Salt-concentration-dependent nucleation rates in low-metastability colloidal charged sphere melts containing small amounts of doublets.

We determined bulk crystal nucleation rates in aqueous suspensions of charged spheres at low metastability. Experiments were performed in dependence on electrolyte concentration and for two different particle number densities. The time-dependent nucleation rate shows a pronounced initial peak, while postsolidification crystal size distributions are skewed towards larger crystallite sizes. At each concentration, the nucleation rate density initially drops exponentially with increasing salt concentration. The full data set, however, shows an unexpected scaling of the nucleation rate densities with metastability times the number density of particles. Parameterization of our results in terms of classical nucleation theory reveals unusually low interfacial free energies of the nucleus surfaces and nucleation barriers well below the thermal energy. We tentatively attribute our observations to the presence of doublets introduced by the employed conditioning technique. We discuss the conditions under which such small seeds may induce nucleation.

Dynamics of the Vortex-Particle Complexes Bound to the Free Surface of Superfluid Helium.

We present an experimental and theoretical study of the 2D dynamics of electrically charged nanoparticles trapped under a free surface of superfluid helium in a static vertical electric field. We focus on the dynamics of particles driven by the interaction with quantized vortices terminating at the free surface. We identify two types of particle trajectories and the associated vortex structures: vertical linear vortices pinned at the bottom of the container and half-ring vortices traveling along the free surface of the liquid.

Taylor cone and electrospraying at a free surface of superfluid helium charged from below.

Electrically charged metallic micro- and nanoparticles are trapped under a free surface of superfluid He in a vertical static electric field. We observe a static deformation of the charged liquid surface in the form of a Taylor cone and the emission of a charged liquid helium jet (electrospray). Our numeric calculations reproduce the static shape of the cone.

Metallic nanowires and mesoscopic networks on a free surface of superfluid helium and charge-shuttling across the liquid-gas interface.

We investigate the motion of electrically charged metallic nano- and microparticles produced by laser ablation in He gas and injected into superfluid helium. In the presence of a vertical static electric field, the particles either perform a repetitive shuttle-like motion transporting the charge across the liquid-gas interface or become trapped under the free surface of liquid He and coalesce into long filaments and complex two-dimensional mesoscopic networks. A classical electrohydrodynamic model is used to describe the motion of charged microparticles in superfluid He. The resulting filaments and networks are analyzed using electron microscopy. It is demonstrated that each filament is in fact composed of a large number of nanowires with a characteristic diameter of order of 10 nm and extremely large aspect ratios.

Enhanced reactivity and related optical changes of Ag nanoparticles on amorphous Al2O3 supports.

Pairs of samples containing Ag nanoparticles (NPs) of different dimensions have been produced under the same conditions but on different substrates, namely standard glass slides and a thin layer of amorphous aluminum oxide (a-Al2O3) on-glass. Upon storage in ambient conditions (air and room temperature) the color of samples changed and a blue-shift and damping of the surface plasmon resonance was observed. The changes are weaker for the samples on-glass and tend to saturate after 12 months. In contrast, the changes for the samples on a-Al2O3 appear to be still progressing after 25 months. While x-ray photoelectron spectroscopy shows a slight sulfurization and negligible oxidation of the Ag for the on-glass samples upon 25 months aging, it shows that Ag is strongly oxidized for the on a-Al2O3 samples and sulfurization is negligible. Both optical and chemical results are consistent with the production of a shell at the expense of a reduction of the metal core dimensions, the latter being responsible for the blue-shift and related to the small (<10 nm initial diameter) of the NPs. The enhanced reactivity of the Ag NPs on the a-Al2O3 supports goes along with specific morphological changes of the Ag NPs and the observation of nitrogen.

Transient increase of the energy gap of superconducting NbN thin films excited by resonant narrow-band terahertz pulses.

Observations of radiation-enhanced superconductivity have thus far been limited to a few type-I superconductors (Al, Sn) excited at frequencies between the inelastic scattering rate and the superconducting gap frequency 2Δ/h. Utilizing intense, narrow-band, picosecond, terahertz pulses, tuned to just below and above 2Δ/h of a BCS superconductor NbN, we demonstrate that the superconducting gap can be transiently increased also in a type-II dirty-limit superconductor. The effect is particularly pronounced at higher temperatures and is attributed to radiation induced nonthermal electron distribution persisting on a 100 ps time scale.

Non-monotonic crossover from single-file to regular diffusion in micro-channels.

The diffusion behavior of interacting particles determines the behavior of a large number of systems ranging from pedestrians crossing a road to ions passing through channels in living cells. Here we present a system in which the nature of the diffusion process varies with changes in the external conditions. We find this special behavior in a colloidal model system, consisting of micron sized particles which are confined to narrow channels and interact via induced magnetic dipoles. When the density of these particles is changed, diffusion alternates between normal Fickian behavior and single-file diffusion. This anomalous behavior is induced by the order of the particles in the restricted geometry and does not depend on the exact nature of the inter-particle interactions.

Energy-gap dynamics of superconducting NbN thin films studied by time-resolved terahertz spectroscopy.

Using time-domain terahertz spectroscopy we performed direct studies of the photoinduced suppression and recovery of the superconducting gap in a conventional BCS superconductor NbN. Both processes are found to be strongly temperature and excitation density dependent. The analysis of the data with the established phenomenological Rothwarf-Taylor model enabled us to determine the bare quasiparticle recombination rate, the Cooper pair-breaking rate and the electron-phonon coupling constant, λ=1.1±0.1, which is in excellent agreement with theoretical estimates.

Point-contact transport properties of strongly correlated electrons on liquid helium.

