Correlative Effects of Carbon Support Structures and Surface Properties on ORR Catalytic Activities of Loaded Catalysts.

As a complex three-phase heterogeneous catalyst, the oxygen reduction reaction (ORR) catalyst activity is determined by the interfacial and surface structures and chemical state of the catalyst support. As a typical biomass carbon-based support, rice husk-based porous carbon (RHPC) has natural unique hierarchical porous structures, which easily regulate the microstructure and surface properties. This study explored the correlative effects of RHPC structure and surface properties on ORR catalytic activity through the typical modification methods, namely, alkali etching, high temperature, oxidation, and ball milling. The various factors for the joint effects are defined as the specific surface area, oxygen-containing functional groups, graphite edge defects, resistivity, and contact angle. The analysis of such joint influences is difficult to quantitatively evaluate due to the large number of experimental factors and small sample sizes. Partial least-squares (PLS) can better deal with such problems. Therefore, a PLS regression model was established to evaluate the relative weight of each factor on the catalytic activity for the RHPC-based support catalysts. The results reveal that the regression coefficients of four factors yield similar magnitude for the effect of the half-wave potential (E1/2). However, graphite edge defects had a more significant impact on the limiting diffusion current density (J) and electron transfer number (n). Furthermore, an optimal support named BM-RHPC-3 was prepared with more defects and oxygen-containing functional groups, which prepared Fe-NS/BM-RHPC-3 presenting the best ORR catalytic activity (E1/2 = 0.880 V, J of 5.15 mA cm-2), superior to Pt/C (E1/2 = 0.844 V, J of 4.99 mA cm-2). The statistical regression model is validated with a relative error of less than 5% between predicted and true values for analyzing RHPC-based ORR catalysts' catalytic performance. It shows the feasibility of experiment-informed learning for data-driven material discovery and design.

Improving the Anti-Corrosion and Anti-Wear Performance of Anodic Coating on the Surface of AA 5052 via Hydro-Thermal Treatment.

Hydro-thermal technology had been used to improve the anti-corrosion and anti-wear performance of anodizing coating on the surface of aluminium alloys. The micromorphology of the coating has been studied by SEM and results proved the coating had a compact structure. The element in the substrate had been characterized by EDS and results proved Fe had redissolved to the Al substrate. The crystalline structure of the coating had been studied by XRD and results proved the anodic coating could be transformed into η-, p- and γ-alumina. The electrochemical properties had been researched using an electrochemical workstation; results proved after the coating had been treated by hydro-thermal technology, its anti-corrosion properties could be improved. At the hydro-thermal temperature of 400 ℃, its open circuit voltage and impedance reached -0.46 V and 160 kΩ × cm2, respectively. The hardness of the coating had to be measured with an HVS-100 micro-hardness tester, with results proving that, after the hydro-thermal treatment, the hardness of the coating increased to 150 HV. The friction coefficient of the coating had been studied using a ball-on-disk tester, and the results proved it decreased to 0.46. The MMW-2 scratch tester had been used to measure the adhesion between the coating and substrate; results proved the coating had better adhesion with the substrate. The thermal conductivity of the coating had been studied by a heat conduction coefficient measurement device; results proved that it reached 11.2 W/m × K at a hydro-thermal temperature of 400 ℃, far higher than that of organic coating.

Propagation characteristics of ultrasonic weld-guided waves in Friction stir welding joint of same material.

Friction stir welding (FSW) is an important technology for manufacturing large-scale aluminum alloy propellant tank. Due to stress corrosion and cyclic loads, the key FSW joints require online monitoring to ensure the structural integrity and service safety of long-term storage propellant tanks. FSW joints in the propellant tank are regarded as a type of circumferential or longitudinal long and narrow region. In order to detect the flaws with high efficiency and fewer sensors, the propagation characteristics of ultrasonic guided waves in the FSW joint of same material is investigated in this paper. The weld of a FSW joint is characterized by concave cross-sectional shape and different microstructure-mechanical parameters. The micro-structure, micro-hardness, and Young's modulus of a real FSW joint are analyzed, and a two-dimensional semi-analytical finite-element (SAFE) method is employed to study the effects of different parameters on the modal characteristics of weld-guided waves in the FSW joint. In the studied fundamental modes (symmetric (S0), anti-symmetric (A0), and shear-horizontal (SH0)), an almost non-leaky A0-like weld-guided wave at a certain frequency range from 100 kHz to 210 kHz is discovered in the welded zone of a specific FSW model and shows a potential for long-distance detection. Parametric simulation results show that A0-like, SH0-like and S0-like modes at 120 kHz always exist when the weld width is changed while the moduli of the welded zone and base metal zone are maintained the same. Additionally, the simulations demonstrate that some weld-guided waves only exist if the modulus value of the welded zone is lower than that of the base metal zone when the cross section is geometrically continuous (i.e. the shoulder plunge depth is zero). Comparing with weld-guided waves affected by weld width, the weld-guided waves affected by the modulus change shows less obvious energy leakage during propagation. The experiments are conducted to validate the existence of A0-like weld-guided mode with a primary energy trapping effect.

Hierarchical porous carbon prepared from biomass through a facile method for supercapacitor applications.

The porous carbon with angstrom-sized pores is important in supercapacitor applications, because of its high pack density and high specific capacitance. In this paper, a facile method is proposed for the preparation of hierarchical porous carbon with high-volume angstrom-sized pores. Onion, as the typical biomass in this research, is used as carbon precursor. First, onion was etched by KOH to obtain a water-soluble lignin-potassium-salt/cellulose composite. This composite was further pyrolyzed under N2 atmosphere to obtain onion derived porous carbon (OPC). The morphology and porous structure of OPC were characterized by scanning electron microscope and N2 adsorption/desorption. The supercapacitive performances of OPC were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge-discharge. OPC shows high specific surface area with high-volume angstrom-sized pores in carbon matrix. When used as supercapacitor electrode materials, OPC shows high specific capacitance and good cycling stability. This paper opens a general way to prepare porous carbon from biomasses, which will promote the development of biomass utilization, preparation of porous carbon and supercapacitors.

Synthesis and infrared and luminescence spectra of rare earth complexes with a new hexapodal ligand.

Solid complexes of rare earth nitrates and picrates with a new hexapodal ligand, 1,2,3,4,5,6-hexa{[(2'-benzylamino-formyl)phenoxyl]methyl}-benzene (L) have been prepared. These complexes were characterized by elemental analysis, IR and molar conductivity. At the same time, the luminescence properties of the Eu(III) and Tb(III) nitrates and picrates complexes in solid state were also investigated. Under the excitation of UV light, these complexes exhibited characteristic emission of europium and terbium ions. The influence of the counter anion on the luminescent intensity was also discussed.