Coupling of the Structure and Magnetism to Spin Splitting in Hybrid Organic-Inorganic Perovskites.

Hybrid organic-inorganic perovskites are famous for the diversity of their chemical compositions, phases, phase transitions, and associated physical properties. We use a combination of experimental and computational techniques to reveal a strong coupling between structure, magnetism, and spin splitting in a representative of the largest family of hybrid organic-inorganic perovskites: the formates. With the help of first-principles simulations, we find spin splitting in both conduction and valence bands of [NH2NH3]Co(HCOO)3 induced by spin-orbit interactions, which can reach up to 14 meV. Our magnetic measurements reveal that this material exhibits canted antiferromagnetism below 15.5 K. The direction of the associated antiferromagnetic order parameter is strongly coupled with spin splitting in the centrosymmetric phase, allowing for the creation and annihilation of spin splitting through the application of a magnetic field. Furthermore, the structural phase transition to the experimentally observed polar Pna21 phase completely changes the aforementioned spin splitting and its coupling to magnetic degrees of freedom. This reveals that in [NH2NH3]Co(HCOO)3, the structure and magnetism are strongly coupled to spin splitting and can be manipulated through electric and magnetic fields. We believe that our findings offer an important step toward a fundamental understanding and practical applications of materials with coupled properties.

2D Materials by Design: Intercalation of Cr or Mn between two VSe2 van der Waals Layers.

Insertion of metal layers between layered transition-metal dichalcogenides (TMDs) enables the design of new pseudo-2D nanomaterials. The general premise is that various metal atoms may adopt energetically favorable intercalation sites between two TMD sheets. These covalently bound metals arrange in metastable configurations and thus enable the controlled synthesis of nanomaterials in a bottom-up approach. Here, this method is demonstrated by the insertion of Cr or Mn between VSe2 layers. Vacuum-deposited transition metals diffuse between VSe2 layers with increasing concentration, arranging in ordered phases. The Cr3+ or Mn2+ ions are in octahedral coordination and thus in a high-spin state. Measured and computed magnetic moments are high for dilute Cr atoms, but with increasing Cr concentration the average magnetic moment decreases, suggesting antiferromagnetic ordering between Cr ions. The many possible combinations of transition metals with TMDs form a library for exploring quantum phenomena in these nanomaterials.

Persistent and Quasipersistent Spin Textures in Halide Perovskites Induced by Uniaxial Stress.

Persistent spin textures are highly desirable for applications in spintronics, as they allow for long carrier spin lifetimes. However, they are also rare, as they require a delicate balance between spin-momentum coupling parameters. We used density functional theory simulations to predict the possibility of achieving these desirable spin textures through the application of uniaxial stress. Hybrid organic-inorganic perovskite MPSnBr3 (MP = CH3PH3) is a ferroelectric semiconductor which exhibits persistent spin textures near its conduction band minimum and mostly Rashba type spin textures in the vicinity of its valence band maximum. Application of uniaxial stress leads to the gradual evolution of the valence band spin textures from mostly Rashba type to quasipersistent ones under a tensile load and to pure Rashba or quasipersistent ones under a compressive load. The material exhibits flexibility, a rubber-like response, and both positive and negative piezoelectric constants. A combination of such properties may create opportunities for flexible and rubbery spintronic devices.

Ferrielectricity in the Archetypal Antiferroelectric, PbZrO3.

Antiferroelectric materials, where the transition between antipolar and polar phase is controlled by external electric fields, offer exceptional energy storage capacity with high efficiencies, giant electrocaloric effect, and superb electromechanical response. PbZrO3 is the first discovered and the archetypal antiferroelectric material. Nonetheless, substantial challenges in processing phase pure PbZrO3 have limited studies of the undoped composition, hindering understanding of the phase transitions in this material or unraveling the controversial origins of a low-field ferroelectric phase observed in lead zirconate thin films. Leveraging highly oriented PbZrO3 thin films, a room-temperature ferrielectric phase is observed in the absence of external electric fields, with modulations of amplitude and direction of the spontaneous polarization and large anisotropy for critical electric fields required for phase transition. The ferrielectric state observations are qualitatively consistent with theoretical predictions, and correlate with very high dielectric tunability, and ultrahigh strains (up to 1.1%). This work suggests a need for re-evaluation of the fundamental science of antiferroelectricity in this archetypal material.

