RESUMO
Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.
RESUMO
The introduction and removal of a phase tag have been used to trigger cyclization events in a new synthesis of benzo[b]carbazoles. The approach has been exploited in a tag-assisted approach to new benzo[b]carbazole end-capped oligothiophenes for preliminary evaluation as semiconductors.