[Potential Risk and Distribution Characteristics of PPCPs in Surface Water and Sediment from Rivers and Lakes in Beijing, China].

Thirty-four water samples and twenty-three sediment samples from the urban rivers, ten water samples and five sediment samples from urban lakes were collected in Beijing. Ten PPCPs (acetaminophen, lincomycin, caffeine, trimethoprim, azithromycin, sulfamethoxazole, diltiazem, tylosin, carbamazepine, fluoxetine) were extracted from water samples by solid-phase extraction (SPE) and from sediment samples by ultrasonic extraction, and then analyzed by high-performance liquid chromatography coupled with tandem mass spectrometry (HPLC-MS/MS). The ranges of geometric mean values were 0-655 ng·L-1 and 0-252 ng·L-1 in water samples from urban rivers and lakes,respectively. The range of detection ratio was 0-100% for 10 PPCPs in river water samples, caffeine was the dominant pollutant in water samples and the detection ratio was 100%, whereas sulfamethoxazole, diltiazem and tylosin were not detected in river samples. The range of detection ratio was 0-100% for 10 PPCPs in lake water samples. The detection ratios of acetaminophen, lincomycin, caffeine and azithromycin were 100%, whereas sulfamethoxazole, diltiazem, tylosin, carbamazepine were not detected in lake water samples. The ranges of geometric mean values were N.D.-1709 ng·g-1and N.D.-35.9 ng·g-1in sediment samples from urban rivers and lakes, respectively. The ranges of detection ratio were 4%-96% and 0-100% for 10 PPCPs in river and lake sediment samples, respectively. The detection ratio of trimethoprim was 96% and that of tylosin was 4% in river sediment, the detection ratio of diltiazem was 100% and caffeine, tylosin,carbamazepine were not detected. The concentrations of PPCPs in water and sediment samples from Yongyin River, Liangshui River, Tonghui River, Bahe River were higher than those in other rivers. The concentrations of PPCPs in water and sediment samples from Yongding River,Kunyu River were lower than those in other rivers. Further risk assessment results showed that the overall risk was not high in water of rivers and lakes and the RQ values were below 0.1, which showed low risk to microorganisms. But the condition was not the same in sediment from rivers and lakes. The RQ values of acetaminophen were between 0.1 and 1 in sediments from Yongyin River, Tonghui River, Bahe River. The RQ values of lincomycin were between 0.1 and 1 in sediments from Yongyin River, Wenyu River,Tonghui River, Hucheng River, Bahe River, Liangshui River, Houhai Lake. The RQ values of trimethoprim were between 0.1 and 1 in sediments from Yongyin River, Qinghe River, Wenyu River, Tonghui River Hucheng River, Bahe River, Liangma River, Liangshui River and Houhai Lake. The RQ values of azithromycin were between 0.1 and 1 in sediments from Liangma River, Liangshui River, which all showed medium risk to microorganisms in sediments. The RQ values of azithromycin exceeded 1 from Yongyin River, Qinghe River, Wenyu River, Tonghui River, Bahe River and Houhai Lake, which showed high risk to microorganisms in sediments.

[Pollution Characteristics of Chlorobenzenes in Organs of Fish from Typical Epidemic Areas of Schistosomiasis Prevalence].

Sixty-eight fish samples were collected from typical epidemic areas of schistosomiasis prevalence. The contents of 12 CB congeners in fish samples were measured using GC/MS technique. The results indicated that 1,3-DIC, 1,4-DIC, 1,2-DIC and HCB were the most predominant CB congeners in the samples from the studying area. The source of HCB was PCP (pentachlorophenol), which was used to control the schistosomiasis prevalence, used in study area. And DIC came from the degradation of HCB and the articles of daily use. The geometric average of CBs in muscle ranged from 2731.50 to 7811.23 ng·g-1 lipid weight, while the summarized concentration of CBs in fish gonads, brains, kidneys, livers ranged from 2557.89 to 4640.05 ng·g-1 lipid weight, 2423.18 to 3329.61 ng·g-1 lipid weight, 1628.05 to 4667.76 ng·g-1 lipid weight and 704.92 to 1086.96 ng·g-1 lipid weight, respectively. When compared to other studies in China and other countries, the concentrations of CBs in these fish samples were at a relatively high level.

