An Ultrahighly Stretchable and Recyclable Starch-Based Gel with Multiple Functions.

With the development of various gel-based flexible sensors, novel gels with multiple integrated and efficient properties, particularly recyclability, have been developed. Herein, a starch-based ADM (amylopectin (AP)-poly(3-[dimethyl-[2-(2-methylprop-2- enoyloxy)ethyl]azaniumyl]propane-1-sulfonate) (PDMAPS)-MXene) gel is prepared by a facile "cooking" strategy accompanying the gelatinization of AP and polymerization reaction of zwitterionic monomers. Reversible crosslinking in the gel occurs through hydrogen bonding and electrostatic interactions. The ADM gel exhibits high stretchability (≈2700%, after one month), swift self-healing performance, self-adhesive properties, favorable freezing resistance, and satisfactory moisturizing properties (≥30 days). Interestingly, the ADM gel can be recycled and reused by a "kneading" method and "dissolution-dialysis" process, respectively. Furthermore, the ADM gel can be assembled as a strain sensor with a broad working strain range (≈800%) and quick response time (response time 211 ms and recovery time 253 ms, under 10% strain) to detect various macro- and micro-human-motions, even under harsh conditions such as pronunciation and handwriting. The ADM gel can also be used as a humidity sensor to investigate humidity and human respiratory status, suggesting its practical application in personal health management. This study provides a novel strategy for the preparation of high-performance recycled gels and flexible sensors.

High-stretchable, self-healing, self-adhesive, self-extinguishing, low-temperature tolerant starch-based gel and its application in stimuli-responsiveness.

Starch with active hydroxyl groups is one of the most attractive carbohydrates for the preparation of gels in recent years. However, the mechanical properties, self-healing properties, self-adhesion properties, especially low-temperature resistance are generally unsatisfactory for current starch-based gels. Based on that, a multiple network structure of amylopectin-carboxymethyl cellulose-polyacrylamide (ACP) gel was prepared by a "cooking" method. Tannic acid (TA) was used to construct multiple hydrogen bonds among molecular chains. ACP gel demonstrates high elongation at break (1090 %) and strength, self-healing performance and adhesion behavior, extraordinary low-temperature resistance (-80 °C) and self-extinguishing. As a sensor device, ACP gel can effectively monitor human movements and microscopic expression changes and achieve real-time monitoring under harsh conditions (After multiple cutting-healing steps, under low-temperature conditions, even a month later). Additionally, ACP gel could be served to detect temperature changes with a wide operating range and a high sensitivity of 33 %·°C-1, which is promising to monitor the changes in temperature. More interestingly, ACP gel can even monitor the cooking process and breathing frequency with fast response, implying applications in food processing, disease diagnosis and medical treatment. This study provides new opportunities for the design and fabrication of carbohydrate-based gels with multiple performance and multifunctional electronic devices.