RESUMO
In this study, we designed a surface phase-matched transmission enhancement top electrode-Ag/indium tin oxide (ITO) structure for highly efficient and aesthetic semitransparent organic photovoltaics (ST-OPVs). The purposed highly transparent back electrodes (Ag/ITO) could selectively decrease visible reflection and increase transparency accordingly. By altering the thicknesses of the Ag and ITO layers, we could control the transmittance curve and increase the transparency of the ST-OPV devices. Devices based on PTB7-Th:IEICO-4F and PM6:Y6:PC71BM displayed outstanding performance (8.1 and 10.2%, respectively) with high photopic-weighted visible light transmittance (36.2 and 28.6%, respectively). The outstanding visible and near-infrared light harvesting of PM6:Y6:PC71BM further allowed a new application: double-sided energy harvesting from solar and indoor illumination. The simple optical design of a top electrode displaying high transparency/conductivity has a wide range of potential applications in, for example, greenhouse photovoltaics, tandem cells, and portable devices.
RESUMO
An acceptor-donor-acceptor (A-D-A)-type non-fullerene acceptor (NFA), PTTtID-Cl, featuring thieno[3,2-b]thieno[2''',3''':4'',5'']-pyrrolo[2'',3'':4',5']thieno[2',3':4,5]thieno-[2,3-d]pyrrole (DTPTt) as the electron-rich core and 2-(5,6-dichloro-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile (ID-Cl) as the peripheral electron-deficient terminal group was synthesized and characterized. PTTtID-Cl exhibited strong absorption in the range of 700-850â nm in CHCl3 and redshifted absorption centered at 881â nm in a thin film. The near infrared (NIR)-absorption of PTTtID-Cl was combined with a low-bandgap polymer donor (PTB7-Th) to achieve binary and semitransparent organic photovoltaics (OPVs) with a power conversion efficiency (PCE) of 8.9 % and 7.7 % (with an average visible transmittance (AVT) of 16.7 %), respectively. A ternary device with a ratio of PM7/PTTtID-Cl/IT-4F=1:0.15:0.85 (w/w) achieved a short-circuit current density of 19.46â mA cm-2 , an open-circuit voltage of 0.87â V, and a fill factor of 71.2 %, giving a PCE of 12.0 %. In addition, by employing the Ag/ITO/Ag microcavity structure, semitransparent colorful binary organic photovoltaics (OPVs) with superior transparency of 27.9 % at 427â nm and 22.7 % at 536â nm for blue and green devices, respectively, were prepared. The semitransparent colorful devices based on the optimized ternary blend gave PCEs of 8.7 %, 8.4 %, and 9.1 % for blue, green, and red devices, respectively. These results indicate the promising potential of PTTtID-Cl as a NIR-absorption NFA for applications in semitransparent colorful binary and ternary OPVs.