[Spatial, Temporal Distribution Characteristics and Potential Risk of PPCPs in Surface Sediments from Taihu Lake].

Fourteen sediment samples from 15 river estuaries and six sediments from 6 drinking water resource were collected from Taihu Lake. Nine pharmaceutical and personal care products(PPCPs) in the sediments samples were measured by using the HPLC-MS/MS technique. The ranges of geometric mean values were 1.60-129 ng·g-1 and 1.36-22.0 ng·g-1, respectively. Caffeine was the dominant pollutant in fourteen sediments near the river estuary, the content of which covered 52% of amounts of 9 PPCPs. Lincomycin, trimethoprime, azithromycin, sulfamethoxazole and tylosin were the dominant pollutants in six sediments near the drinking water resource, the contents of which covered 79% of amounts 9 PPCPs. From the point of spatial distribution, the results of PPCPs in Zhushan bay and East of Yixing in the northwest and west of Taihu Lake showed higher concentration than those in other sample sites. From the composition, the origin of PPCPs was different. Municipal sewage, stock farming and aquaculture were the main sources of PPCPs in Taihu Lake. Pharmaceuticals of human use showed the dominant pollution in fourteen sediments near the river estuary and drugs of veterinary use showed the dominant pollution in six sediments near the water resource. The concentrations of PPCPs in fourteen sediments of river mouth showed high level. It suggested that PPCPs pollutants were discharged to Taihu Lake continuously. Further risk assessment results showed that the overall risk was not high except for some PPCPs compounds. The RQ exceeded 1 for acetaminophen, azithromycin and sulfamethoxazole in the surface sediments of 15 river estuaries and 6 water resources, which showed high risk. The RQ was between 0.01 to 0.1 for carbazepine in the surface sediments of 15 river estuaries and 6 water resources, which showed medium risk. The RQ was below 0.01 for caffeine, lincomycin, trimethoprim, diltiazem and tylosin in the sediments of 15 river estuaries and 6 water resources, which showed low risk.

Tris-(nitrato-κ(2)O,O')bis[4,4,5,5-tetra-methyl-2-(pyridin-2-yl-κN)imidazoline-1-oxyl 3-oxide-κO]holmium(III).

In the title compound, [Ho(NO(3))(3)(C(12)H(16)N(3)O(2))(2)], the Ho(III) ion is ten-coordinated in a distorted bicapped square-anti-prismatic environment by two N,O-bidentate nitronyl nitroxide radical ligands and three O,O'-bidentate nitrate anions. Complex mol-ecules are connected by C-H⋯O hydrogen bonds into a three-dimensional network.

Bis[4,4,5,5-tetra-methyl-2-(pyridin-2-yl-κ(2)N)imidazoline-1-oxyl 3-oxide-κO]tris-(nitrato-κ(2)O,O')terbium(III).

The title compound, [Tb(NO(3))(3)(C(12)H(16)N(3)O(2))(2)], was prepared from the nitroxide radical ligand 4,4,5,5-tetra-methyl--2-(pyridin-2-yl)-imidazoline-1-oxyl-3-oxide and Tb(III) nitrate. The Tb(III) ion adopts a doubly-capped square-anti-prismatic coord-ination environment defined by three chelating nitrate anions and two N,O-bidentate nitronyl nitroxide radical ligands. Weak C-H⋯O hydrogen bonds connect the molecules into a three-dimensional framework. The title structure is isotypic with the Ho analogue [Li (2012 ▶). Acta Cryst. E68, 550].