Composite spiral waves in discrete-time systems.

Spiral waves are a type of typical pattern in open reaction-diffusion systems far from thermodynamic equilibrium. The study of spiral waves has attracted great interest because of its nonlinear characteristics and extensive applications. However, the study of spiral waves has been confined to continuous-time systems, while spiral waves in discrete-time systems have been rarely reported. In recent years, discrete-time models have been widely studied in ecology because of their appropriateness to systems with nonoverlapping generations and other factors. Therefore, spiral waves in discrete-time systems need to be studied. Here, we investigated a novel type of spiral wave called a composite spiral wave in a discrete-time predator-pest model, and we revealed the formation mechanism. To explain the observed phenomena, we defined and quantified a move state effect of multiperiod states caused by the coupling of adjacent stable multiperiod orbits, which is strictly consistent with the numerical results. The other move state effect is caused by an unstable focus, which is the state of the local points at the spiral center. The combined effect of these two influences can lead to rich dynamical behaviors of spiral waves, and the specific structure of the composite spiral waves is the result of the competition of the two effects in opposite directions. Our findings shed light on the dynamics of spiral waves in discrete-time systems, and they may guide the prediction and control of pests in deciduous forests.

Simultaneous detection of multi-component greenhouse gases based on an all-fibered near-infrared single-channel frequency-division multiplexing wavelength-modulated laser heterodyne radiometer.

The performance of an all fibered near-infrared (NIR) single-channel frequency-division multiplexing wavelength-modulated laser heterodyne radiometer (FDM WM-LHR) is demonstrated in ground-based solar occultation mode. The system modulates the laser through the high-frequency signal output by the lock-in amplifier to replace the traditional chopper modulation, making it more stable and compact. Moreover, personal computers are used to simultaneously control the operating current of two distributed feedback (DFB) lasers through a general purpose interface bus-universal serial bus (GPIB-USB), thereby controlling the central wavelength of the laser at 1602.88 and 1653.727 nm, which serve as the absorption lines for the local oscillator detection of the two main greenhouse gases: CO2 and CH4. Firstly, the performance of traditional laser heterodyne radiometer (LHR) and the wavelength-modulated laser heterodyne radiometer (WM-LHR) are compared. The results reveal that both the radiometers have an optimized 2f signal when the modulation amplitude m = 2.2. In the actual measurement, 0.25 V and 0.21 V are selected as the modulation amplitude of the laser for the detection of CH4 and CO2. Under the same experimental parameters, at 1602.88 nm, the signal-to-noise ratio (SNR) for the 2f signal of CO2 in the WM-LHR system is 500.24, while that for the direct absorption signal (DAS) of CO2 in the traditional LHR system is 337.94. At 1653.727 nm, the SNR for the 2f signal in the WM-LHR system and the DAS of CH4 in the traditional LHR system are 512.04 and 389.58, respectively. Obviously, the SNR for the WM-LHR system is greatly improved. Finally, the application of frequency-division multiplexing (FDM) technology in the WM-LHR system is discussed. The modulation frequency of the two lasers should be appropriately selected to avoid interference between the signals. Overall, the results show that the FDM WM-LHR system can not only detect multiple gases simultaneously but also reduce the implementation cost of the ground-based radiometer. In addition, this study provides useful insights on planetary atmosphere exploration.

A self-healing polymerized-ionic-liquid-based polymer electrolyte enables a long lifespan and dendrite-free solid-state Li metal batteries at room temperature.

