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1.
Materials (Basel) ; 12(2)2019 Jan 09.
Artigo em Inglês | MEDLINE | ID: mdl-30634420

RESUMO

Implementation of new energy efficiency measures for the heating and building sectors is of utmost importance. Demand side management offers means to involve individual buildings in the optimization of the heat demand at city level to improve energy efficiency. In this work, two models were applied to forecast the heat demand from individual buildings up to a city-wide area. District heating data at the city level from more than 4000 different buildings was utilized in the validation of the forecast models. Forecast simulations with the applied models and measured data showed that, during the heating season, the relative error of the city level heat demand forecast for 48 h was 4% on average. In individual buildings, the accuracy of the models varied based on the building type and heat demand pattern. The forecasting accuracy, the limited amount of measurement information and the short time required for model calibration enable the models to be applied to the whole building stock. This should enable demand side management and lead to the predictive optimization of heat demand at city level, leading to increased energy efficiency.

2.
Materials (Basel) ; 12(1)2018 Dec 21.
Artigo em Inglês | MEDLINE | ID: mdl-30577608

RESUMO

An advanced model-based control method for the integrated fuel processing and a fuel cell system consisting of ethanol reforming, hydrogen purification, and a proton exchange membrane fuel cell is presented. For process identification, a physical model of the process chain was constructed. Subsequently, the simulated process was approximated with data-driven control models. Based on these control models, a hierarchical control framework consisting of model predictive controller and a global optimization algorithm was introduced. The performance of the new control method was evaluated with simulations. Results indicate that the new optimization concept enables resource efficient and fast control of the studied energy conversion process. Fast and efficient fuel cell process could then provide sustainable power source for autonomous and mobile applications in the future.

3.
Environ Technol ; 39(24): 3193-3202, 2018 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-28862059

RESUMO

New monitoring methods are required to enhance the operation of a wastewater treatment process and to meet the constantly tightening regulations for the effluent discharges. An on-line optical monitoring device, that analyses the morphological parameters of the flocs, has been shown to be a potential tool for assessing the wastewater quality and the state of the activated sludge process. In this paper, the earlier presented trend analysis method is applied to the operating conditions, the treatment results and the optical monitoring variables of a full-scale biological wastewater treatment process. The trend episodes and the deviation indices resulted from the trend analysis provide warning of the changes in the monitored variables and the received information can be used as assistance in the treatment process operation and avoiding harmful environmental risks.


Assuntos
Dispositivos Ópticos , Águas Residuárias , Esgotos , Eliminação de Resíduos Líquidos
4.
Environ Technol ; 39(11): 1442-1449, 2018 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-28504018

RESUMO

Traditionally the modelling in an activated sludge process has been based on solely the process measurements, but as the interest to optically monitor wastewater samples to characterize the floc morphology has increased, in the recent years the results of image analyses have been more frequently utilized to predict the characteristics of wastewater. This study shows that the traditional process measurements or the automated optical monitoring variables by themselves are not capable of developing the best predictive models for the treated wastewater quality in a full-scale wastewater treatment plant, but utilizing these variables together the optimal models, which show the level and changes in the treated wastewater quality, are achieved. By this early warning, process operation can be optimized to avoid environmental damages and economic losses. The study also shows that specific optical monitoring variables are important in modelling a certain quality parameter, regardless of the other input variables available.


Assuntos
Águas Residuárias , Qualidade da Água , Automação , Óptica e Fotônica , Esgotos , Eliminação de Resíduos Líquidos
5.
Environ Technol ; 38(1): 1-13, 2017 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-27109694

RESUMO

A novel optical monitoring device was used for imaging an activated sludge process in situ during a period of over one year. In this study, the dependencies between the results of image analysis and the process measurements were studied, and the optical monitoring results were utilized to predict the important quality parameters for the wastewater treatment process efficiency: suspended solids, biological oxygen demand, chemical oxygen demand, total nitrogen and total phosphorous in biologically treated wastewater. The optimal subsets of variables for each model were searched using five variable selection methods. It was shown that online optical analysis results have clear dependencies on some process variables and the purification result. The model based on optical monitoring and process variables from the early stage of the treatment process can be used to predict the levels of important quality parameters, and to show the quality of the biologically treated wastewater hours in advance. This study confirms that the optical monitoring method is a valuable tool for monitoring a wastewater treatment process and receiving new information in real time. Combined with predictive modelling, it has the potential to be used in process control, keeping the process in a stable operating condition and avoiding environmental risks.


Assuntos
Modelos Teóricos , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/análise , Análise da Demanda Biológica de Oxigênio , Nitrogênio/análise , Fenômenos Ópticos , Fósforo/análise , Poluentes da Água/análise
6.
J Water Health ; 14(3): 433-42, 2016 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-27280609

RESUMO

Monitoring and control of water treatment plants play an essential role in ensuring high quality drinking water and avoiding health-related problems or economic losses. The most common quality variables, which can be used also for assessing the efficiency of the water treatment process, are turbidity and residual levels of coagulation and disinfection chemicals. In the present study, the trend indices are developed from scaled measurements to detect warning signs of changes in the quality variables of drinking water and some operating condition variables that strongly affect water quality. The scaling is based on monotonically increasing nonlinear functions, which are generated with generalized norms and moments. Triangular episodes are classified with the trend index and its derivative. Deviation indices are used to assess the severity of situations. The study shows the potential of the described trend analysis as a predictive monitoring tool, as it provides an advantage over the traditional manual inspection of variables by detecting changes in water quality and giving early warnings.