We present transport measurements of a nondegenerate two-dimensional electron system on the surface of liquid helium at a point constriction. The constriction is formed in a microchannel by a split gate beneath the helium surface. The electrostatic energy of the electron system, which depends in part on the electron density, determines the split-gate voltage threshold of current flow through the constriction. Steplike increases in conductance are observed as the confinement strength is reduced. As the Coulomb interaction between electrons is strong, we attribute this effect to the increase in the number of electrons that can pass simultaneously through the constriction. Close to the threshold, single-electron transport is observed.

Density reduction and diffusion in driven two-dimensional colloidal systems through microchannels.

The behavior of particles driven through a narrow constriction is investigated in experiment and simulation. The system of particles adapts to the confining potentials and the interaction energies by a self-consistent arrangement of the particles. It results in the formation of layers throughout the channel and of a density gradient along the channel. The particles accommodate to the density gradient by reducing the number of layers one by one when it is energetically favorable. The position of the layer reduction zone fluctuates with time while the particles continuously pass this zone. The flow behavior of the particles is studied in detail. The velocities of the particles and their diffusion behavior reflect the influence of the self-organized order of the system.

Generation of surface energy patterns by single pulse laser interference on self-assembled monolayers.

Single pulse laser interference lithography is used to structure self-assembled monolayers of thiols on gold. This structuring process is investigated by attenuated total reflection measurements, and a demixing process of a binary polymer blend is used to visualize the produced surface energy pattern. The lithography can be realized with different wavelengths (266, 532, and 1064 nm) which shows that the structuring is a thermal process. As a first demonstration of this process, structures down to 800 nm period and 300 nm width are fabricated.

Influence of chopped laser light onto the electronic transport through atomic-sized contacts.

This paper reports on the influence of laser irradiation onto the electrical conductance of gold nanocontacts established with the mechanically controllable breakjunction technique. We concentrate here on the study of reversible conductance changes which can be as high as 200%. We investigate the dependence on the initial conductance of the contacts, the wavelength, the intensity and position of the laser spot with respect to the sample. Under most conditions an enhancement of the conductance is observed. We discuss several physical mechanisms which might contribute to the observed effect including thermal expansion, rectification and photon-assisted transport. We conclude that thermal expansion is not the dominating one.

Influence of laser light on electronic transport through atomic-size contacts.

This Letter reports on the influence of laser irradiation onto the electrical conductance of gold nanocontacts established with the mechanically controllable break-junction technique. We concentrate on the study of reversible conductance changes which can be as high as 200%. We investigate the dependence on the initial conductance of the contacts, and on the wavelength, the intensity, and the position of the laser spot with respect to the sample. Under most conditions an enhancement of the conductance is observed. Several physical mechanisms which might contribute to the observed effect including thermal expansion, rectification, plasmon excitation, and photon-assisted transport are discussed, among which the two latter ones are most likely the dominating ones.

Characterization of magnetic colloids by means of magnetooptics.

A new, efficient method for the characterization of magnetic colloids based on the Faraday effect is proposed. According to the main principles of this technique, it is possible to detect the stray magnetic field of the colloidal particles induced inside the magnetooptical layer. The magnetic properties of individual particles can be determined providing measurements in a wide range of magnetic fields. The magnetization curves of capped colloids and paramagnetic colloids were measured by means of the proposed approach. The registration of the magnetooptical signals from each colloidal particle in an ensemble permits the use of this technique for testing the magnetic monodispersity of colloidal suspensions.

Layer reduction in driven 2D-colloidal systems through microchannels.

The transport behavior of a system of gravitationally driven superparamagnetic colloidal particles is investigated. The motion of the particles through a narrow channel is governed by magnetic dipole interactions, and a layered structure forms parallel to the walls. The arrangement of the particles is perturbed by diffusion and the motion induced by gravity leading to a density gradient along the channel. Our main result is the reduction of the number of layers. Experiments and Brownian dynamics simulations show that this occurs due to the density gradient along the channel.

Jumping nanodroplets.

Flat gold nanostructures on inert substrates like glass or graphite were illuminated by single intensive laser pulses with fluences above the gold melting threshold. The liquid structures produced in this way are far from their equilibrium shape, and a dewetting process sets in. On a time scale of a few nanoseconds, the liquid contracted toward a sphere. During this contraction, the center of mass moved upward, which could lead to detachment of droplets from the surface due to inertia. The resulting velocities were on the order of 10 meters per second for droplets with radii in the range of 100 nanometers.

Direct measurement of entropic forces induced by rigid rods.

We present the first direct depletion potential measurements for a single colloidal sphere close to a wall in a suspension of rigid colloidal rods. Since all particle interactions are as good as hard-core-like, the depletion potentials are of entirely entropic origin. We developed a density functional theory approach that accurately accounts for this experimental situation. The depletion potentials calculated for different rod number densities are in very good quantitative agreement with the experimental results.

Triple-point wetting on rough substrates.

The influence of substrate roughness on the wetting scenario of adsorbed van der Waals films is investigated by theory and experiment. Calculating the bending free energy penalty of a solid sheet picking up the substrate roughness, we show that a finite roughness always leads to triple-point wetting reducing the widths of the adsorbed solid films considerably as compared to that of smooth substrates. Testing the theory against our experimental data for molecular hydrogen adsorbed on gold, we find quantitative agreement.

Local field enhancement effects for nanostructuring of surfaces.

We report on a method that allows the nanostructuring of surfaces with intense laser pulses. For this purpose isolated polystyrene spheres with diameters in the order of the laser wavelength were deposited on a silicon or glass surface. Illumination with short and ultrashort laser pulses produced holes underneath these particles. Calculations of the field near the particles make clear that geometrical optics, that is, focusing by a spherical lens, as well as near-field effects, contribute to the size and shape of these holes. This technique can be utilized for the parallel structuring of large surface areas with a single laser shot.