1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 3): m306, 2012 Mar 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22412448
RESUMO
In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenyl-pyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetyl-acetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56â (14) and 58.99â (14)° for one mdpp ligand and 9.34â (14) and 79.94â (15)° for the other.