Solar-based photocatalytic ozonation employing novel S-scheme ZnO/Cu2O/CuO/carbon xerogel photocatalyst: effect of pH, salinity, turbidity, and temperature on salicylic acid degradation.

This paper proposes the study of a solar-based photocatalytic ozonation process for the degradation of salicylic acid (SA) using a novel S-scheme ZnO/Cu2O/CuO/carbon xerogel photocatalyst. The incorporation of CuO and Cu2O aims to enhance charge mobility through the formation of p-n heterojunctions with ZnO, whereas the carbon xerogel (XC) was selected due to its eco-friendly nature, capacity to stabilize S-scheme heterojunctions as a solid-state electron mediator, and ability to function as a reducing agent under high temperatures. The characterization of the composites demonstrates that the presence of the XC during the calcination step led to the reduction of a fraction of the CuO into Cu2O, forming a ternary semiconductor heterojunction system. In terms of photocatalysis, the XC/ZnO-CuxO 5% composite achieved the best efficiency for salicylic acid degradation, mainly due to the stabilization of the S-scheme charge transfer pathway between the ZnO/CuO/Cu2O semiconductors by the XC. The total organic carbon (TOC) removal during heterogeneous photocatalysis was 80% for the solar-based process and 68% for the visible light process, after 300 min. The solar-based photocatalytic ozonation process was highly successful regarding the degradation of SA, achieving a 75% increase in the apparent reaction rate constant when compared to heterogeneous photocatalysis. Furthermore, a 78% TOC removal was achieved after 150 min, which is half the time required by the heterogeneous photocatalysis to obtain the same result. Temperature, salinity, and turbidity had major effects on the efficiency of the photocatalytic ozonation process; the system's pH did not cause any major performance variation, which holds relevance for industrial applications.

Black-wattle tannin/kraft lignin H3PO4-activated carbon xerogels as excellent and sustainable adsorbents.

This work proposed new black-wattle tannin/kraft lignin H3PO4-activated carbon xerogels as sustainable and efficient adsorbents. The precursors were chosen based on their eco-friendly and cost-effective nature, aiming to achieve adsorbents with high adsorption capacities. Carbon xerogels were synthesized through polycondensation with formaldehyde and alkaline catalyst in a simple one-pot procedure. Activation was performed using H3PO4 in a tubular furnace (500 °C), under a nitrogen atmosphere. Results show that the inclusion of the kraft lignin led to changes in the morphology of the materials, facilitating the development of their porous structure and increasing specific surface area and pore volume. The best adsorbent (XLT 50 %) was synthesized using a 1:1 tannin/kraft lignin mass ratio. This material presented an adsorption capacity of nearly 1150 mg g-1 of methylene blue (pH = 5 and T = 298 K), which was linked to its high specific surface area of 1348 m2 g-1. The adsorption process followed the pseudo-second-order kinetic model, whereas the adsorption isotherms were best fitted by the Sips model. The XLT 50 % presented good reusability properties, maintaining its adsorption capacity for 3 cycles. Finally, the XLT 50 % presented good adsorptive properties toward other pollutants (methyl orange, 4-chlorophenol, and hexavalent chromium), indicating its versatility for adsorption processes.

Kraft lignin-based carbon xerogel/zinc oxide composite for 4-chlorophenol solar-light photocatalytic degradation: effect of pH, salinity, and simultaneous Cr(VI) reduction.

Considering the ever-increasing need for efficient wastewater treatment, this study focused on the development of new kraft lignin-based carbon xerogel/zinc oxide (XCL/ZnO w) photocatalysts. The inclusion of the carbon xerogel is expected to cause an improvement in charge transfer throughout the photoactivation process, consequently enhancing its overall photocatalytic efficiency. Characterization shows that the materials developed are composed of both zinc oxide and carbon xerogel. The addition of the lignin-based carbon xerogel caused a significant morphological modification to the composite materials, resulting in a greater specific surface area. Regarding the photocatalytic efficiency, the optimized composite (XCL/ZnO 1.0) displayed superior efficiency to the pure zinc oxide, especially when calcined at 700 °C, with an increase of 20% in the overall photodegradation capacity for the 4-chlorophenol (4CP) molecule. The XCL/ZnO 1.0 also displayed better performance than its tannin counterpart, previously reported in the literature, obtaining a 60% increase in the apparent reaction rate constant. The XCL/ZnO 1.0 also displayed better performance for the simultaneous hexavalent chrome (Cr (VI)) reduction/4CP oxidation reaction. Salinity and system pH had a significant influence on the efficiency of the 4CP photodegradation, as higher values of salinity and lower pHs caused a decrease in the overall efficiency of the process. At last, chronoamperometry and open-circuit potential tests confirmed the superiority of the XCL/ZnO 1.0 over the pure ZnO, highlighting the beneficial impact of the carbon xerogel on the charge transport dynamics of the composite.