The implementation of high-safety Li metal batteries (LMBs) needs more stable and safer electrolytes. The solid-state electrolytes (SSEs) with their advantageous properties stand out for this purpose. However, low Li/electrolyte interfacial instability and uncontrolled Li dendrites growth trigger unceasing breakage of the solid electrolyte interphase (SEI), leading to fast capacity degradation. In response to these shortcomings, a new type of polymer electrolyte with self-healing capacity is introduced by grafting ionic liquid chain units into the backbones of polymers, which inherits the chemical inertness against the Li anode, allowing high Li+ transport, wide electrochemical window, and self-healing traits. Benefiting from the strong external H-bonding interactions, the obtained polymer electrolyte can spontaneously reconstruct dendrite-induced defects and fatigue crack growth at the Li/electrolyte interface, and, in turn, help tailor Li deposition. Owing to the resilient Li/electrolyte interface and dendrite-free Li plating, the equipped Li|LFP batteries display a high initial specific capacity of 134.7 mA h g-1, rendering a capacity retention of 91.2% after 206 cycles at room temperature. The new polymer electrolyte will undoubtedly bring inspiration for developing practical LMBs with highly improved safety and interfacial stability.

Non-monotonic dependence of polymer chain dynamics on active crowder size.

Configuration dynamics of flexible polymer chains is of ubiquitous importance in many biological processes. Here, we investigate a polymer chain immersed in a bath of size-changed active particles in two dimensional space using Langevin dynamics simulations. Particular attention is paid to how the radius of gyration Rg of the polymer chain depends on the size σc of active crowders. We find that Rg shows nontrivial non-monotonic dependence on σc: The chain first swells upon increasing σc, reaching a fully expanded state with maximum Rg, and then, Rg decreases until the chain collapses to a compact coil state if the crowder is large enough. Interestingly, the chain may oscillate between a collapse state and a stretched state at moderate crowder size. Analysis shows that it is the competition between two effects of active particles, one stretching the chain from inside due to persistence motion and the other compressing the chain from outside, that leads to the non-monotonic dependence. Besides, the diffusion of the polymer chain also shows nontrivial non-monotonic dependence on σc. Our results demonstrate the important interplay between particle activity and size associated with polymer configurations in active crowding environments.

Configuration dynamics of a flexible polymer chain in a bath of chiral active particles.

We investigate the configuration dynamics of a flexible polymer chain in a bath of active particles with dynamic chirality, i.e., particles rotate with a deterministic angular velocity ω besides self-propulsion, by Langevin dynamics simulations in a two dimensional space. Particular attention is paid to how the radius of gyration Rg changes with the propulsion velocity v0, the angular velocity ω, and the chain length N. We find that in a chiral bath with a typical nonzero ω, the chain first collapses into a small compact cluster and then swells again with increasing v0, in quite contrast to the case for a normal achiral bath (ω = 0) wherein a flexible chain swells with increasing v0. More interestingly, the polymer can even form a closed ring if the chain length N is large enough, which may oscillate with the cluster if v0 is large. Consequently, the gyration radius Rg shows nontrivial nonmonotonic dependences on v0, i.e., it undergoes a minimum for relatively short chains and two minima with a maximum in between for longer chains. Our analysis shows that such interesting phenomena are mainly due to the competition between two roles played by the chiral active bath: while the persistence motion due to particle activity tends to stretch the chain, the circular motion of the particle may lead to an effective osmotic pressure that tends to collapse the chain. In addition, the size of the circular motion R0 = v0/ω plays an important role in that the compact clusters and closed-rings are both observed at nearly the same values of R0 for different ω.

A new choice for the treatment of segmental tibial bone defects: intramedullary nail internal fixation combined adipose-derived stem cells technique.

The repair of various segmental tibial bone defects continues to be a challenging part of many reconstructive procedures. Many methods have been tried to repair the defects, followed by many complications and the results may be unsatisfied. Since 2001 Zuk et al. established human adipose-derived stem cells (hASCs) as a multipotent stem cell population with the ability to assume osteogenic phenotypes through chemically induced differentiation, hASCs represent a valuable tool for pharmacological and biological studies of osteoblast differentiation in vitro and bone development in vivo, and have been proved to be a useful source of stem cells in bone repair. Recently, hASCs have been found to repair both animals and human calvarial defects. In this paper, we hypothesize that hASCs cultured on custom scaffolds can be used to repair of tibial segmental bone defects with intramedullary nail internal fixed. Unlike current treatment modalities, it would promote the regeneration of tibial defects, provide structural support and allow for weight bearing and bony substitution over time.