Zero-field-cooling exchange bias up to room temperature in the strained kagome antiferromagnet Mn3.1Sn0.9.

Zero-field-cooling exchange bias (ZFC EB) has always been a research hotspot for researchers, because it can realize the movement of the magnetization hysteresis loop along the field axis without field cooling, which greatly expands the universality and convenience of the application of the exchange bias effect. Achieving ZFC EB at room temperature is an ongoing challenge. To this end, a design strategy from the sublattice level is proposed, and a wide temperature range ZFC EB up to room temperature with a vertical magnetization shift is observed in the strained kagome antiferromagnet Mn3.1Sn0.9. Magnetic analysis and first-principles calculations reveal that the ZFC EB arises from the strong exchange interaction between the non-coplanar antiferromagnetic Mn kagome sublattice occupying normal Mn sites and the collinear ferromagnetic Mn sublattice occupying Sn sites. This discovery is of great significance for the application of ZFC EB in antiferromagnetic spintronic devices.

Flexible Hybrid Photo-Thermoelectric Generator Based on Single Thermoelectric Effect for Simultaneously Harvesting Thermal and Radiation Energies.

Wearable electronic devices have great potential in the fields of the Internet of Things (IoT), sports and entertainment, and healthcare, and they are essential in advancing the development of next-generation electronic information technology. However, conventional lithium batteries, which are currently the main power supply of wearable electronic devices, have some critical issues, such as frequent charging, environmental pollution, and no surface adaptability, which limit the further development of wearable electronic devices. To address these challenges, we present a flexible hybrid photothermoelectric generator (PTEG) with a simple structure composed of a thermoelectric generator (TEG) and a light-to-thermal conversion layer to simultaneously harvest thermal and radiation energies based on a single working mechanism. The mature mass-fabrication technology of screen printing was applied to successively prepare n-type (i.e., Bi2Te2.7Se0.3) and p-type (i.e., Sb2Te3) thermoelectric inks atop a polyimide substrate to form the TEG with a serpentine thermocouple chain, which was further covered by a light-to-thermal conversion layer to constitute the PTEG. The resulting PTEG with five pairs of thermocouples generated a direct-current output of 82.4 mV at a temperature difference of 50 °C and a direct-current output of 41.2 mV under 20 mW/cm2 infrared radiation. Meanwhile, the remarkable mechanical reliability and output stability were experimentally demonstrated through a systematic test, which indicated the feasibility and potential of the developed PTEG as a reliable power source. In addition, as desirable application prototypes, the fabricated PTEGs have been successfully demonstrated to harvest biothermal energy and infrared radiation to drive portable electronic devices (e.g., a calculator and a clock). Hybrid energy harvesting technology based on a simple structure may provide a new solution to current power supply issues of wearable electronic device.

Wearable multi-sensing double-chain thermoelectric generator.

Wearable electronics play a crucial role in advancing the rapid development of artificial intelligence, and as an attractive future vision, all-in-one wearable microsystems integrating powering, sensing, actuating and other functional components on a single chip have become an appealing tendency. Herein, we propose a wearable thermoelectric generator (ThEG) with a novel double-chain configuration to simultaneously realize sustainable energy harvesting and multi-functional sensing. In contrast to traditional single-chain ThEGs with the sole function of thermal energy harvesting, each individual chain of the developed double-chain thermoelectric generator (DC-ThEG) can be utilized to scavenge heat energy, and moreover, the combination of the two chains can be employed as functional sensing electrodes at the same time. The mature mass-fabrication technology of screen printing was successfully introduced to print n-type and p-type thermoelectric inks atop a polymeric substrate to form thermocouples to construct two independent chains, which makes this DC-ThEG flexible, high-performance and cost-efficient. The emerging material of silk fibroin was employed to cover the gap of the fabricated two chains to serve as a functional layer for sensing the existence of liquid water molecules in the air and the temperature. The powering and sensing functions of the developed DC-ThEG and their interactions were systematically studied via experimental measurements, which proved the DC-ThEG to be a robust multi-functional power source with a 151 mV open-circuit voltage. In addition, it was successfully demonstrated that this DC-ThEG can convert heat energy to achieve a 3.3 V output, matching common power demands of wearable electronics, and harvest biothermal energy to drive commercial electronics (i.e., a calculator). The integration approach of powering and multi-functional sensing based on this new double-chain configuration might open a new chapter in advanced thermoelectric generators, especially in the applications of all-in-one self-powered microsystems.