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Harnessing mechanical force to modulate material properties and enhance biomechanical functions is essential for advancing smart materials and bioengineering. Polymer mechanochemistry provides an emerging toolkit for exploring unconventional chemical transformations and modulating molecular structures through mechanical force. One of the key challenges is developing innovative force-sensing mechanisms for precise and in situ force detection. This study introduces mDPAC, a dynamic and sensitive mechanophore, demonstrating its mechanochromic properties through synergetic conformational gearing. Its unique mechanoresponsive mechanism is based on the simultaneous conformational synergy between its phenazine and phenyl moieties, facilitated by a worm-gear-like structure. We confirm mDPAC's complex mechanochemical response and elucidate its mechanotransduction mechanism through our experimental data and comprehensive simulations. The compatibility of mDPAC with hydrogels is particularly notable, highlighting its potential for applications in aqueous biological environments as a dynamic force sensor. Moreover, mDPAC's multicolored mechanochromic responses facilitate direct force sensing and visual detection, paving the way for precise and real-time mechanical force sensing in bulk materials.
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A method is developed for facile encapsulation of reactive organic bases with potential application for autonomous damage detection and self-healing polymers. Highly reactive chemicals such as bases and acids are challenging to encapsulate by traditional oil-water emulsion techniques due to unfavorable physical and chemical interactions. In this work, reactivity of the bases is temporarily masked with photo-removable protecting groups, and the resulting inactive payloads are encapsulated via an in situ emulsion-templated interfacial polymerization method. The encapsulated payloads are then activated to restore the organic bases via photo irradiation, either before or after being released from the core-shell carriers. The efficacy of the photo-activated capsules is demonstrated by a damage-triggered, pH-induced color change in polymeric coatings and by recovery of adhesive strength of a damaged interface. Given the wide range of potential photo-deprotection chemistries, this encapsulation scheme provides a simple but powerful method for storage and targeted delivery of a broad variety of reactive chemicals, promoting design of diverse autonomous functionalities in polymeric materials.
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A near-infrared (NIR) mechanophore was developed and incorporated into a poly(methyl acrylate) chain to showcase the first force-induced NIR chromism in polymeric materials. This mechanophore, based on benzo[1,3]oxazine (OX) fused with a heptamethine cyanine moiety, exhibited NIR mechanochromism in solution, thin-film, and bulk states. The mechanochemical activity was validated using UV-vis-NIR absorption/fluorescence spectroscopies, gel permeation chromatography (GPC), NMR, and DFT simulations. Our work demonstrates that NIR mechanochromic polymers have considerable potential in mechanical force sensing, damage detection, bioimaging, and biomechanics.
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Detection and assessment of small-scale damage at early stages are essential for polymeric materials to extend lifetime, avoid catastrophic structural failure, and improve cost-efficiency. Previous self-reporting coatings provide visual indication of surface damage but have been limited to a single layer without information on the depth of crack penetration. Here, we present a novel strategy for autonomous indication of damage in multilayered polymeric materials using aggregation-induced emission luminogens (AIEgens). Three different AIEgens are encapsulated and layered into polymeric coatings. When scratches of varying depths penetrate the coating layers, different combinations of AIEgens are activated to visually detect the depth of damage based on the corresponding fluorescent colors. The AIEgen-based detection mechanism makes this system a powerful tool for damage indication in a variety of polymeric coatings.
