Fluctuotaxis: Nanoscale directional motion away from regions of fluctuation.

Regulating the motion of nanoscale objects on a solid surface is vital for a broad range of technologies such as nanotechnology, biotechnology, and mechanotechnology. In spite of impressive advances achieved in the field, there is still a lack of a robust mechanism which can operate under a wide range of situations and in a controllable manner. Here, we report a mechanism capable of controllably driving directed motion of any nanoobjects (e.g., nanoparticles, biomolecules, etc.) in both solid and liquid forms. We show via molecular dynamics simulations that a nanoobject would move preferentially away from the fluctuating region of an underlying substrate, a phenomenon termed fluctuotaxis-for which the driving force originates from the difference in atomic fluctuations of the substrate behind and ahead of the object. In particular, we find that the driving force can depend quadratically on both the amplitude and frequency of the substrate and can thus be tuned flexibly. The proposed driving mechanism provides a robust and controllable way for nanoscale mass delivery and has potential in various applications including nanomotors, molecular machines, etc.

Nanoscale directional motion by angustotaxis.

Directing motion of a nanoscale object on solid surfaces, in particular in an intrinsic way, is crucial for many aspects of nanotechnology applications. Here we report a novel intrinsic mechanism for nanoscale directional motion, termed angustotaxis, where a wide single walled carbon nanotube in a tapered channel drives itself toward the narrower end of the channel. The underlying physics of angustotaxis is attributed to the lower system potential when the nanotube is at a narrower region of the channel due to the increased contact area between the nanotube and the channel. Angustotaxis could lead to promising routes not only for nanoscale energy conversion from van der Waals potential to mechanical work, but also for mass transport like surface cleaning.

An intrinsic energy conversion mechanism via telescopic extension and retraction of concentric carbon nanotubes.

The conversion of other forms of energy into mechanical work through the geometrical extension and retraction of nanomaterials has a wide variety of potential applications, including for mimicking biomotors. Here, using molecular dynamics simulations, we demonstrate that there exists an intrinsic energy conversion mechanism between thermal energy and mechanical work in the telescopic motions of double-walled carbon nanotubes (DWCNTs). A DWCNT can inherently convert heat into mechanical work in its telescopic extension process, while convert mechanical energy into heat in its telescopic retraction process. These two processes are nearly thermodynamically reversible. The underlying mechanism for this energy conversion is that the configurational entropy changes with the telescopic overlapping length of concentric individual tubes. We also find that the entropy effect enlarges with the decreasing intertube space of DWCNTs. As a result, the spontaneous telescopic motion of a condensed DWCNT can be switched to extrusion by increasing the system temperature above a critical value. These findings are important for fundamentally understanding the mechanical behavior of concentric nanotubes, and may have general implications in the application of DWCNTs as linear motors in nanodevices.

Negative Thermophoresis in Concentric Carbon Nanotube Nanodevices.

Positive and negative thermophoresis in fluids has found widespread applications from mass transport to molecule manipulation. In solids, although positive thermophoresis has been recently discovered in both theoretical and experimental studies, negative thermophoresis has never been reported. Here we reveal via molecular dynamics simulations that negative thermophoresis does exist in solids. We consider the motion of a single walled carbon nanotube nested inside of two separate outer tubes held at different temperatures. It is found that a sufficiently long inner tube will undergo negative thermophoresis, whereas positive thermophoresis is favorable for a relatively short inner tube. Mechanisms for the observed positive thermophoresis and negative thermophoresis are shown to be totally different. In positive thermophoresis, the driving force comes mainly from the thermally induced edge force and the interlayer attraction force, whereas the driving force for negative thermophoresis is mainly due to the thermal gradient force. These findings have enriched our knowledge of the fundamental driving mechanisms for thermophoresis in solids and may stimulate its further applications in nanotechnology.