Assuntos
Água Potável/análise , Monitoramento Ambiental/métodos , Qualidade da Água , Finlândia , Modelos Teóricos , Purificação da Água
7.
Environ Technol ; 37(3): 344-51, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26238162

RESUMO

One activated sludge process line was optically monitored in situ by a novel image analysis equipment. The results of the image analysis were studied to find out dependencies to the process variables of the wastewater treatment plant (WWTP) and to the quality of the treated wastewater. The quality parameter of the treated wastewater, suspended solids, was modelled using the image analysis results. The model can be used for evaluating the performance of the WWTP and for the better control for stable effluent quality. It was shown that the results of the online optical monitoring reveal useful information from the process and can be used in forecasting the quality of biologically treated wastewater. The optical monitoring method together with process measurements has an important role in keeping the process in stable operating conditions and avoiding environmental risks.


Assuntos
Processamento de Imagem Assistida por Computador/métodos , Esgotos/química , Águas Residuárias/química , Purificação da Água/métodos , Finlândia , Modelos Teóricos , Imagem Óptica
8.
J Water Health ; 12(2): 230-41, 2014 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-24937217

RESUMO

One of the common quality parameters for drinking water is residual aluminium. High doses of residual aluminium in drinking water or water used in the food industry have been proved to be at least a minor health risk or even to increase the risk of more serious health effects, and cause economic losses to the water treatment plant. In this study, the trend index is developed from scaled measurement data to detect a warning of changes in residual aluminium level in drinking water. The scaling is based on monotonously increasing, non-linear functions, which are generated with generalized norms and moments. Triangular episodes are classified with the trend index and its derivative. The severity of the situations is evaluated by deviation indices. The trend episodes and the deviation indices provide good tools for detecting changes in water quality and for process control.


Assuntos
Alumínio/análise , Monitoramento Ambiental/métodos , Poluentes Químicos da Água/análise , Qualidade da Água , Finlândia , Modelos Teóricos , Dinâmica não Linear , Estações do Ano
9.
Drug Dev Ind Pharm ; 39(11): 1802-8, 2013 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-23163644

RESUMO

CONTEXT: Continuous processing is becoming popular in the pharmaceutical industry for its cost and quality advantages. OBJECTIVE: This study evaluated the mechanical properties, uniformity of dosage units and drug release from the tablets prepared by continuous direct compression process. MATERIALS AND METHODS: The tablet formulations consisted of acetaminophen (3-30% (w/w)) pre-blended with 0.25% (w/w) colloidal silicon dioxide, microcrystalline cellulose (69-96% (w/w)) and magnesium stearate (1% (w/w)). The continuous tableting line consisted of three loss-in-weight feeders and a convective continuous mixer and a rotary tablet press. The process continued for 8 min and steady state was reached within 5 min. The effects of acetaminophen content, impeller rotation rate (39-254 rpm) and total feed rate (15 and 20 kg/h) on tablet properties were examined. RESULTS AND DISCUSSION: All the tablets complied with the friability requirements of European Pharmacopoeia and rapidly released acetaminophen. However, the relative standard deviation of acetaminophen content (10% (w/w)) increased with an increase in impeller rotation rate at a constant total feed rate (20 kg/h). A compression force of 12 kN tended to result in greater tablet hardness and subsequently a slower initial acetaminophen release from tablets when compared with those made with the compression force of about 8 kN. CONCLUSIONS: In conclusion, tablets could be successfully prepared by a continuous direct compression process and process conditions affected to some extent tablet properties.


Assuntos
Acetaminofen/química , Analgésicos não Narcóticos/química , Celulose/química , Excipientes/química , Modelos Moleculares , Dióxido de Silício/química , Ácidos Esteáricos/química , Automação , Fenômenos Químicos , Coloides , Composição de Medicamentos , Finlândia , Dureza , Cinética , Fenômenos Mecânicos , Controle de Qualidade , Solubilidade , Comprimidos , Tecnologia Farmacêutica , Resistência à Tração
10.
Environ Technol ; 31(5): 555-66, 2010 Apr 14.
Artigo em Inglês | MEDLINE | ID: mdl-20480830

RESUMO

A mathematical model modified from the well established Activated Sludge Model no. 1 was used for modelling a full-scale wastewater treatment plant (WWTP) in a bleached kraft pulp mill. Effluents from the pulp and paper industry are typically nutrient deficient, which was considered in the model. The wastewater characterization and model calibration were based on respirometric batch experiments with sludge and wastewater sampled from the WWTP. The model performance was validated in a long-term simulation using routinely measured process data from the WWTP as the model inputs. The simulation results proved useful in evaluating nutrient dosage strategies at the WWTP and in troubleshooting poor treatment plant performance. However, in order to achieve a completely accurate description of nitrogen removal, more complex phenomena would have to be included in the model. Even though the simulated period was long compared to the brief measurement campaign used in the model calibration, the model was able to describe the treatment plant's behaviour. The calibrated model can be expected to stay valid for a long time, which allows the use of deterministic modelling in practical applications at pulp and paper WWTPs.


Assuntos
Resíduos Industriais , Purificação da Água/métodos , Biodegradação Ambiental , Calibragem , Simulação por Computador , Hidrólise , Modelos Estatísticos , Nitrogênio , Oxigênio/química , Esgotos , Fatores de Tempo , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/isolamento & purificação
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