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Compartmentalized structures widely exist in cellular systems (organelles) and perform essential functions in smart composite materials (microcapsules, vasculatures, and micelles) to provide localized functionality and enhance materials' compatibility. An entirely water-free compartmentalization system is of significant value to the materials community as nonaqueous conditions are critical to packaging microcapsules with water-free hydrophilic payloads while avoiding energy-intensive drying steps. Few nonaqueous encapsulation techniques are known, especially when considering just the scalable processes that operate in batch mode. Herein, we report a robust oil-in-oil Pickering emulsion system that is compatible with nonaqueous interfacial reactions as required for encapsulation of hydrophilic payloads. A major conceptual advance of this work is the notion of the partitioning inhibitor-a chemical agent that greatly reduces the payload's distribution between the emulsion's two phases, thus providing appropriate conditions for emulsion-templated interfacial polymerization. As a specific example, an immiscible hydrocarbon-amine pair of liquids is emulsified by the incorporation of guanidinium chloride (GuHCl) as a partitioning inhibitor into the dispersed phase. Polyisobutylene (PIB) is added into the continuous phase as a viscosity modifier for suitable modification of interfacial polymerization kinetics. The combination of GuHCl and PIB is necessary to yield a robust emulsion with stable morphology for 3 weeks. Shell wall formation was accomplished by interfacial polymerization of isocyanates delivered through the continuous phase and polyamines from the droplet core. Diethylenetriamine (DETA)-loaded microcapsules were isolated in good yield, exhibiting high thermal and chemical stabilities with extended shelf-lives even when dispersed into a reactive epoxy resin. The polyamine phase is compatible with a variety of basic and hydrophilic actives, suggesting that this encapsulation technology is applicable to other hydrophilic payloads such as polyols, aromatic amines, and aromatic heterocyclic bases. Such payloads are important for the development of extended pot or shelf life systems and responsive coatings that report, protect, modify, and heal themselves without intervention.
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Stimuli-responsive materials activated by a pair of molecular or ionic species are of interest in the design of chemical logic gates and signal amplification schemes. There are relatively few materials whose coactivated response has been well-characterized. Here, we demonstrate a specific ion coactivation (SICA) effect at the interfaces of transient polymer solids and liquid solutions. We found that depolymerization of the transient polymer, cyclic poly(phthalaldehyde) (cPPA), exhibited a SICA effect when the cPPA core-shell microcapsules were suspended in ion-containing acidic methanol solutions. Significant acceleration in cPPA depolymerization rate is triggered by the combination of acid and ion coactivators. Intriguingly, the SICA effect is related to the Hofmeister behavior. The SICA effect is primarily determined by anions, and cations exhibit a secondary effect that modulates the coactivation strength. Based on these observations, we developed cPPA programmable microcapsules whose payload release rates depend on the composition and concentration of the salt/acidic-methanol solutions.
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Synthesis of giant unimolecular dendrimers is challenging due, in part, to difficulties encountered at higher generations, in both convergent and divergent protocols because of the multistep construction/purification process. Herein, we report a hybrid synthetic procedure in which the core is constructed last. This quantitative assembly generated a metallodendrimer that is supercharged (120+), large (11.3 nm diameter), and its core was previously established. The series of complexes has been unequivocally characterized by NMR, ESI-IM-MS, and TEM techniques.
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Inspiration for molecular design and construction can be derived from mathematically based structures. In the quest for new materials, the adaptation of new building blocks can lead to unexpected results. Towards these ends, the quantitative single-step self-assembly of a shape-persistent, Archimedean-based building block, which generates the largest molecular sphere (a cuboctahedron) that has been unequivocally characterized by synchrotron X-ray analysis, is described. The unique properties of this new construct give rise to a dilution-based transformation into two identical spheres (octahedra) each possessing one half of the molecular weight of the parent structure; concentration of this octahedron reconstitutes the original cuboctahedron. These chemical phenomena are reminiscent of biological fission and fusion processes. The large 6â nm cage structure was further analyzed by 1D and 2D NMR spectroscopy, mass spectrometry, and collision cross-section analysis. New routes to molecular encapsulation can be envisioned.
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Substâncias Macromoleculares/química , Metais/química , Ligantes , Espectroscopia de Ressonância Magnética , Nanoestruturas/química , Espectrometria de Massas por Ionização por ElectrosprayRESUMO
A terpyridine-based, concentration-dependent, facile self-assembly process is reported, resulting in two three-dimensional metallosupramolecular architectures, a bis-rhombus and a tetrahedron, which are formed using a two-dimensional, planar, tris-terpyridine ligand. The interconversion between these two structures is concentration-dependent: at a concentration higher than 12 mg mL(-1), only a bis-rhombus, composed of eight ligands and 12 Cd(2+) ions, is formed; whereas a self-assembled tetrahedron, composed of four ligands and six Cd(2+) ions, appears upon sufficient dilution of the tris-terpyridine-metal solution. At concentrations less than 0.5 mg mL(-1), only the tetrahedron possessing an S4 symmetry axis is detected; upon attempted isolation, it quantitatively reverts to the bis-rhombus. This observation opens an unexpected door to unusual chemical pathways under high dilution conditions.
