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1.
Sensors (Basel) ; 23(7)2023 Apr 03.
Artigo em Inglês | MEDLINE | ID: mdl-37050765

RESUMO

A dual-coil inductive displacement transducer is a non-contact type measuring element for measuring displacement and is widely used in large power equipment systems such as construction machinery and agricultural equipment. However, the effect of the coil excitation method on the performance of dual-coil inductive displacement sensors has not been studied. This paper investigates the impact of different coil excitation methods on the operating performance of displacement transducers. The working principle, electromagnetic characteristics, and electrical characteristics were analyzed by building a mathematical model. A transducer measurement device was used to determine the relationship between core displacement and coil inductance. Three coil excitation methods were proposed, and the effects of the three coil excitation methods on the amplitude variation, phase shift, linearity, and sensitivity of the output signal were studied by simulation based on the AD630 chip as the core of the conditioning circuit. Finally, the study's feasibility was demonstrated by comparing the experiment to the simulation. The results show that, under the uniform magnetic field strength distribution in the coil, the coil voltage variation is proportional to the inductive core displacement. The amplitude variation is the largest for the dual-coil series three-wire (DCSTW) and is the same for the dual-coil series four-wire (DCSFW) and dual-coil parallel differential (DCPD). DCSFW has an enormous phase shift. DCSTW has the best linearity. The research in this paper provides a theoretical basis for selecting a suitable coil excitation, which is conducive to further improving the operating performance of dual-coil inductive displacement transducers.

2.
Sensors (Basel) ; 23(7)2023 Apr 06.
Artigo em Inglês | MEDLINE | ID: mdl-37050839

RESUMO

A double-coil inductive displacement transducer is a non-contact element for measuring displacement and is widely used in large power equipment systems such as construction machinery and agricultural machinery equipment. The type of coil excitation signal has an impact on the performance of the transducer, but there is little research on this. Therefore, the influence of the coil excitation signal on transducer performance is investigated. The working principle and characteristics of the double-coil inductive displacement transducer are analyzed, and the circuit simulation model of the transducer is established. From the aspects of phase shift, linearity, and sensitivity, the effects of a sine signal, a triangle signal, and a pulse signal on the transducer are compared and analyzed. The results show that the average phase shift, linearity, and sensitivity of the sine signal were 11.53°, 1.61%, and 0.372 V/mm, respectively; the average phase shift, linearity and sensitivity of the triangular signal were 1.38°, 1.56%, and 0.300 V/mm, respectively; and the average phase shift, linearity, and sensitivity of the pulse signal were 0.73°, 1.95%, and 0.621 V/mm, respectively. It can be seen that the phase shift of a triangle signal and a pulse signal is smaller than that of a sine signal, which can result in better signal phase-locked processing. The linearity of the triangle signal is better than the sine signal, and the sensitivity of the pulse signal is better than that of the sine signal.

3.
J Comput Chem ; 44(1): 15-26, 2023 Jan 05.
Artigo em Inglês | MEDLINE | ID: mdl-36169382

RESUMO

The hydrogen evolution effect of ZrS2 carrier loaded with transition metal single-atom (SA) was explored by first-principles method. ZrS2 was constructed with transition metal single-atom and dual-atom. The structure-activity relationship of supported single-atom catalysts was described by electronic properties and hydrogen evolution kinetics. The results show that the ZrS2 carrier-loaded atomic-level catalysts are more likely to occur in acidic environments, where the Mo SA load has a higher hydrogen precipitation capacity than the Pt SA. In the case of dual-atom adsorption, most of the hydrogen reduction processes are higher than that of single atom loading, which indicates that the outer orbital hybridization is more likely to lead to the interfacial charge recombination of the catalyst. Thereinto, Ni/Pt @ZrS2 has the lowest Gibbs free energy (0.08 eV), and the synergistic effect of transition metals induces the deviation of the center of the d-band from the Fermi level and improves the dissociation ability of H ions. The design provides a new catalytic model for the HER and provides some ideas for understanding the two-site catalysis.

4.
Heliyon ; 8(11): e11700, 2022 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-36458286

RESUMO

The hydraulic force has a great negative effect on the cartridge poppet valve system. Based on the law of momentum, the calculation formula of flow force of outflow poppet valve is modified, and a new valve core structure is designed. The compensation effect of the improved main valve core structure on the hydraulic force is discussed; secondly, CFD simulation is carried out to obtain the influence rules of these parameters on hydrodynamic forces. According to the analysis, the influence of main valve core arc structure on hydrodynamic force compensation under different opening degrees is also studied; then the optimal parameters of the arc structure are obtained through analysis. AMEsim system simulation model and test-bed are built to verify the hydrodynamic formula and simulation results. The experimental results verify that the new valve core structure has a good hydrodynamic compensation effect.

5.
Front Chem ; 10: 865281, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35665061

RESUMO

In recent years, thermoelectric functional materials have been widely concerned in temperature difference power generation, electric refrigeration and integrated circui, and so on. In this paper, the design and research progress of thermoelectric materials around lifting ZT value in recent years are reviewed. Optimizing the carrier concentration to improve the Seebeck coefficient, the steady improvement of carrier mobility and the influence of energy band engineering on thermoelectric performance are discussed. In addition, the impact of lattice thermal conductivity on ZT value is also significant. We discuss the general law that the synergistic effect of different dimensions, scales, and crystal structures can reduce lattice thermal conductivity, and introduce the new application of electro-acoustic decoupling in thermoelectric materials. Finally, the research of thermoelectric materials is summarized and prospected in the hope of providing practical ideas for expanding the application and scale industrialization of thermoelectric devices.

