlation domain analysis (BOCDA) system enhanced by a differential measurement scheme. On-off control of the pump phase modulation with an intentional loss at the end of a fiber under test is applied for the acquisition of a Brillouin gain spectrum. This application leads to a four-fold enhancement of the spatial resolution and doubling of the measurement range in comparison with the former system under the same modulation parameters.

Mode-locked pulse generation from an all-fiberized, Tm-Ho-codoped fiber laser incorporating a graphene oxide-deposited side-polished fiber.

An in-depth experimental investigation was conducted into the use of a graphene oxide-based saturable absorber implemented on a side-polished fiber platform for femtosecond pulse generation in the 2 µm region. First, it was experimentally shown that an all-fiberized thulium-holmium (Tm-Ho)-codoped fiber ring laser with reduced cavity length can produce stable femtosecond pulses by incorporating a graphene oxide-deposited side-polished fiber. Second, the measurement accuracy issue in obtaining a precise pulse-width value by use of an autocorrelator together with a silica fiber-based 2 µm-band amplifier was investigated. It showed that the higher-order soliton compression effect caused by the combination of anomalous dispersion and Kerr nonlinearity can provide incorrect pulse-width information. Third, an experimental investigation into the precise role of the graphene oxide-deposited side-polished fiber was carried out to determine whether its polarization-dependent loss (PDL) can be a substantial contributor to mode-locking through nonlinear polarization rotation. By comparing its performance with that of a gold-deposited side-polished fiber, the PDL contribution to mode-locking was found to be insignificant, and the dominant mode-locking mechanism was shown to be saturable absorption due to mutual interaction between the evanescent field of the oscillated beam and the deposited graphene oxide particles.

Differential measurement scheme for Brillouin optical correlation domain analysis.

We newly propose and experimentally demonstrate a differential measurement scheme for Brillouin optical correlation domain analysis, where the difference between Brillouin gain spectra constructed by a normal and a phase-modulated Brillouin pump waves are analyzed to measure local Brillouin frequencies in optical fibers. In experiments, a five-fold enhancement in the spatial resolution is obtained compared to an ordinary BOCDA system under the same modulation parameters, as a result of the improved dynamic range by the suppression of background noises.

Bidirectional measurement for Brillouin optical correlation domain analysis.

We propose and experimentally demonstrate a bidirectional measurement for Brillouin optical correlation domain analysis as a novel and simple way of the performance enhancement. Brillouin gain and loss spectra of two adjacent correlation peaks are simultaneously and independently analyzed by applying midpoint attenuation in a fiber under test, which doubles both the speed and the range of the distributed measurement.

In situ gas sensing using a remotely detectable probe with replaceable insert.

We demonstrate a spectroscopic gas sensor using an optical fiber probe with a replaceable insert. The probe consists of a hollow-core photonic bandgap fiber (HC-PBGF) with a core diameter of 10.9 µm and a glass tube where a 2-µm hollow core fiber (HCF) with a gold coated end facet can be inserted. The HCF is designed to function as both a gate where gases can enter the HC-PBGF and a mirror reflecting the guided light back to the HC-PBGF. The opposite distal end of the probe is also designed to be able to regulate the gas pressure within the HC-PBGF for a high gas flow rate, while still transmitting the reflected light to the analysis instrument. The remote sensing probe, we believe, has much potential for detecting gases in hazardous environments.

Variable-frequency lock-in detection for the suppression of beat noise in Brillouin optical correlation domain analysis.

We propose and experimentally demonstrate a novel lock-in detection method to avoid a beat noise in Brillouin optical correlation domain analysis (BOCDA) which appears in the sweep of the sensing position and deteriorates the measurement accuracy by distorting the acquired Brillouin gain spectrum. In our analysis, the origin of the beat noise is shown to be the fluctuation of the Brillouin gain induced by the chopping of the intensity-modulated pump wave, and the optimal relation between the modulation and the lock-in frequencies is developed as an effective solution to circumvent the beat noise.

Design of waveguide grating with ultrafast tunable index contrast.

A long-period waveguide grating (LPWG) with a tunable index contrast is proposed. The design features a simple configuration that consists of a two-mode waveguide formed on periodically poled lithium niobate with an angle with respect to its domain wall and a traveling-wave electrode. In the design, the electrical traveling wave introduces a periodic change in the refractive index of waveguide, which functions as a long-period waveguide grating that couples between symmetric and anti-symmetric core modes. The index contrast of grating can be controlled by the traveling-wave intensity. For application to ultrafast device, structural parameters satisfying velocity and impedance matching conditions are numerically calculated.

High-accuracy measurement of cladding noncircularity based on phase velocity difference between acoustic polarization modes.

A high-accuracy measurement method for the noncircularity (ellipticity) of silica glass fibers is demonstrated. This method makes use of the phase velocity difference between two eigen polarization modes of the lowest-order acoustic flexural wave in an optical fiber. The relationship between the acoustic phase velocity difference and the fiber ellipticity is formulated. Three types of optical fibers were examined; photonic crystal fiber, elliptical core fiber, and standard single-mode fiber. Fiber ellipticity of less than 0.001 was successfully measured.

Tunable photonic microwave notch filter using SOA-based single-longitudinal mode, dual-wavelength laser.

A novel photonic microwave notch filter with capability of frequency tuning is proposed and experimentally demonstrated. The scheme is based on a fiber Bragg grating (FBG)-based, single longitudinal mode, wavelength-spacing tunable dual-wavelength fiber laser and a dispersive fiber delay line. By using a symmetrical S-bending technique along the FBGs, the wavelength spacing of the laser can be tuned, which enables the microwave notch frequency tuning. Experimental results show that the notch rejection of more than 30 dB and the flexible tunability of notch frequency can be readily achieved in the range of 1.2 approximately 6.7 GHz.