Mechanical characterization of oligo(ethylene glycol)-based hydrogels by dynamic nanoindentation experiments.

Oligo(ethylene glycol)-based (OEG) hydrogel samples of varying cross-link densities and degrees of swelling were characterized through dynamic nanoindentation testing. Experiments were performed using a non-standard nanoindentation method, which was validated on a standard polystyrene sample. This method maximizes the capability of the instrument to measure the stiffness and damping of highly compliant, viscoelastic materials. Experiments were performed over the frequency range of 1 to 50 Hz, using a 1mm diameter flat punch indenter. A hydration method was adopted to avoid sample dehydration during testing. Values of storage modulus (E') ranged from 3.5 to 8.9 MPa for the different OEG-hydrogel samples investigated. Samples with higher OEG concentrations showed greater scatter in the modulus measurements and it is attributed to inhomogeneities in these materials. The (E') values did not show a strong variation over frequency for any of the samples. Values of loss modulus (E") were two orders of magnitude lower than the storage modulus, resulting in very low values of loss factor (E"/E'<0.1). These are characteristics of strong gels, which present negligible viscous properties.

The coordinated buckling of carbon nanotube turfs under uniform compression.

Complex structures consisting of intertwined, nominally vertical carbon nanotubes (CNTs), referred to as turfs, have unique properties that arise from their complex nanogeometry and interactions between individual CNT segments. For applications such as contact switches for electrical or thermal transfer it is necessary to understand the properties that arise from the collective behavior of an assemblage of CNTs rather than the properties of a single tube. In this study, the mechanical response of turfs bonded to substrates under compressive loading is demonstrated experimentally; coordinated alignment and buckling takes place under uniform loads. The mechanical response of turf structures provides some surprising results regarding parameters that control permanent deformation and buckling in assemblages of nanostructures; buckling of the turf structure is controlled by the height and effective modulus of the turf, but not the aspect ratio of the structure. We present and verify a model which describes the coordinated buckling phenomena relevant for applications such as CNT turfs for thermal transfer media.