Oriented Interpenetrating Capillary Network with Surface Engineering by Porous ZnO from Wood for Membrane Emulsification.

Membrane emulsification technology has garnered increasing interest in emulsion preparation due to controllable droplet size, narrower droplet size distribution, low energy consumption, simple process design and excellent reproducibility. Nevertheless, the pore structure and surface engineering in membrane materials design play a crucial role in achieving high-quality emulsions with high throughput simultaneously. In this work, an oriented interpenetrating capillary network composed of highly aligned and interconnected wood cell lumens has been utilized to fabricate an emulsion membrane. A novel honeycomb porous ZnO layer obtained by a seed prefabrication-hydrothermal growth method was designed to reconstruct wood channel surfaces for enhanced microfluid mixing. The results show that through the unique capillary mesh microstructure of wood, the emulsion droplets were smaller in size, had narrower pore-size distribution, and were easy to obtain under high throughput conditions. Meanwhile, a well-designed ZnO layer could further improve the emulsion quality of a wood membrane, while the emulsifying throughput is still maintained at a higher level. This demonstrates that the convection process of the microfluid in these wood capillary channels was intensified markedly. This study not only develops advanced membrane materials in emulsion preparation, but also introduces a brand-new field for functional applications of wood.

Removal of Plastics from Micron Size to Nanoscale Using Wood Filter.

Plastic pollution, particularly microplastic (MP) and nanoplastic (NP) pollution, has become a significant concern. This study explores the use of porous wood for filtration to remove MPs and NPs and investigates their removal mechanisms. Undecorated fir wood with a thickness of 4 mm achieves a 91% removal rate for model polystyrene (PS) MPs (2.6 µm) at a water flux of 198 L/m2h. However, its separation performance for NPs (255.8 and 50.9 nm) is poor. It also shows that fir wood (coniferous wood) has a higher PS removal rate than poplar wood (hard wood). With poly dimethyl diallyl ammonium chloride (PDDA) modification, both MPs and NPs are effectively removed, with NPs' removal rate increasing from <10% to 90% for PDDA/wood. Characterization results reveal that size-exclusive interception dominates for micron-sized particles, and electrostatic interaction is crucial for nanosized particles. Additionally, intercepted NPs have been used as a strong binder for hot-pressed wood to remarkably enhance the mechanical properties of wood, suggesting a novel recycle utilization of discarded wood filters. Overall, this renewable wood material offers a simple solution for tackling MP/NP pollution.

Synthesis of X@DRHC (X=Co, Ni, Mn) catalyst from comprehensive utilization of waste rice husk and spent lithium-ion batteries for efficient peroxymonosulfate (PMS) activation.

Highly efficient resource recycling and comprehensive utilization play a crucial role in achieving the goal of reducing resource wasting, environmental protection, and achieving goal of sustainable development. In this work, the two kinds waste resources of agricultural rice husk and metal ions (Co, Ni, and Mn) from spent lithium-ion batteries have been skillfully utilized to synthesize novel Fenton-like catalysts. Desiliconized rice husk carbon (DRHC) with rich pore structure and large specific surface area from rice husk has been prepared and used as scalable carrier, and dandelion-like nanoparticles cluster could be grown in situ on the surface of the carrier by using metal ions contained waste water. The designed catalysts (X@DRHC) as well as their preparation process were characterized in detail by SEM, TEM, BET, XRD and XPS, respectively. Meanwhile, their catalytic abilities were also studied by activating potassium peroxomonosulfate (PMS) to remove methylene blue (MB). The results indicate X@DRHC displays excellent degradation efficiency on MB with wide pH range and stable reusability, which is suitable for the degradation of various dyes. This work has realized the recycling and high-value utilization of waste resources from biomass and spent lithium-ion batteries, which not only creates an efficient way to dispose waste resources, but also shows high economic benefits in large-scale water treatment.

