RESUMO
Spectroscopic chemometric based on-line monitoring of used nuclear fuel (UNF) reprocessing solutions and characterization of legacy nuclear waste (LNW) stored at Hanford is discussed in this manuscript. Utilizing on-line and near real-time monitoring, as opposed to traditional off-line monitoring, can significantly reduce the cost, risk and improve the efficiency of characterizing UNF and LNW processing streams. Specifically, this manuscript will highlight the benefits of spectroscopy-based monitoring approaches, which generally include the ability to collect data non-destructively. Furthermore, significant literature precedence supports the use of various real-time analysis methods, including chemometric analysis, that enable near-instantaneous conversion of spectroscopic data into information useable by process operators. This approach can accurately quantify and qualify nuclear material in near-real time enabling immediate condition characterization and potential diversion detection within UNF reprocessing streams and LNW. The ability to be applied in a real reprocessing plant and in an actual Hanford waste tank/transfer pipe has been demonstrated by applying this technique to accurately quantify analytes in real UNF streams and LNW samples. The future development of spectroscopy-based on-line monitoring is also discussed in this manuscript.
