RESUMO
Electrocatalysts with outstanding performance have been highly desired toward exploration of new energy storage and conversion devices/systems as well as making an efficient and eco-friendly utilization of green energy. In this study, we composed an iron-based binary diselenide-derived oxide (Fe-SDO) with a facile one-step hydrothermal method to utilize the earth-abundant iron and the probably prosperous catalytic performance of metal-selenides compounds. The catalyst exhibits an overpotential of 226 mV at a current density of 10 mA/cm2, a Tafel slope of 41 mV dec-1, and robust durability after catalyzing vigorous OER for 36 h constantly. Through several analytical methods conducted before and after the oxygen evolution reaction activation on FeSe2 it was discovered that such catalyst possessed a morphology as "Cuju"-like balls with porosity inside in which we explored the vacancy defects and lattice distortion that play significant roles in generating the high electrocatalytic performance of our proposed catalyst by inducing remarkable electron conductivity in the porous Cuju balls (a Chinese traditional football). Throughout our work the superb electrocatalyst performance of the iron-based compounds was demonstrated, and subsequently the underlying reason for such electrocatalyst performance was addressed, which may push boundaries for the exploration of iron-based compounds as OER catalyst and large-scale commercial application of such compounds in the future.