Improving the Autofluorescence of Lophira alata Woody Cells via the Removal of Extractives.

The autofluorescence phenomenon is an inherent characteristic of lignified cells. However, in the case of Lophira alata (L. alata), the autofluorescence is nearly imperceptible during occasional fluorescence observations. The aim of this study is to investigate the mechanism behind the quenching of lignin's autofluorescence in L. alata by conducting associated experiments. Notably, the autofluorescence image of L. alata observed using optical microscopy appears to be quite indistinct. Abundant extractives are found in the longitudinal parenchyma, fibers, and vessels of L. alata. Remarkably, when subjected to a benzene-alcohol extraction treatment, the autofluorescence of L. alata becomes progressively enhanced under a fluorescence microscope. Additionally, UV-Vis absorption spectra demonstrate that the extractives derived from L. alata exhibit strong light absorption within the wavelength range of 200-500 nm. This suggests that the abundant extractives in L. alata are probably responsible for the autofluorescence quenching observed in the cell walls. Moreover, the presence and quantity of these extractives have a significant impact on the fluorescence intensity of lignin in wood, resulting in a significant decrease therein. In future studies, it would be interesting to explore the role of complex compounds such as polyphenols or terpenoids, which are present in the abundant extractives, in interfering with the fluorescence quenching of lignin in L. alata.

Engineering a hierarchical reduced graphene oxide and lignosulfonate derived carbon framework supported tin dioxide nanocomposite for lithium-ion storage.

Tin dioxide (SnO2) is widely recognized as a high-performance anode material for lithium-ion batteries. To simultaneously achieve satisfactory electrochemical performances and lower manufacturing costs, engineering nano-sized SnO2 and further immobilizing SnO2 with supportive carbon frameworks via eco-friendly and cost-effective approaches are challenging tasks. In this work, biomass sodium lignosulfonate (LS-Na), stannous chloride (SnCl2) and a small amount of few-layered graphene oxide (GO) are employed as raw materials to engineer a hierarchical carbon framework supported SnO2 nanocomposite. The spontaneous chelation reaction between LS-Na and SnCl2 under mild hydrothermal condition generates the corresponding SnCl2@LS sample with a uniform distribution of Sn2+ in the LS domains, and the SnCl2@LS sample is further dispersed by GO sheets via a redox coprecipitation reaction. After a thermal treatment, the SnCl2@LS@GO sample is converted to the final SnO2/LSC/RGO sample with an improved microstructure. The SnO2/LSC/RGO nanocomposite exhibits excellent lithium-ion storage performances with a high specific capacity of 938.3 mAh/g after 600 cycles at 1000 mA g-1 in half-cells and 517.1 mAh/g after 50 cycles at 200 mA g-1 in full-cells. This work provides a potential strategy of engineering biomass derived high-performance electrode materials for rechargeable batteries.

Biochar/layered double hydroxides composites as catalysts for treatment of organic wastewater by advanced oxidation processes: A review.

Heterogeneous advanced oxidation process has been widely studied as an effective method for removing organic pollutants in wastewater, but the development of efficient catalysts is still challenging. This review summaries the present status of researches on biochar/layered double hydroxides composites (BLDHCs) as catalysts for treatment of organic wastewater. The synthesis methods of layered double hydroxides, the characterizations of BLDHCs, the impacts of process factors influencing catalytic performance, and research advances in various advanced oxidation processes are discussed in this work. The integration of layered double hydroxides and biochar provides synthetic effects for improving pollutant removal. The enhanced pollutant degradation in heterogeneous Fenton, sulfate radical-based, sono-assisted, and photo-assisted processes using BLDHCs have been verified. Pollutant degradation in heterogeneous advanced oxidation processes using BLDHCs is influenced by process factors such as catalyst dosage, oxidant addition, solution pH, reaction time, temperature, and co-existing substances. BLDHCs are promising catalysts due to the unique features including easy preparation, distinct structure, adjustable metal ions, and high stability. Currently, catalytic degradation of organic pollutants using BLDHCs is still in its infancy. More researches should be conducted on the controllable synthesis of BLDHCs, the in-depth understanding of catalytic mechanism, the improvement of catalytic performance, and large-scale application of treating real wastewater.