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A facile high yield, self-assembly process that leads to a terpyridine-based, three-dimensional, bis-rhomboidal-shaped, molecular wheel is reported. The desired coordination-driven supramolecular wheel involves eight structurally distorted tristerpyridine (tpy) ligands possessing a 60° angle between the adjacent tpy units and twelve Zn(2+) ions. The tpy ligand plays dual roles in the self-assembly process: two are staggered at 180° to create the internal hub, while six produce the external rim. The wheel can be readily generated by mixing the tpy ligand and Zn(2+) in a stoichiometric ratio of 2:3; full characterization is provided by ESI-MS, NMR spectroscopy, and TEM imaging.
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Ligantes , Piridinas/química , Isomerismo , Espectroscopia de Ressonância Magnética , Simulação de Dinâmica Molecular , Espectrometria de Massas por Ionização por Electrospray , Zinco/químicaRESUMO
Dipole induced vacuum level shift has been demonstrated to be responsible for the enhanced efficiency in polymer solar cells (PSCs).The modified energy level alignment could reduce the energy barrier and facilitate charge transport, thereby increasing the efficiency of PSCs. Herein, we report a new mechanism toward enhanced efficiency by using a nondipolar water/alcohol-soluble neutral fullerene derivative to reengineer the surface of the zinc oxide (ZnO) electron extraction layer (EEL) in inverted PSCs. Because of the neutral property (ion-free) of the fullerene derivatives, no dipole moment was introduced at the EEL/active layer interface. A negligible change in open-circuit voltage was observed from inverted PSCs with the neutral fullerene derivative layer. The neutral fullerene derivative layer greatly increased the surface electronic conductivity of the ZnO EEL, suppressed surface charge recombination, and increased the short-circuit current density and fill factor. An overall power conversion efficiency increase of more than 30% from inverted PSCs was obtained. These results demonstrate that the surface electronic conductivity of the EEL plays an important role in high performance inverted PSCs.
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The design and construction of the first multicomponent stepwise assembly of a
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Compostos Macrocíclicos/síntese química , Compostos Organometálicos/síntese química , Piridinas/síntese química , Rutênio/química , Compostos Macrocíclicos/química , Modelos Moleculares , Compostos Organometálicos/química , Piridinas/químicaRESUMO
The self-assembly of the o-carborane-based, bisterpyridyl monomer, 1,2-bis[4'-(4-ethynylphenyl)-2,2':6',2''-terpyridine]-o-carborane, utilizing either Zn(II) or Fe(II) in a precise metal : ligand ratio (1 : 1), generated a family of metallomacrocycles that were studied via ESI-TWIM-MS, (1)H NMR, and 2D NMR (COSY, NOESY). Under kinetic control, via formation of Fe(II) complexes, the main cyclic product was triangular, as is typical of 60°-based bisligands. Under thermodynamic control using more labile transition metal complexes, e.g. Zn(II), the ratio of cyclic species was found to be concentration and temperature dependent, and under an adequate entropic driving force, the cyclic dimer was formed. This system was probed via variable temperature NMR to reveal dynamic equilibrium between the entropically favored dimer and enthalpically favored trimer.
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Compostos de Boro/química , Complexos de Coordenação/química , Compostos Macrocíclicos/química , Piridinas/química , Cristalografia por Raios X , Ferro/química , Cinética , Espectroscopia de Ressonância Magnética , Modelos Moleculares , Estrutura Molecular , Espectrometria de Massas por Ionização por Electrospray , Temperatura , Termodinâmica , Zinco/químicaRESUMO
A three-dimensional, highly symmetric, terpyridine-based, spherical complex was synthesized via the coordination of four novel, trisdentate ligands and six Ru(2+) ions, and it exhibits excellent stability over a wide range of pH values (1-14). Structural confirmation was obtained by NMR and ESI-TWIM-MS.
