Gate-Controlled Neuromorphic Functional Transition in an Electrochemical Graphene Transistor.

Neuromorphic devices have attracted significant attention as potential building blocks for the next generation of computing technologies owing to their ability to emulate the functionalities of biological nervous systems. The essential components in artificial neural networks such as synapses and neurons are predominantly implemented by dedicated devices with specific functionalities. In this work, we present a gate-controlled transition of neuromorphic functions between artificial neurons and synapses in monolayer graphene transistors that can be employed as memtransistors or synaptic transistors as required. By harnessing the reliability of reversible electrochemical reactions between carbon atoms and hydrogen ions, we can effectively manipulate the electric conductivity of graphene transistors, resulting in a high on/off resistance ratio, a well-defined set/reset voltage, and a prolonged retention time. Overall, the on-demand switching of neuromorphic functions in a single graphene transistor provides a promising opportunity for developing adaptive neural networks for the upcoming era of artificial intelligence and machine learning.

Effects of waves, burial depth and material density on microplastic retention in coastal sediments.

Coastal sediments, recognized as a major sink for microplastics (MPs), are subject to frequent physical disturbances, such as wave disturbance and associated sediment dynamics. Yet it remains poorly understood how wave disturbance regulates MPs accumulation in such a dynamic environment. Here, we examined the effects of waves and their interactions with material density and burial depth on the retention of MPs in coastal sediments, through manipulative experiments in a mangrove habitat along the coast of South China. The results clearly revealed that stronger waves removed more buried MPs from the sediments. Moreover, storms can have disproportional effects on MPs retention by inducing large waves and strong sediment erosion. We also demonstrated that MPs retention generally increased linearly with growing material density and non-linearly with raised burial depth in the sediment. Overall, our findings highlight the importance of both external and internal factors in shaping MPs retention in coastal ecosystems like mangroves, which is essential to assess and predict MPs accumulation patterns as well as its impacts on ecosystem functioning of such blue carbon habitats.

The role of bio-geomorphic feedbacks in shaping microplastic burial in blue carbon habitats.

Coastal sediments are considered as hotspots of microplastics (MPs), with substantial MPs stocks found in blue carbon habitats such as mangroves and tidal marshes, where wave-damping vegetation reduces sediment erosion and enhances accretion. Here, we examined the effects of such bio-geomorphic feedbacks in shaping MPs burial, through a year-round field study in a mangrove habitat along the coast of South China. The results revealed that MPs abundance decreased significantly with the increase of cumulative sediment erosion as the strength of bio-geomorphic feedbacks declined. More shapes and colors of MPs were found at locations with weaker waves and less sediment erosion, where the average particle size was also higher. Our findings highlight the importance of bio-geomorphic feedbacks in affecting both the abundance and characteristics of the buried MPs. Such knowledge extends our understanding of MPs transport and burial from the perspective of bio-geomorphology, which is essential to assess and predict MPs accumulation patterns as well as its impacts on ecosystem functioning of the blue carbon habitats.

Tafel-Kinetics-Controlled High-Speed Switching in a Electrochemical Graphene Field-Effect Transistor.

Graphene field-effect transistors (FETs) have attracted tremendous attention owing to the single-atomic-layer thickness and high electron mobility for potential applications in next-generation electronics. With regards to switching methodology, the electric-field-induced metal-insulator transition offers a new strategy to produce a large on/off current ratio through reversible electrochemical hydrogenation of the graphene channels. Therefore, the performance of such electrochemical graphene FETs greatly relies on the kinetics of hydrogenation reaction. Here, we show that the switching time can be systemically controlled by the applied gate voltages and geometries of graphene channels. The turn-on and turn-off time display an exponential dependence on the gate voltages, manifesting the dominated Tafel-form kinetics of hydrogenation reaction in a two-dimensional limit. Moreover, the turn-off time is inversely proportional to the channel width but independent of the length, while the turn-on time relies on both the width and length, as well as the off-state gate voltage and duration. Our work improves the response time to the magnitude of tens of microseconds and advances the application of graphene-based electronic devices.

Coordination-directed self-assembly of molecular motors: towards a two-wheel drive nanocar.

Designing and constructing hierarchical and stimuli-responsive motorized nanocar systems to perform useful tasks on-demand is highly imperative towards molecular nanotechnology. In this work, a most simplified two-wheel nanocar was successfully prepared through a facile strategy of coordination-directed self-assembly. The nanocar meso-AgL2 features a central pseudo square-planar Ag(I) which was bridged by two enantiomeric motors as the wheels that ensure the car moves in the same direction when observed externally. Thanks to the electronic push-pull characteristic of L and 3ILCT triplet sensitization, this nanocar can be driven by visible light up to 500 nm. Furthermore, it could be disassembled into individual motor elements through the addition of pyridine, thus allowing dynamic regulation over the function of the nanocar. Importantly, our STM imaging results showed very organized tilted layered structures for meso-AgL2 on highly oriented pyrolytic graphite (HOPG) that are quite similar to its crystalline ones, paving the way for future single molecule manipulations. The nanocar reported here represents the first example of integrating individual motors into a hierarchical motorized nanocar system via the facile coordination-directed self-assembly method and may offer a good starting point to realize its robotic functions, e.g., metal transportation and release.