Electrostatic deposition of TiO2 nanoparticles on porous wood veneer for improved membrane filtration performance and antifouling properties.

Wood has been a promising water purifier material on account of its abundant natural transport channels, easy processing, and renewability, which is mainly focused on its utilization in growth direction for effective separation.Wood veneer manufacured from raw wood block has a reversed-tree pore structure, and possesses advantages of low cost, easy fabrication, material saving, and abundant sources. To realize its functionalization and practicable application for membrane separation, modification of wood veneer is prerequisite. Herein, thin wood veneer with disparate utilization direction of wood was developed to design filter membrane loading TiO2 nanoparticles for treatment of dye wastewater. Wood veneer with reversed-tree transport pathways exhibits unique porous structure, and filtering direction and wood growth direction is almost orthogonal generated numerous sinuous channels. Thereout, sufficient area for loading TiO2 nanoparticles and contacting pollutants as well as appropriate water transport pathways at significantly shrinking thickness of wood (the thickness of 0.2 mm) can be provide by these sinuous channels. TiO2 nanoparticles was first modified by (3-Aminopropyl)triethoxysilane with high positive charge, and immobilized on negatively charged wood surface through atmospheric impregnation via strong electrostatic attractive interaction. Vast quantities of exposed TiO2 nanoparticles on wood cell lumens significantly enhance the adsorption ability for dye contaminants, resulting in a high membrane separation performance. The flux of TiO2/wood veneer membrane can achieve high level of 636.94 L/(m2h) with considerable methylene blue removal of 99.9% at 0.01 MPa. Meanwhile, it shows good cycling stability as well as decent flexibility and excellent mechanical strength. Moreover, the designed membrane with photocatalytic function of TiO2 also displays impressive decontaminated and recycling ability. The flux can recover its pre-recession level after 10 h light irradiation. The designed TiO2/wood veneer with simple preparation process and excellent water treatment capacity exhibits promising results for practical wastewater treatment.

Semi-Embedding Zn-Co3O4 Derived from Hybrid ZIFs into Wood-Derived Carbon for High-Performance Supercapacitors.

Transition metal oxides (TMOs) can provide high theoretical capacitance due to the change of multiple valence states of transition metals. However, their intrinsic drawbacks, including poor electrical conductivity, lower energy density, and huge volume expansion, will result in the pulverization of electrode materials and restricted electrochemical kinetics, thus leading to poor rate capability and rapid capacity fading. Composite electrodes based on transition metal oxides and carbon-based materials are considered to be promising candidates for overcoming these limitations. Herein, we reported a preparation method of hybrid ZIFs derived Zn-doped Co3O4/carbon (Zn-Co3O4/C-230) particles semi-embedded in wood-derived carbon skeleton for integrated electrodes. A large specific surface area, excellent conductivity, and electrochemical stability provide a larger electrochemical activity and potential window for the electrode. Prepared Zn-Co3O4@CW-230 electrode (0.6 mm thick) displays ultrahigh area specific capacitances of 7.83 and 6.46 F cm-2 at the current densities of 5 and 30 mA cm-2, respectively. Moreover, a symmetric supercapacitor assembled by two identical Zn-Co3O4@CW-230 electrodes delivers a superior area-specific capacitance of 2.61 F cm-2 at the current densities of 5 mA cm-2 and great energy densities of 0.36 mWh cm-2 (6.0 mWh cm-3) at 2.5 mW cm-2, while maintaining 97.3% of initial capacitance over 10,000 cycles. It notably outperforms those of most carbon-based metal oxides, endowing the Zn-Co3O4@CW-230 with extensive prospects for practical application.

