RESUMO
The enhancement of display performance and durability in polymer-stabilized vertical alignment liquid crystal and the liquid crystal are negative liquid crystals, which can be vertically aligned under the action of a vertical orientation layer and an electric field. Devices (PSVA LCDs) are crucial for advancing LCD technology. This study aims to investigate the electro-optical characteristics of PSVA LCDs by varying polymerization monomer concentrations. Using both simulations via TechWiz LCD 3D and experimental methods, such as polymer-induced phase separation, we developed an optoelectronic testing framework to assess voltage transmittance and response times. In our main findings, we show that an increase in polymeric monomer concentration from 3% to 7% resulted in a 67% increase in threshold voltage and a 44% decrease in saturation voltage. The on-state response time increased by about a factor of three, while the off-state response time decreased by about a factor of three. The alignment of our simulation results with experimental data validates our methodology, offering the potential of simulation tools as a pivotal resource in the PSVA LCDs. The alignment of our simulation results with experimental data validates our methodology, offering the potential of simulation tools as a pivotal resource in the PSVA LCDs. These advancements promise significant improvements in PSVA LCD performance and durability.
RESUMO
As one of the main methods for fabricating microstructured surfaces, micro-injection molding has the advantages of short cycle time, high production efficiency, and the potential for batch manufacturing. However, non-negligible residual stresses inside the molded part could affect the replication quality, dimensions, and physical properties of the microstructure. Therefore, studying the effects of processing parameters on residual stresses is a necessary prerequisite to ensure the successful fabrication of microstructured parts. In this paper, an injection molding simulation model of micro-pillar arrays was developed using molecular dynamics software, and a series of injection molding experiments were conducted. It was found that increasing the mold temperature and melt temperature can reduce the thermal residual stresses and molecular orientation stresses, and effectively improve the uniformity of residual stress distribution. The increase in the packing pressure can make the shear field of flow more intense and increase the molecular orientation stresses, thus making the residual stresses more severe.
RESUMO
Injection molding is an economical and effective method for manufacturing polymer parts with nanostructures and residual stress in the parts is an important factor affecting the quality of molding. In this paper, taking the injection molding of polymethyl methacrylate (PMMA) polymer in a nano-cavity with an aspect ratio of 2.0 as an example, the formation mechanism of residual stresses in the injection molding process was studied, using a molecular dynamics simulation. The changes in dynamic stress in the process were compared and analyzed, and the morphological and structural evolution of molecular chains in the process of flow were observed and explained. The effects of different aspect ratios of nano-cavities on the stress distribution and deformation in the nanostructures were studied. The potential energy, radius of gyration and elastic recovery percentage of the polymer was calculated. The results showed that the essence of stress formation was that the molecular chains compressed and entangled under the flow pressure and the restriction of the cavity wall. In addition, the orientation of molecular chains changed from isotropic to anisotropic, resulting in the stress concentration. At the same time, with the increase in aspect ratio, the overall stress and deformation of the nanostructures after demolding also increased.