Reversible and selective ion intercalation through the top surface of few-layer MoS2.

Electrochemical intercalation of ions into the van der Waals gap of two-dimensional (2D) layered materials is a promising low-temperature synthesis strategy to tune their physical and chemical properties. It is widely believed that ions prefer intercalation into the van der Waals gap through the edges of the 2D flake, which generally causes wrinkling and distortion. Here we demonstrate that the ions can also intercalate through the top surface of few-layer MoS2 and this type of intercalation is more reversible and stable compared to the intercalation through the edges. Density functional theory calculations show that this intercalation is enabled by the existence of natural defects in exfoliated MoS2 flakes. Furthermore, we reveal that sealed-edge MoS2 allows intercalation of small alkali metal ions (e.g., Li+ and Na+) and rejects large ions (e.g., K+). These findings imply potential applications in developing functional 2D-material-based devices with high tunability and ion selectivity.

Dynamic MRI of rat brain following manganese administration through the internal carotid artery.

OBJECTIVE: In this study, we investigated the dynamic distribution processes of Mn(2+) in rat brain using magnetic resonance imaging (MRI) after an intra-arterial (IA) injection of MnCl2 and following the breaking of the blood-brain barrier (BBB). METHODS: Adult male Sprague-Dawley (SD) rats were employed in the study. After the rats were anesthetized with urethane, 25% mannitol was administrated into the right internal carotid artery (ICA) in order to disrupt the BBB, 50 mmol/l (10 mg/kg) of MnCl2 was then injected into ICA prior to the MRI assay. The MRI was performed at 7 T for a continuous 2 hours following the administration of MnCl2. Image reconstruction and analysis were performed using the Statistical Parametric Mapping (SPM) software. RESULTS: As time progressed, the Mn(2+) enhanced signal intensity showed a gradual increase with a maximum increase at 10 minutes following MnCl2 administration, and began to decline after 10 minutes. From 30 minutes to 2 hours, the signal-enhanced region became more homogeneous, and the signal-enhanced range spread to the contralateral area up to 2 hours after MnCl2 administration. CONCLUSION: These results will help future research to select an appropriate time point to perform functional MRI for different types of activity-induced manganese (AIM) MRI research studies. These findings will allow researchers to discriminate intended, stimulation-specific enhanced signal from unintended, nonspecific enhanced signals.

Acute toxicity of zinc oxide nanoparticles to the rat olfactory system after intranasal instillation.

With the increased applications of zinc oxide (ZnO) nanoparticles (NPs), the toxicity of ZnO NPs arouses great concerns from the nano community and the general public. In this study, we report the toxicity of ZnO NPs (30 nm) to the rat olfactory system after intranasal instillation revealed by non-invasive magnetic resonance imaging (MRI). MRI scans were performed on a 4.7-T scanner at 1, 2, 3 and 7 days post-exposure, and the histological changes of the rat olfactory epithelium were evaluated. The influences of chemical component and dispersant of the NPs were also investigated. In addition, an olfactory behavior test was performed. The MRI and histological results indicated that ZnO NPs induced significant damages to the olfactory epithelium, including disruption of the olfactory epithelial structures and inflammation. The destruction of mitochondria in epithelial cells was observed under transmission electron microscopy (TEM), suggesting that the possible toxicological mechanism might involve cellular energy metabolic dysfunction. Further, the lesion of the olfactory epithelium disturbed sniffing behaviors of the treated animals. The results suggest that MRI is potentially useful as a screening tool to assess the consequence of occupational exposure of ZnO NPs. Caution should therefore be taken during the use and disposal of ZnO NPs to prevent the unintended public health impacts.

A taxonomy of green supply chain management capability among electronics-related manufacturing firms in Taiwan.

This study investigated crucial green supply chain management (GSCM) capability dimensions and firm performance based on electronics-related manufacturing firms in Taiwan. On the basis of a factor analysis, six green supply chain management dimensions were identified: green manufacturing and packaging, environmental participation, green marketing, green suppliers, green stock, and green eco-design. According to their factor scores in the GSCM dimensions, a cluster analysis subsequently assigned responding firms into four groups, namely, the weak GSCM oriented group, the green marketing oriented group, the green supplier oriented group, and the green stock oriented group. Differences in firm performance and GSCM dimensions among groups were examined. Results indicated that the green marketing oriented group performed best. Based on the resource-based view (RBV), the capability of the green marketing oriented group was considered to be the deployment of a collection of resources that enables it to successfully compete against rivals. The importance of green marketing as a GSCM capability and strategic asset/critical resources for electronics-related manufacturing firms to obtain a competitive edge is therefore highlighted in this study.