Tannin-Derived Hard Carbon for Stable Lithium-Ion Anode.

Graphite anodes are well established for commercial use in lithium-ion battery systems. However, the limited capacity of graphite limits the further development of lithium-ion batteries. Hard carbon obtained from biomass is a highly promising anode material, with the advantage of enriched microcrystalline structure characteristics for better lithium storage. Tannin, a secondary product of metabolism during plant growth, has a rich source on earth. But the mechanism of hard carbon obtained from its derivation in lithium-ion batteries has been little studied. This paper successfully applied the hard carbon obtained from tannin as anode and illustrated the relationship between its structure and lithium storage performance. Meanwhile, to further enhance the performance, graphene oxide is skillfully compounded. The contact with the electrolyte and the charge transfer capability are effectively enhanced, then the capacity of PVP-HC is 255.5 mAh g-1 after 200 cycles at a current density of 400 mA g-1, with a capacity retention rate of 91.25%. The present work lays the foundation and opens up ideas for the application of biomass-derived hard carbon in lithium anodes.

Biochar-based slow-release of fertilizers for sustainable agriculture: A mini review.

Increasing global population and decreasing arable land pose tremendous pressures to agricultural production. The application of conventional chemical fertilizers improves agricultural production, but causes serious environmental problems and significant economic burdens. Biochar gains increasing interest as a soil amendment. Recently, more and more attentions have been paid to biochar-based slow-release of fertilizers (SRFs) due to the unique properties of biochar. This review summarizes recent advances in the development, synthesis, application, and tentative mechanism of biochar-based SRFs. The development mainly undergoes three stages: (i) soil amendment using biochar, (ii) interactions between nutrients and biochar, and (iii) biochar-based SRFs. Various methods are proposed to improve the fertilizer efficiency of biochar, majorly including in-situ pyrolysis, co-pyrolysis, impregnation, encapsulation, and granulation. Considering the distinct features of different methods, the integrated methods are promising for fabricating effective biochar-based SRFs. The in-depth understanding of the mechanism of nutrient loading and slow release is discussed based on current knowledge. Additionally, the perspectives and challenges of the potential application of biochar-based SRFs are described. Knowledge surveyed from this review indicates that applying biochar-based SRFs is a viable way of promoting sustainable agriculture.

Realizing Improved Sodium-Ion Storage by Introducing Carbonyl Groups and Closed Micropores into a Biomass-Derived Hard Carbon Anode.

Micropores and defects, like oxygen-containing groups, as active sites for sodium-ion storage in hard carbon have attracted considerable attention; nevertheless, most oxygen doping or oxidizing processes inevitably introduce undesired oxygen groups into a carbon framework, leading to deteriorated initial Coulombic efficiency (ICE). Here, precise carbonyl groups and closed micropores are together introduced into biomass-derived hard carbon to enhance the Na-ion storage performance. The hard carbon delivers a large reversible capacity of 354.6 mA h g-1 at 30 mA g-1, a high ICE (88.7%), as well as ultra-long cycling stability (277 mA h g-1 at 0.3 A g-1 over 1000 cycles; 243 mA h g-1 at 1 A g-1 over 5000 cycles). The rate capability and cycling stability of hard carbon in carbonate- and diglyme-based electrolytes are contrasted to demonstrate the superiority of diglyme. Cyclic voltammetry at varied scans and galvanostatic intermittent titration techniques are carried out to clarify the disparity between the two different electrolyte systems. Furthermore, the as-prepared hard carbon is utilized as the anode for sodium-ion full cells exhibiting an energy density of 166.2 W h kg-1 at 0.2 C and a long-cycle life (47.9% retention over 200 cycles at 1 C).

Assembly of Copolymer and Metal-Organic Framework HKUST-1 to Form Cu2-xS/CNFs Intertwining Network for Efficient Electrocatalytic Hydrogen Evolution.