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A series of giant polymer-dendron conjugates with a dendron head and a linear polymer tail were synthesized via"click" chemistry between azide-functionalized polystyrene (PS(N), N: degree-of-polymerization) and t-butyl protected, alkyne-functionalized second generation dendron (tD), followed by a deprotection process to generate a dendron termini possessing nine carboxylic acid groups. The molecular structures were confirmed by nuclear magnetic resonance, size-exclusion chromatographic analyses, and matrix-assisted laser desorption ionization time-of-flight mass spectra. These well-defined conjugates can serve as a model system to study the effects of the molecular geometries on the self-assembly behaviour, as compared with their linear analogues. Four phase morphologies found in flexible linear diblock copolymer systems, including lamellae, bicontinuous double gyroids, hexagonal packed cylinders, and body-centred cubic packed spheres, were observed in this series of conjugates based on the results of small angle X-ray scattering and transmission electron microscopy. All of the domain sizes in these phase separated structures were around or less than 10 nm. A 'half' phase diagram was constructed based on the experimental results. The geometrical effect was found not only to enhance the immiscibility between the PS(N) tail and dendron head, but also systematically shift all of the phase boundaries towards higher volume fractions of the PS(N) tails, resulting in an asymmetrical phase diagram. This study may provide a pathway to the construction of ordered patterns of sub-10 nm feature size using polymer-dendron conjugates.
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Where there's a wheel, there's a way: The terpyridine-based title system has been synthesized through a facile self-assembly process. Two tris(terpyridine) ligands possessing angles of either 120° or 60° between adjacent tpy units were mixed with a stoichiometric amount of Zn(2+) (2:6:12) to generate the desired coordination-driven bicycle-like wheel (90 % yield).
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Complexos de Coordenação/química , Piridinas/síntese química , Zinco/química , Complexos de Coordenação/metabolismo , Ligantes , Modelos Moleculares , Estrutura Molecular , Piridinas/metabolismo , Zinco/metabolismoRESUMO
Multicomponent, self-assembled rhomboidal constructs are reported, in which bis-terpyridines possessing 120° or 60° directionality and Zn(II) or Cd(II) in a stoichiometric ratio (1 : 1 : 2) initially form rhomboid and triangle mixtures; whereas, a tris-terpyridine reacts with the 60°-based bis-ligand and metal to quantitatively form a heteroleptic, centrally fused, rhomboidal structure.
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Cádmio/química , Piridinas/química , Zinco/química , Ligantes , Espectroscopia de Ressonância MagnéticaRESUMO
An approach to multicomponent coordination-driven self-assembly of the first terpyridine-based, shape-persistent, giant two-dimensional D(6h) supramacromolecular spoked wheel is reported. Mixing core T6, rim T3, and Zn(II) or Cd(II) ions in a stoichiometric ratio (1:6:12) permitted the selective generation of a highly symmetric spoked wheel in 94% isolated yield via geometric and thermodynamic control. The products were characterized by a combination of traveling-wave ion mobility mass spectrometry and NMR techniques together with TEM imaging, which agreed with computational simulations.
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Piridinas/síntese química , Ligantes , Substâncias Macromoleculares/síntese química , Substâncias Macromoleculares/química , Estrutura Molecular , Tamanho da Partícula , Piridinas/química , Propriedades de Superfície , TermodinâmicaRESUMO
The synthesis, purification, structural analysis, and photophysical properties of a series of five-, six-, and seven-sided Fe(II) macrocycles and the corresponding hexameric Cd(II) macrocycle, all prepared by self-assembly of a 120° bis(terpyridine) ligand modified with first- and second-generation 1â3 C-branched dendrons, are reported. All metallomacrocycles were fully characterized by (1)H and (13)C NMR spectroscopy, traveling-wave ion-mobility mass spectrometry (TWIM MS), molecular modeling, UV/Vis absorption spectroscopy, photoluminescence, and cyclic voltammetry. A gradual increase of the collision cross sections of the Fe(II) metallomacrocycles was observed with a successive increase of the number and molecular size of the ligands. The combination of ion-mobility mass spectrometry and NMR techniques unveils structural features that agree well with calculations. Extinction coefficients and emission are significantly modulated by increasing the ring size and changing the metal ion center from Fe(II) to Cd(II) .