Silane influence on bonding to CAD-CAM composites: An interfacial fracture toughness study.

OBJECTIVES: To evaluate silane influence on the interfacial fracture toughness (IFT) of composite cement, with the two sub-classes of CAD-CAM composites, polymer-infiltrated ceramic networks (PICN) and dispersed fillers (DF), after hydrofluoric acid etching (HF) or airborne-particle abrasion (AB). A secondary objective was to correlate results with developed interfacial area ratio (Sdr) and surface wettability. METHODS: Experimental PICN and DF blocks were cut into equilateral half-prisms, which were treated with HF or AB, then treated with an experimental silane or not and bonded to their counterparts with an experimental light-cure resin cement. After thermocycling, samples (n=30 per group) were tested for IFT using the notchless triangular prism test in a water bath at 36°C. Moreover, profilometry and contact angle measurement were performed on rectangular samples of each group. Finally, bonding interface was analysed by SEM. RESULTS: PICN-HF treated with silane showed the highest IFT significantly. Three-way ANOVA revealed the influence of silane, material class and surface pre-treatment (HF or AB) on IFT (p<0.05). When silane was used, IFT was correlated with Sdr, while surface wettability was increased. Silane application significantly increased IFT for PICN but not for DF, while PICN performed better with HF and DF with AB. SIGNIFICANCE: Silane increases IFT of composite cement with PICNs, but not with DF materials. Results suggest that silane increases the micromechanical bond by promoting resin cement spreading and penetration in surface roughness. This roughness is significantly higher for pre-treated PICNs than for DF due to their specific honeycomb microstructure when etched, which explains their better bonding properties.

Flat Fresnel doublets made of PMMA and PC: combining low cost production and very high concentration ratio for CPV.

The linear chromatic aberration (LCA) of several combinations of polycarbonates (PCs) and poly (methyl methacrylates) (PMMAs) as singlet, hybrid (refractive/diffractive) lenses and doublets operating with wavelengths between 380 and 1600 nm - corresponding to a typical zone of interest of concentrated photovoltaics (CPV) - are compared. Those comparisons show that the maximum theoretical concentration factor for singlets is limited to about 1000 × at normal incidence and that hybrid lenses and refractive doublets present a smaller LCA increasing the concentration factor up to 5000 × and 2 × 10(6) respectively. A new achromatization equation more useful than the Abbé equation is also presented. Finally we determined the ideal position of the focal point as a function of the LCA and the geometric concentration which maximizes the flux on the solar cell.

High transmission efficiency for surface plasmon resonance by use of a dielectric grating.

The efficiency of the transmission of surface plasmon waves by use of a dielectric diffraction grating is discussed. The Kretschmann device allows us to obtain a surface plasmon resonance that consists of an absorption peak in the reflection spectrum. When surface plasmon resonance occurs, the TM-polarization mode of the incident electromagnetic wave is neither transmitted nor reflected. The procedure to transform an 4bsorption peak into a transmission peak is described. Transmittivity of 68% is obtained for a simple structure that consists of a thin-film layer of Ag coated on a volume diffraction grating and embedded between two dielectric media. The results presented herein were obtained by numerical simulations that were carried out by use of an algorithm based on the rigorous coupled-wave theory.

Use of subwavelength gratings in TIR incidence as achromatic phase shifters.

Nulling interferometry constitutes a very promising technique in observational astrophysics. This method consists in attenuating the signal of a bright astrophysical object in order to detect much fainter nearby features, e.g. exoplanets around their host star. An on-axis destructive interference is created by adjusting the phases of the beams coming from various telescopes. The huge flux ratio between the parent star and the planet (106 in the thermal infrared) requires unprecedented high performance broadband phase shifters. We present a new design for these key components called Achromatic Phase Shifters (APS). We propose to use subwavelength diffractive optical elements under total internal reflection (TIR) incidence. Our component can be seen as an evolution of the Fresnel Rhomb technology.