6.
ACS Omega ; 6(22): 14585-14597, 2021 Jun 08.
Artigo em Inglês | MEDLINE | ID: mdl-34124482

RESUMO

In this work, the influence of different N2/CO2 contents (up to 60% in fuel volume) on combustion features of laminar-premixed CO/CH4/H2 flame with various equivalence ratios (0.6-1.6) at standard conditions was numerically calculated using ANSYS CHEMKIN-PRO with the GRI-Mech 3.0 mechanism. The mole fraction profiles of the major species and the rate of production of dominant elementary reactions in the flames of CO/CH4/H2/N2/CO2/air were obtained. The effect of inert gas addition on the formation of NO X , H, O, and OH was analyzed, and the sensitivity coefficient of the active radical mole fraction was obtained. The results suggest that the addition of inert gas of the fuel mixture with various equivalence ratios reduces laminar burning velocity and adiabatic temperature, which have always had a good positive correlation and the maximum peak point shifted left. CO2 has obvious inhibitory effect on the formation of NO by reducing the amount of O radicals and obstructing the conduct of the reaction of NNH + O ⇔ NH + NO, but it promotes the formation of NO2 mainly through the reaction HO2 + NO ⇔ NO2 + OH. The reactions H + O2 + H2O ⇔ HO2 + H2O, H + O2 ⇔ O + OH, and OH + CO ⇔ H + CO2 are three very important reactions for the molar fractions of H, O, and OH that decrease significantly with an increase of inert gas concentration.

7.
Chemistry ; 13(36): 10225-38, 2007.
Artigo em Inglês | MEDLINE | ID: mdl-17907134

RESUMO

The concise asymmetric total synthesis of scyphostatin has been achieved by condensation of the optically active cyclohexane unit, prepared from the commercially available 1,4-cyclohexadiene by our own method, and the side chain, prepared by the method developed by Hoye and Tennakoon (T. R. Hoye, M. A. Tennakoon, Org. Lett. 2000, 2, 1481-1483). The modification of the epoxy cyclohexenone unit was achieved in a late stage of the total synthesis, and deprotection of the primary alcohol was conducted in the final step. During the synthesis several key reactions were attained: 1) intramolecular bromoetherification of the cyclohexadiene acetal; 2) stereoselective introduction of the tertiary alcohol, 3) deprotection of the acetal function to the aldehyde by combination with silyl triflate/2,4,6-collidine and the one-pot synthesis of the disilyl aldehyde compounds, with different types of silyl groups, from the dihydroxy acetal compounds; and 4) facile deprotection of the 2,4-dimethoxyphenylmethyl ((2,4)DMPM) protecting group of the primary alcohol.


Assuntos
Amidas/síntese química , Amidas/farmacologia , Inibidores Enzimáticos/síntese química , Pironas/síntese química , Pironas/farmacologia , Esfingomielina Fosfodiesterase/antagonistas & inibidores , Acetais/síntese química , Acetais/química , Álcoois/química , Aldeídos/química , Amidas/química , Cicloexenos/síntese química , Cicloexenos/química , Inibidores Enzimáticos/química , Inibidores Enzimáticos/farmacologia , Hidroxilação , Estrutura Molecular , Nitrogênio/química , Pironas/química , Esfingomielina Fosfodiesterase/metabolismo , Estereoisomerismo
8.
J Org Chem ; 72(21): 7898-902, 2007 Oct 12.
Artigo em Inglês | MEDLINE | ID: mdl-17887700

RESUMO

A mild and efficient method for the preparation of O,O-mixed, O,S- and N,O-acetals from symmetrical O,O-acetals has been developed. Thus, the treatment of symmetrical O,O-acetals with TESOTf and 2,4,6-collidine formed weakly electrophilic collidinium salts. The addition of nucleophiles, such as an alcohol, lithium thioxide, and sodium azide, to the salts afforded the corresponding O,O-mixed, O,S- and N,O-acetals in good yields. The reaction proceeded under weakly basic conditions. No overreaction then occurred and many acid-labile functional groups could remain intact.


Assuntos
Acetais/síntese química , Química Orgânica/métodos , Sais/química , Acetais/química , Eletroquímica , Estrutura Molecular
9.
J Am Chem Soc ; 128(17): 5930-8, 2006 May 03.
Artigo em Inglês | MEDLINE | ID: mdl-16637661

RESUMO

We report here unexpected highly chemoselective deprotection of the acetals from aldehydes. Treatment of acetal compounds from aldehydes with TESOTf-2,6-lutidine or TESOTf-2,4,6-collidine in CH2Cl2 at 0 degrees C followed by H2O workup at the same temperature caused the conversion of the acetal functions to aldehyde functions. The reaction had generality and was applied to many acetal compounds. Study using various bases revealed the reaction and reached the best combination of TESOTf-base. It was very mild and highly chemoselective and proceeded under weakly basic conditions. Then, many functional groups such as allyl alcohol, silyl ether, acetate, methyl ether, triphenylmethyl (Tr) ether, 1,3-dithiolane, methyl ester, and tert-butyl ester could survive under these conditions. Furthermore, this methodology could selectively deprotect the acetals in the presence of ketals as the most characteristic feature, although this chemoselectivity is difficult to achieve by other previously reported methods. A detailed study of the reaction including MS and NMR studies revealed the reaction mechanism for determining the structures of the intermediates, pyridinium-type salts. These intermediates had a weak electrophilicity and were successfully applied to the efficient formation of the mixed acetals in high yields.

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