The construction of complex intertwined networks that provide fast transport pathways for ions/electrons is very important for electrochemical systems such as water splitting, but a challenge. Herein, a three dimensional (3-D) intertwined network of Cu2-xS/CNFs (x = 0 or 0.04) has been synthesized through the morphology-preserved thermal transformation of the intertwined PEG-b-P4VP/ HKUST-1 hybrid networks. The strong interaction between PEG chains and Cu2+ is the key to the successful assembly of PEG-b-P4VP nanofibers and HKUST-1, which inhibits the HKUST-1 to form individual crystalline particles. The obtained Cu2-xS/CNFs composites possess several merits, such as highly exposed active sites, high-speed electronic transmission pathways, open pore structure, etc. Therefore, the 3-D intertwined hierarchical network of Cu2-xS/CNFs displays an excellent electrocatalytic activity for HER, with a low overpotential (η) of 276 mV to reach current densities of 10 mA cm-2, and a smaller Tafel slope of 59 mV dec-1 in alkaline solution.

Sulfur-Doped and Bio-Resin-Derived Hard Carbon@rGO Composites as Sustainable Anodes for Lithium-Ion Batteries.

Hard carbon derived from fossil products is widely used as anode material for lithium-ion batteries. However, there are still several main shortcomings such as high cost, and poor rate performance, which restrict its wide application. Then tremendous efforts have been devoted to developing biomaterials in the battery applications. Recently, especially agricultural and industrial by-products have attracted much attention due to the electric double-layer capacitors. Herein, we report the sulfur-doped hard carbon (SHC) materials from the tannin-furanic resins (TF-Resin) of the derived agricultural by-products, followed by enveloping rGO on its surface through the hexadecyl trimethyl ammonium bromide. SHC provides sites for the storage of lithium, while the rGO layers can offer a highly conductive matrix to achieve good contact between particles and promote the diffusion and transport of ions and electrons. As a result, the SHC@rGO shows excellent lithium storage performance with initial discharge capacity around 746 mAh g-1 at a current density of 50 mA g-1, and shows superb stability keeping capacity retention of 91.9% after 200 cycles. Moreover, even at a high current density of 2,000 mAg-1, SHC@rGO still delivers a specific capacity of 188 mAg-1. These desired promising properties are active to the implement in the possible practical application.

Facile in-situ growth of Ag/TiO2 nanoparticles on polydopamine modified bamboo with excellent mildew-proofing.

Bamboo with the outstanding properties, such as good mechanical strength, fast growth rate and low growth cost, is considered as one of utilitarian structural nature materials. But bamboo is easy to get mildewed resulting in disfiguration and fungi corrosion. In this work, a facile method was developed to improve the mildew-proofing capability of bamboo. Mussel-inspired polydopamine (PDA) with biomimetic adhesion function and highly active functional groups was employed to immobilize highly-dispersed Ag and TiO2 nanoparticles on the surface of bamboo via an in-situ growth method. Integrating the uniform PDA coating, photocatalytic function of TiO2 nanoparticles and bactericidal role of Ag nanoparticles, the mildew-proofing capability of bamboo is enhanced significantly. The results show a non-covalent interaction is more likely to account for the binding mechanism of PDA to bamboo. And the prepared bamboo samples show good photocatalytic performance and have excellent resistance leachability. Meanwhile, the mildew-proofing property of prepared bamboo sample was greatly improved.

A strong adsorbent for Cu²âº: graphene oxide modified with triethanolamine.

A strong adsorbent TEA-GO for Cu(2+) is prepared using TEA modified GO nanosheets. FT-IR and XPS results show that epoxy groups on GO are eliminated, and simultaneously hydroxyl groups and C-N dominate the surface groups of TEA-GO. The increased equilibrium capacity of TEA-GO for a high initial concentration of Cu(2+) makes it a promising adsorbent for heavy metal ions.