Negative Longitudinal Piezoelectricity Coexisting with both Negative and Positive Transverse Piezoelectricity in a Hybrid Formate Perovskite.

Negative longitudinal piezoelectric response is a rare property, which has been found mostly in inorganic materials. We use first-principles density functional theory simulations to predict such an unusual response in [NH2NH3]Co(HCOO)3 ─a representative of a large family of hybrid organic-inorganic formate perovskites. A feature that sets aside [NH2NH3]Co(HCOO)3 from inorganic compounds with a negative longitudinal piezoelectric response is that this rare property coexists with both negative and positive transverse piezoelectric responses, which is highly desirable for tunable applications. Atomistic analysis reveals that this unusual electromechanical coupling originates from the high anisotropy of materials response to uniaxial stress. Such a deformation produces oxygen octahedral tilts in the framework, whose magnitude depends strongly on the direction of the applied strain. For hard directions, the tilts make the dominant contribution to the deformation-induced change in polarization, while for the softer direction, it is the tilts of the NH2NH3+ cation that dominate the polarization response. The latter occur as the complex hydrogen bond network responds to the octahedral tilts. As high anisotropy of mechanical properties is a common feature across the formate perovskites, we expect our findings to stimulate more discoveries of unusual electromechanical couplings in this family.

Phase Switching as the Origin of Large Piezoelectric Response in Organic-Inorganic Perovskites: A First-Principles Study.

Piezoelectrics are critical functional components of many practical applications such as sensors, ultrasonic transducers, actuators, medical imaging, and telecommunications. So far, the best performing piezoelectrics are ferroelectric ceramics, many of which are toxic, heavy, hard, and cost-ineffective. Recently, a groundbreaking discovery of extraordinarily large piezoelectric coefficients in the family of organic-inorganic perovskites gave a hope for a cheaper, environmentally friendly, inexpensive, lightweight, and flexible alternative. However, the origin of such a response in organic-inorganic ferroelectrics whose spontaneous polarization is an order of magnitude smaller than for inorganic counterparts remains unclear. In our study, we employ first-principles simulations to predict that the mechanism associated with large piezoelectric constants is of extrinsic origin and associated with switching between the stable phase and a previously overlooked energetically competitive metastable phase that can be stabilized by the external stress. The phase switching changes the polarization direction and therefore produces a large piezoelectric response similar to PbZr_{1-x}Ti_{x}O_{3} near the morphotropic phase boundary. The existence of such metastable phases is likely to manifest as the dynamical molecular disorder above the Curie temperature and therefore could be intrinsic to the entire family of organic-inorganic ferroelectrics with such disorder.

Elastocaloric Effect in Carbon Nanotubes and Graphene.

Carbon nanotubes are famous for their many extraordinary properties. We use a thermodynamical approach, experimental data from the literature, and atomistic simulations to reveal one more remarkable property of the carbon nanotubes that has so far been overlooked. Namely, we predict the existence of very large elastocaloric effect that can reach up to 30 K under moderate loads. Potentially even larger values could be achieved under extreme loads, putting carbon nanotubes in the forefront of caloric materials. Other remarkable features of the elastocaloric effect in carbon nanotubes include linearity of elastocaloric temperature change in applied force (compressive or stretching), very weak dependence on the temperature, and an absence of hysteresis. Such features are extremely desirable for practical applications in cooling devices. Moreover, a similarly large elastocaloric effect is predicted for the graphene. The prediction of a large elastocaloric effect in carbon nanotubes and graphene sets forward an unconventional strategy of targeting materials with moderate caloric responses but the ability to withstand very large loads.

Nanowires as semi-rigid substrates for growth of thick, In(x)Ga(1-x)N (x > 0.4) epi-layers without phase segregation for photoelectrochemical water splitting.

Here, we show that GaN nanowires (diameter <30 nm) can be used as strain relaxing substrates for the heteroepitaxial growth of stable In(x)Ga(1-x)N alloys of controlled composition and thickness. Thinner nanowires with their smaller interfacial area reduce the heteroepitaxial stress. Also, the limited adatom diffusion length scales on the thinner nanowires aid in reducing the kinetic segregation effects. In addition to being single crystal templates for heteroepitaxial growth, these thick single crystal overlayers on nanowire substrates can provide suitable architectures for photoelectrochemical applications. The stability and crystallinity of the In(x)Ga(1-x)N layers are preserved by the nanowires acting as compliant substrates. Photoelectrochemical water splitting requires In(x)Ga(1-x)N alloys with a 2.2-1.6 eV band gap (i.e. 0.45 < x < 0.65) and 150-200 nm film thickness for efficient light absorption and carrier generation. At such compositions, the In(x)Ga(1-x)N alloys are inherently unstable, the thickness-dependent stress builds up during the commonly employed heteroepitaxial growth methods, and adds to the instability causing phase segregation and property degradation. A dependence of the growth morphology on the GaN nanowire growth orientation was observed and a growth mechanism is presented for the observed orientation dependent growth on a-plane and c-plane GaN nanowires. Photoactivity of GaN and In(x)Ga(1-x)N films on GaN nanowires is also investigated which shows a distinct difference attributable to GaN and In(x)Ga(1-x)N, demonstrating the advantages of using nanowires as strain relaxing substrates.

Magnetic anisotropy and engineering of magnetic behavior of the edges in Co embedded graphene nanoribbons.

Using first-principles calculations, we demonstrate the existence of anisotropic ferromagnetic interactions in Co embedded graphene nanoribbons (GNRs). Spin polarization of the edge states is found to alter significantly compared to the metal-free cases. Our findings can all be well-justified as the output of the interplay between the development of an induced spin polarization in the neighborhood of the Co atoms and the maintaining of the polarization picture of the Co-free GNR. Based on our results, we propose an efficient pathway for graphene-based spintronics applications.

Ferromagnetic interactions in hosted bipartite materials--generalized-double-exchange and generalized-superexchange interactions.

Defect-induced magnetism in dilute magnetic semiconductors challenges our understanding of magnetism in solids. Theories based on conventional superexchange or double-exchange interactions cannot explain long range magnetic order at concentrations below the percolation threshold in these materials. On the other hand, the codoping-induced magnetism, which can explain magnetic interactions below the percolation threshold, has eluded explanation. In this work we propose that defect-induced magnetism in codoped non-magnetic materials can be viewed within a molecular generalization of the atomic double-exchange and superexchange interactions applied to an arbitrary bipartite lattice hosted by (or embedded in) defect-free non-magnetic materials. In this view, the crucial factor for the development of magnetism appears to be the defect complementarity of the codopants. We demonstrate this by taking ZnO and GaN (the most widely studied doped oxide and nitride magnetic semiconductors, respectively) as host materials and perform theoretical calculations using ab initio methods after codoping them with transition metal impurities for a variety of configurations. Our results indicate that the magnetic coupling among the induced and/or doped magnetic moments takes the form of an interaction among spin-polarized molecular units which is facilitated by the formation of the hosted bipartite codopant structures. The universality of the proposed mechanism is further supported by earlier results referring to the rhombohedral C(60)-based polymers.

Geometric frustration in compositionally modulated ferroelectrics.

Geometric frustration is a broad phenomenon that results from an intrinsic incompatibility between some fundamental interactions and the underlying lattice geometry. Geometric frustration gives rise to new fundamental phenomena and is known to yield intriguing effects such as the formation of exotic states like spin ice, spin liquids and spin glasses. It has also led to interesting findings of fractional charge quantization and magnetic monopoles. Mechanisms related to geometric frustration have been proposed to understand the origins of relaxor and multiferroic behaviour, colossal magnetocapacitive coupling, and unusual and novel mechanisms of high-transition-temperature superconductivity. Although geometric frustration has been particularly well studied in magnetic systems in the past 20 years or so, its manifestation in the important class formed by ferroelectric materials (which are compounds with electric rather than magnetic dipoles) is basically unknown. Here we show, using a technique based on first principles, that compositionally graded ferroelectrics possess the characteristic 'fingerprints' associated with geometric frustration. These systems have a highly degenerate energy surface and display critical phenomena. They further reveal exotic orderings with novel stripe phases involving complex spatial organization. These stripes display spiral states, topological defects and curvature. Compositionally graded ferroelectrics can thus be considered the 'missing link' that brings ferroelectrics into the broad category of materials able to exhibit geometric frustration. Our ab initio calculations allow deep microscopic insight into this novel geometrically frustrated system.